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Preparation of conducting and transparent indium-doped ZnO thin films by chemical spray
Transparent conducting indium-doped zinc oxide thin films were prepared on soda-lime glass substrates by the spray pyrolysis technique. The dependence of the electrical, structural, morphological and optical properties on the preparation conditions has been studied. Two main variables, substrate tem...
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Published in: | Solar energy materials and solar cells 2006-04, Vol.90 (6), p.733-741 |
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container_title | Solar energy materials and solar cells |
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creator | Lucio-López, M.A. Luna-Arias, M.A. Maldonado, A. de la L. Olvera, M. Acosta, D.R. |
description | Transparent conducting indium-doped zinc oxide thin films were prepared on soda-lime glass substrates by the spray pyrolysis technique. The dependence of the electrical, structural, morphological and optical properties on the preparation conditions has been studied. Two main variables, substrate temperature and molar concentration, were varied in the ranges of 425–525
°C and 0.05–0.5
M, respectively, in order to obtain films with low electrical resistivity and high optical transparency in the visible region. A minimum resistivity value around of 3×10
−3
Ω
cm was obtained for films deposited from highly concentrated starting solutions, 0.4 and 0.5
M. The values of the free-carrier concentration and the electronic mobility were estimated by Hall effect measurements. X-ray diffraction spectra evidenced a preferential orientation along the (1
0
1) direction. The surface morphology was clearly affected with the molar concentration variation, leading to a smoother appearance as the zinc concentration in the starting solution is increased. Typical optical transmittance values in the order of 85% were obtained in all the films. |
doi_str_mv | 10.1016/j.solmat.2005.04.010 |
format | article |
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°C and 0.05–0.5
M, respectively, in order to obtain films with low electrical resistivity and high optical transparency in the visible region. A minimum resistivity value around of 3×10
−3
Ω
cm was obtained for films deposited from highly concentrated starting solutions, 0.4 and 0.5
M. The values of the free-carrier concentration and the electronic mobility were estimated by Hall effect measurements. X-ray diffraction spectra evidenced a preferential orientation along the (1
0
1) direction. The surface morphology was clearly affected with the molar concentration variation, leading to a smoother appearance as the zinc concentration in the starting solution is increased. Typical optical transmittance values in the order of 85% were obtained in all the films.</description><identifier>ISSN: 0927-0248</identifier><identifier>EISSN: 1879-3398</identifier><identifier>DOI: 10.1016/j.solmat.2005.04.010</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Applied sciences ; Chemical spray ; Energy ; Exact sciences and technology ; Indium-doped zinc oxide ; Natural energy ; Photovoltaic conversion ; Solar cells. Photoelectrochemical cells ; Solar energy ; Thin films</subject><ispartof>Solar energy materials and solar cells, 2006-04, Vol.90 (6), p.733-741</ispartof><rights>2005 Elsevier B.V.</rights><rights>2006 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c433t-e3be4eab19687a303b60b479c9485b184fea39e87d907e7d96cb809277ea671e3</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>310,311,315,786,790,795,796,23958,23959,25170,27957,27958</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=17596191$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Lucio-López, M.A.</creatorcontrib><creatorcontrib>Luna-Arias, M.A.</creatorcontrib><creatorcontrib>Maldonado, A.</creatorcontrib><creatorcontrib>de la L. Olvera, M.</creatorcontrib><creatorcontrib>Acosta, D.R.</creatorcontrib><title>Preparation of conducting and transparent indium-doped ZnO thin films by chemical spray</title><title>Solar energy materials and solar cells</title><description>Transparent conducting indium-doped zinc oxide thin films were prepared on soda-lime glass substrates by the spray pyrolysis technique. The dependence of the electrical, structural, morphological and optical properties on the preparation conditions has been studied. Two main variables, substrate temperature and molar concentration, were varied in the ranges of 425–525
°C and 0.05–0.5
M, respectively, in order to obtain films with low electrical resistivity and high optical transparency in the visible region. A minimum resistivity value around of 3×10
−3
Ω
cm was obtained for films deposited from highly concentrated starting solutions, 0.4 and 0.5
M. The values of the free-carrier concentration and the electronic mobility were estimated by Hall effect measurements. X-ray diffraction spectra evidenced a preferential orientation along the (1
0
