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A New Hexaferrocene Complex with a [M3(μ3-O)]7+ Core
The new hexaferrocene complex 1 has been synthesized and characterized by X-ray diffraction. Its magnetization data were fitted to a detailed theoretical model that considers nonequivalent exchange parameters between Fe ions to yield the magnetic exchange coupling values of J 1/k B = −31.5 K and J 2...
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Published in: | Inorganic chemistry 2006-12, Vol.45 (26), p.10443-10445 |
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Main Authors: | , , , , , , , , , |
Format: | Article |
Language: | English |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | The new hexaferrocene complex 1 has been synthesized and characterized by X-ray diffraction. Its magnetization data were fitted to a detailed theoretical model that considers nonequivalent exchange parameters between Fe ions to yield the magnetic exchange coupling values of J 1/k B = −31.5 K and J 2/k B = −25.8 K. Moreover, the cyclic voltammogram of complex 1 confirmed its redox activity associated with the presence of ferrocene units, with very small or negligible electronic interactions between them. |
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ISSN: | 0020-1669 1520-510X |
DOI: | 10.1021/ic061322s |