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Fluorescent detection of phosphate anion by a highly selective chemosensor in water
A macrocyclic dinuclear copper complex, [Cu 2 II( 1)Br 4]·2H 2O has been synthesized and characterized by X-ray crystallography, in which each metal ion is pentacoordinated in a square pyramidal environment and the macrocycle is folded to form a boat-shaped empty cavity. As studied by an indicator d...
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| Published in: | Tetrahedron letters 2010-09, Vol.51 (37), p.4904-4907 |
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| Main Authors: | , , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c529t-bcf197b0b8ee5851d01721817d147e8afccc742868b5043e7688b1a3be8bee423 |
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| cites | cdi_FETCH-LOGICAL-c529t-bcf197b0b8ee5851d01721817d147e8afccc742868b5043e7688b1a3be8bee423 |
| container_end_page | 4907 |
| container_issue | 37 |
| container_start_page | 4904 |
| container_title | Tetrahedron letters |
| container_volume | 51 |
| creator | Saeed, Musabbir A. Powell, Douglas R. Hossain, Md. Alamgir |
| description | A macrocyclic dinuclear copper complex, [Cu
2
II(
1)Br
4]·2H
2O has been synthesized and characterized by X-ray crystallography, in which each metal ion is pentacoordinated in a square pyramidal environment and the macrocycle is folded to form a boat-shaped empty cavity. As studied by an indicator displacement assay, the dinuclear complex shows strong selectivity for phosphate over sulfate, nitrate, perchlorate and halides in water at physiological pH. |
| doi_str_mv | 10.1016/j.tetlet.2010.07.078 |
| format | article |
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II(
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4]·2H
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2
II(
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4]·2H
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| ispartof | Tetrahedron letters, 2010-09, Vol.51 (37), p.4904-4907 |
| issn | 0040-4039 1873-3581 |
| language | eng |
| recordid | cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_2935809 |
| source | ScienceDirect Journals |
| title | Fluorescent detection of phosphate anion by a highly selective chemosensor in water |
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