Giant Negative Thermal Expansion in the Iron Perovskite SrCu3Fe4O12

Big and cold: Strong internal compression of the Sr ion in the novel perovskite SrCu3Fe4O12 (see structure) leads to giant negative thermal expansion (NTE) between 170 and 270 K. Mössbauer spectroscopy shows charge disproportionation of FeIV to FeIII and FeV below 200 K. Thus, the isoelectric substi...

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Published in:Angewandte Chemie (International ed.) 2011-07, Vol.50 (29), p.6579-6582
Main Authors: Yamada, Ikuya, Tsuchida, Kazuki, Ohgushi, Kenya, Hayashi, Naoaki, Kim, Jungeun, Tsuji, Naruki, Takahashi, Ryoji, Matsushita, Masafumi, Nishiyama, Norimasa, Inoue, Toru, Irifune, Tetsuo, Kato, Kenichi, Takata, Masaki, Takano, Mikio
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Language:English
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charge disproportionation
high-pressure chemistry
Mössbauer spectroscopy
negative thermal expansion
perovskite phases
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container_issue 29
container_start_page 6579
container_title Angewandte Chemie (International ed.)
container_volume 50
creator Yamada, Ikuya
Tsuchida, Kazuki
Ohgushi, Kenya
Hayashi, Naoaki
Kim, Jungeun
Tsuji, Naruki
Takahashi, Ryoji
Matsushita, Masafumi
Nishiyama, Norimasa
Inoue, Toru
Irifune, Tetsuo
Kato, Kenichi
Takata, Masaki
Takano, Mikio
description Big and cold: Strong internal compression of the Sr ion in the novel perovskite SrCu3Fe4O12 (see structure) leads to giant negative thermal expansion (NTE) between 170 and 270 K. Mössbauer spectroscopy shows charge disproportionation of FeIV to FeIII and FeV below 200 K. Thus, the isoelectric substitution of the A‐site cation can induce a drastic change of the structural and electronic properties in ACu3Fe4O12 perovskites.
doi_str_mv 10.1002/anie.201102228
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Chem. Int. Ed</addtitle><date>2011-07-11</date><risdate>2011</risdate><volume>50</volume><issue>29</issue><spage>6579</spage><epage>6582</epage><pages>6579-6582</pages><issn>1433-7851</issn><eissn>1521-3773</eissn><coden>ACIEAY</coden><notes>Ministry of Education, Culture, Sports, Science and Technology of Japan - No. 21750062</notes><notes>Priority Nanotechnology Support Program - No. 2010A1616</notes><notes>ark:/67375/WNG-H6QKQ8N6-C</notes><notes>istex:67B35C4D897A87686934FA9D61B6EB5D944E13A9</notes><notes>We thank Masahiko Isobe and Yutaka Ueda for help with the low-temperature XRD measurements at ISSP, Hiroshi Kageyama for help with the synchrotron XRD measurements, and Yuichi Shimakawa for allowing the use of the Mössbauer spectrometer. The synchrotron radiation experiments were performed at SPring-8 under the Priority Nanotechnology Support Program administered by JASRI (Proposal No. 2010A1616). This work was partly performed using the facilities of ISSP and supported by the Ministry of Education, Culture, Sports, Science and Technology of Japan with a Grant-in-Aid for Young Scientists (B) No. 21750062.</notes><notes>ArticleID:ANIE201102228</notes><notes>We thank Masahiko Isobe and Yutaka Ueda for help with the low‐temperature XRD measurements at ISSP, Hiroshi Kageyama for help with the synchrotron XRD measurements, and Yuichi Shimakawa for allowing the use of the Mössbauer spectrometer. The synchrotron radiation experiments were performed at SPring‐8 under the Priority Nanotechnology Support Program administered by JASRI (Proposal No. 2010A1616). 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subjects charge disproportionation
high-pressure chemistry
Mössbauer spectroscopy
negative thermal expansion
perovskite phases
title Giant Negative Thermal Expansion in the Iron Perovskite SrCu3Fe4O12
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