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Magnetite Colloidal Nanocrystals: A Facile Pathway To Prepare Mesoporous Hematite Thin Films for Photoelectrochemical Water Splitting
In this study, we demonstrate an alternative and promising way to produce hematite photoanodes with high performance and without the addition of doping or catalytic coating. In this approach, we processed hematite thin films using a colloidal dispersion of magnetite nanocrystals as the precursor. Th...
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Published in: | Journal of the American Chemical Society 2011-04, Vol.133 (15), p.6012-6019 |
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Main Authors: | , , |
Format: | Article |
Language: | English |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | In this study, we demonstrate an alternative and promising way to produce hematite photoanodes with high performance and without the addition of doping or catalytic coating. In this approach, we processed hematite thin films using a colloidal dispersion of magnetite nanocrystals as the precursor. The photoelectrochemical characterization shows that the colloidal approach used to process an undoped hematite photoanode produced a high-performance electrode for water photooxidation with an onset potential as low as 0.8 VRHE. This value is comparable to the best results reported in the literature for a hematite photoanode modified with catalytic materials. We demonstrate that pure hematite thin films reach 1.1 mA·cm−2 at 1.23 VRHE with back-side illumination. |
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ISSN: | 0002-7863 1520-5126 |
DOI: | 10.1021/ja111454f |