1) direction. The surface morphology was clearly affected with the molar concentration variation, leading to a smoother appearance as the zinc concentration in the starting solution is increased. Typical optical transmittance values in the order of 85% were obtained in all the films.</description><subject>Applied sciences</subject><subject>Chemical spray</subject><subject>Energy</subject><subject>Exact sciences and technology</subject><subject>Indium-doped zinc oxide</subject><subject>Natural energy</subject><subject>Photovoltaic conversion</subject><subject>Solar cells. Photoelectrochemical cells</subject><subject>Solar energy</subject><subject>Thin films</subject><issn>0927-0248</issn><issn>1879-3398</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2006</creationdate><recordtype>article</recordtype><recordid>eNp9kEFr3DAQhUVpINtN_0EOurQ3OyNLa1mXQlmaNBBIDwmBXoQsj7tabMmVtIH999Gygd56mTnMe294HyHXDGoGrL3Z1ylMs8l1A7CpQdTA4ANZsU6qinPVfSQrUI2soBHdJfmU0h4AmpaLFXn5FXEx0WQXPA0jtcEPB5ud_0ONH2iOxqdyR5-p84M7zNUQFhzob_9I8855OrppTrQ_UrvD2Vkz0bREc7wiF6OZEn5-32vyfPvjafuzeni8u99-f6is4DxXyHsUaHqm2k4aDrxvoRdSWSW6Tc86MaLhCjs5KJBYZmv77tRFomklQ74mX8-5Swx_D5iynl2yOE3GYzgk3agNb0XpuibiLLQxpBRx1Et0s4lHzUCfKOq9PlPUJ4oahC4Ui-3Le75JpdxYeFiX_nnlRrVMsaL7dtZhKfvqMOpkHXqLg4tosx6C-_-jN86Rit0</recordid><startdate>20060414</startdate><enddate>20060414</enddate><creator>Lucio-López, M.A.</creator><creator>Luna-Arias, M.A.</creator><creator>Maldonado, A.</creator><creator>de la L. Olvera, M.</creator><creator>Acosta, D.R.</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7TB</scope><scope>7U5</scope><scope>8FD</scope><scope>FR3</scope><scope>L7M</scope></search><sort><creationdate>20060414</creationdate><title>Preparation of conducting and transparent indium-doped ZnO thin films by chemical spray</title><author>Lucio-López, M.A. ; Luna-Arias, M.A. ; Maldonado, A. ; de la L. Olvera, M. ; Acosta, D.R.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c433t-e3be4eab19687a303b60b479c9485b184fea39e87d907e7d96cb809277ea671e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2006</creationdate><topic>Applied sciences</topic><topic>Chemical spray</topic><topic>Energy</topic><topic>Exact sciences and technology</topic><topic>Indium-doped zinc oxide</topic><topic>Natural energy</topic><topic>Photovoltaic conversion</topic><topic>Solar cells. Photoelectrochemical cells</topic><topic>Solar energy</topic><topic>Thin films</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lucio-López, M.A.</creatorcontrib><creatorcontrib>Luna-Arias, M.A.</creatorcontrib><creatorcontrib>Maldonado, A.</creatorcontrib><creatorcontrib>de la L. Olvera, M.</creatorcontrib><creatorcontrib>Acosta, D.R.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Solar energy materials and solar cells</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lucio-López, M.A.</au><au>Luna-Arias, M.A.</au><au>Maldonado, A.</au><au>de la L. Olvera, M.</au><au>Acosta, D.R.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Preparation of conducting and transparent indium-doped ZnO thin films by chemical spray</atitle><jtitle>Solar energy materials and solar cells</jtitle><date>2006-04-14</date><risdate>2006</risdate><volume>90</volume><issue>6</issue><spage>733</spage><epage>741</epage><pages>733-741</pages><issn>0927-0248</issn><eissn>1879-3398</eissn><notes>ObjectType-Article-2</notes><notes>SourceType-Scholarly Journals-1</notes><notes>ObjectType-Feature-1</notes><notes>content type line 23</notes><abstract>Transparent conducting indium-doped zinc oxide thin films were prepared on soda-lime glass substrates by the spray pyrolysis technique. The dependence of the electrical, structural, morphological and optical properties on the preparation conditions has been studied. Two main variables, substrate temperature and molar concentration, were varied in the ranges of 425–525
°C and 0.05–0.5
M, respectively, in order to obtain films with low electrical resistivity and high optical transparency in the visible region. A minimum resistivity value around of 3×10
−3
Ω
cm was obtained for films deposited from highly concentrated starting solutions, 0.4 and 0.5
M. The values of the free-carrier concentration and the electronic mobility were estimated by Hall effect measurements. X-ray diffraction spectra evidenced a preferential orientation along the (1
0
1) direction. The surface morphology was clearly affected with the molar concentration variation, leading to a smoother appearance as the zinc concentration in the starting solution is increased. Typical optical transmittance values in the order of 85% were obtained in all the films.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/j.solmat.2005.04.010</doi><tpages>9</tpages></addata></record> |
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subjects | Applied sciences Chemical spray Energy Exact sciences and technology Indium-doped zinc oxide Natural energy Photovoltaic conversion Solar cells. Photoelectrochemical cells Solar energy Thin films |
title | Preparation of conducting and transparent indium-doped ZnO thin films by chemical spray |
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