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Modeling heterogeneous chemical processes on aerosol surface
To explore the possible impact of heterogeneous chemical processes on atmospheric trace components, a coupled box model including gas-phase chemical processes, aerosol thermodynamic equilibrium processes, and heterogeneous chemical processes on the surface of dust, black carbon (BC) and sea salt is...
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Published in: | Particuology 2010-08, Vol.8 (4), p.308-318 |
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creator | Deng, Junjun Wang, Tijian Liu, Li Jiang, Fei |
description | To explore the possible impact of heterogeneous chemical processes on atmospheric trace components, a coupled box model including gas-phase chemical processes, aerosol thermodynamic equilibrium processes, and heterogeneous chemical processes on the surface of dust, black carbon (BC) and sea salt is set up to simulate the effects of heterogeneous chemistry on the aerosol surface, and analyze the primary factors affecting the heterogeneous processes. Results indicate that heterogeneous chemical processes on the aerosol surface in the atmosphere will affect the concentrations of trace gases such as H2O2, HO2, O3, NO2, NO3, HNO3 and SO2, and aerosols such as SO42-, NO3- and NH4+. Sensitivity tests suggest that the magnitude of the impact of heterogeneous processes strongly depends on aerosol concentration and the surface uptake coefficients used in the box model. However, the impact of temperature on heterogeneous chemical processes is considerably less. The "renoxification" of HNO3 will affect the components of the troPosPhere such as nitrogen oxide and ozone. |
doi_str_mv | 10.1016/j.partic.2009.12.003 |
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Results indicate that heterogeneous chemical processes on the aerosol surface in the atmosphere will affect the concentrations of trace gases such as H2O2, HO2, O3, NO2, NO3, HNO3 and SO2, and aerosols such as SO42-, NO3- and NH4+. Sensitivity tests suggest that the magnitude of the impact of heterogeneous processes strongly depends on aerosol concentration and the surface uptake coefficients used in the box model. However, the impact of temperature on heterogeneous chemical processes is considerably less. 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Results indicate that heterogeneous chemical processes on the aerosol surface in the atmosphere will affect the concentrations of trace gases such as H2O2, HO2, O3, NO2, NO3, HNO3 and SO2, and aerosols such as SO42-, NO3- and NH4+. Sensitivity tests suggest that the magnitude of the impact of heterogeneous processes strongly depends on aerosol concentration and the surface uptake coefficients used in the box model. However, the impact of temperature on heterogeneous chemical processes is considerably less. The "renoxification" of HNO3 will affect the components of the troPosPhere such as nitrogen oxide and ozone.</description><subject>Aerosols</subject><subject>Box model</subject><subject>Carbon</subject><subject>Dust</subject><subject>Heterogeneous chemistry</subject><subject>Mathematical models</subject><subject>Nitrogen oxides</subject><subject>Sea salt</subject><subject>Thermodynamic equilibrium</subject><subject>Trace gases</subject><subject>Troposphere</subject><subject>Uptakes</subject><subject>化学过程</subject><subject>均质过程</subject><subject>微量成分</subject><subject>气溶胶浓度</subject><subject>耦合模型</subject><subject>表面吸收</subject><subject>非均相</subject><issn>1674-2001</issn><issn>1672-2515</issn><issn>2210-4291</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><recordid>eNqFkE1L5TAUhoM44NWZfzCL4kZctHOSprEBEeTix4AyG_eHND3tzbW3uSa9fsyvN1r3QuAs8pyP92HsN4eCA1d_1sXWhMnZQgDogosCoNxjCyE45FJovs8WXJ3JPH3zA3YY4xpACSXKBTu_9y0NbuyzFU0UfE8j-V3M7Io2zpoh2wZvKUaKmR8zk4johyzuQmcs_WQ_OjNE-vVVj9jD9dXD8ja_-3fzd3l5l9tS6ylvuNZV05VkFZClyijRSqlM01iQbW3S0RXppuPc1md1o2sQ6XGqlSQBVXnETuexL2bszNjj2u_CmBbi__5xeG0wURxAAojEnsxsuvtpR3HCjYuWhsF85sJaallBLVUi5UzalCkG6nAb3MaEN-SAH1pxjbNW_NCKXGDSmtou5jZKgZ8dBYzW0WipdYHshK133w04_tq78mP_lNRjY-xj5wbCspJVDSnyO4LzjZQ</recordid><startdate>20100801</startdate><enddate>20100801</enddate><creator>Deng, Junjun</creator><creator>Wang, Tijian</creator><creator>Liu, Li</creator><creator>Jiang, Fei</creator><general>Elsevier B.V</general><general>School of Atmospheric Sciences,Nanjing University,22 Hankou Road,Nanjing 210093,China%School of Atmospheric Sciences,Nanjing University,22 Hankou Road,Nanjing 210093,China</general><general>Guizhou Institute of Mountainous Climate and Environment,Guiyang 550002,China</general><scope>2RA</scope><scope>92L</scope><scope>CQIGP</scope><scope>W92</scope><scope>~WA</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7TB</scope><scope>8BQ</scope><scope>8FD</scope><scope>FR3</scope><scope>JG9</scope><scope>KR7</scope><scope>2B.</scope><scope>4A8</scope><scope>92I</scope><scope>93N</scope><scope>PSX</scope><scope>TCJ</scope></search><sort><creationdate>20100801</creationdate><title>Modeling heterogeneous chemical processes on aerosol surface</title><author>Deng, Junjun ; 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Results indicate that heterogeneous chemical processes on the aerosol surface in the atmosphere will affect the concentrations of trace gases such as H2O2, HO2, O3, NO2, NO3, HNO3 and SO2, and aerosols such as SO42-, NO3- and NH4+. Sensitivity tests suggest that the magnitude of the impact of heterogeneous processes strongly depends on aerosol concentration and the surface uptake coefficients used in the box model. However, the impact of temperature on heterogeneous chemical processes is considerably less. The "renoxification" of HNO3 will affect the components of the troPosPhere such as nitrogen oxide and ozone.</abstract><pub>Elsevier B.V</pub><doi>10.1016/j.partic.2009.12.003</doi><tpages>11</tpages></addata></record> |
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subjects | Aerosols Box model Carbon Dust Heterogeneous chemistry Mathematical models Nitrogen oxides Sea salt Thermodynamic equilibrium Trace gases Troposphere Uptakes 化学过程 均质过程 微量成分 气溶胶浓度 耦合模型 表面吸收 非均相 |
title | Modeling heterogeneous chemical processes on aerosol surface |
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