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Influence of a selected hardener on the phase separation in epoxy/thermoplastic polymer blends
Low molecular weight thermoplastic PES : PEES (polyethersulfone : polyetherethersulfone) copolymer, bearing amine reactive end groups, was blended with a diglycidyl ether of bisphenol A (EPON828) epoxy resins. Two different curing agents, MDEA [methylene bis(2,6‐diethylaniline)] and 3,3′DDS (3,3′‐di...
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Published in: | Journal of applied polymer science 2004-10, Vol.94 (1), p.361-371 |
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description | Low molecular weight thermoplastic PES : PEES (polyethersulfone : polyetherethersulfone) copolymer, bearing amine reactive end groups, was blended with a diglycidyl ether of bisphenol A (EPON828) epoxy resins. Two different curing agents, MDEA [methylene bis(2,6‐diethylaniline)] and 3,3′DDS (3,3′‐diamino diphenyl sulfone), were used separately to compare flow behavior, curing kinetics, and morphology of the final samples. Emphasis was placed on different phase behaviors of the cured systems, attributed to different solubilities of thermoplastic in the thermoset system as well as to the reactivity of the two curing agents. The presence of PES : PEES was shown not to affect the reaction rate of epoxy blends with respect to the neat resin by the reactive nature of its end groups. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 94: 361–371, 2004 |
doi_str_mv | 10.1002/app.20927 |
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Two different curing agents, MDEA [methylene bis(2,6‐diethylaniline)] and 3,3′DDS (3,3′‐diamino diphenyl sulfone), were used separately to compare flow behavior, curing kinetics, and morphology of the final samples. Emphasis was placed on different phase behaviors of the cured systems, attributed to different solubilities of thermoplastic in the thermoset system as well as to the reactivity of the two curing agents. The presence of PES : PEES was shown not to affect the reaction rate of epoxy blends with respect to the neat resin by the reactive nature of its end groups. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 94: 361–371, 2004</description><identifier>ISSN: 0021-8995</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/app.20927</identifier><identifier>CODEN: JAPNAB</identifier><language>eng</language><publisher>Hoboken: Wiley Subscription Services, Inc., A Wiley Company</publisher><subject>Applied sciences ; differential scanning calorimetry (DSC) ; epoxy resin ; Exact sciences and technology ; interpenetrating networks (IPN) ; Physicochemistry of polymers ; Polymer industry, paints, wood ; Technology of polymers ; thermoplastics ; viscoelastic properties ; viscoelastic properties, differential scanning calorimetry (DSC)</subject><ispartof>Journal of applied polymer science, 2004-10, Vol.94 (1), p.361-371</ispartof><rights>Copyright © 2004 Wiley Periodicals, Inc.</rights><rights>2005 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4327-344488d72f3b2fc5c86a8195d33792a4858f6f9ac0f40f9e5eacb0120b4966713</citedby><cites>FETCH-LOGICAL-c4327-344488d72f3b2fc5c86a8195d33792a4858f6f9ac0f40f9e5eacb0120b4966713</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fapp.20927$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fapp.20927$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>315,786,790,27957,27958,50923,51032</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=16036941$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Blanco, I.</creatorcontrib><creatorcontrib>Cicala, G.</creatorcontrib><creatorcontrib>Motta, O.</creatorcontrib><creatorcontrib>Recca, A.</creatorcontrib><title>Influence of a selected hardener on the phase separation in epoxy/thermoplastic polymer blends</title><title>Journal of applied polymer science</title><addtitle>J. Appl. Polym. Sci</addtitle><description>Low molecular weight thermoplastic PES : PEES (polyethersulfone : polyetherethersulfone) copolymer, bearing amine reactive end groups, was blended with a diglycidyl ether of bisphenol A (EPON828) epoxy resins. Two different curing agents, MDEA [methylene bis(2,6‐diethylaniline)] and 3,3′DDS (3,3′‐diamino diphenyl sulfone), were used separately to compare flow behavior, curing kinetics, and morphology of the final samples. Emphasis was placed on different phase behaviors of the cured systems, attributed to different solubilities of thermoplastic in the thermoset system as well as to the reactivity of the two curing agents. The presence of PES : PEES was shown not to affect the reaction rate of epoxy blends with respect to the neat resin by the reactive nature of its end groups. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 94: 361–371, 2004</description><subject>Applied sciences</subject><subject>differential scanning calorimetry (DSC)</subject><subject>epoxy resin</subject><subject>Exact sciences and technology</subject><subject>interpenetrating networks (IPN)</subject><subject>Physicochemistry of polymers</subject><subject>Polymer industry, paints, wood</subject><subject>Technology of polymers</subject><subject>thermoplastics</subject><subject>viscoelastic properties</subject><subject>viscoelastic properties, differential scanning calorimetry (DSC)</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2004</creationdate><recordtype>article</recordtype><recordid>eNp1kEtv1DAUhS1EJYaWBf_AG5BYpONX_FhWFZRKLa14doV1x7nWBDyJsTOi8--bMoWuWFm65zufpUPIS86OOWNiCTkfC-aEeUIWnDnTKC3sU7KYM95Y59pn5HmtPxjjvGV6Qb6fDzFtcQhIx0iBVkwYJuzoGkqHAxY6DnRaI81rqDjHGQpM_XzsB4p5vN0t57RsxpygTn2geUy7zVxbJRy6ekQOIqSKLx7eQ_Ll3dvPp--bi6uz89OTiyYoKUwjlVLWdkZEuRIxtMFqsNy1nZTGCVC2tVFHB4FFxaLDFiGsGBdspZzWhstD8nrvzWX8tcU6-U1fA6YEA47b6oUVLXfWzOCbPRjKWGvB6HPpN1B2njN_v6CfF_R_FpzZVw9SqAFSLDCEvj4WNJPaqfvPl3vud59w93-hP7m-_mtu9o2-Tnj7rwHlp9dGmtZ_-3DmLz_xG_H144038g6uRY8D</recordid><startdate>20041005</startdate><enddate>20041005</enddate><creator>Blanco, I.</creator><creator>Cicala, G.</creator><creator>Motta, O.</creator><creator>Recca, A.</creator><general>Wiley Subscription Services, Inc., A Wiley Company</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8FD</scope><scope>H8D</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20041005</creationdate><title>Influence of a selected hardener on the phase separation in epoxy/thermoplastic polymer blends</title><author>Blanco, I. ; Cicala, G. ; Motta, O. ; Recca, A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4327-344488d72f3b2fc5c86a8195d33792a4858f6f9ac0f40f9e5eacb0120b4966713</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2004</creationdate><topic>Applied sciences</topic><topic>differential scanning calorimetry (DSC)</topic><topic>epoxy resin</topic><topic>Exact sciences and technology</topic><topic>interpenetrating networks (IPN)</topic><topic>Physicochemistry of polymers</topic><topic>Polymer industry, paints, wood</topic><topic>Technology of polymers</topic><topic>thermoplastics</topic><topic>viscoelastic properties</topic><topic>viscoelastic properties, differential scanning calorimetry (DSC)</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Blanco, I.</creatorcontrib><creatorcontrib>Cicala, G.</creatorcontrib><creatorcontrib>Motta, O.</creatorcontrib><creatorcontrib>Recca, A.</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Aerospace Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Blanco, I.</au><au>Cicala, G.</au><au>Motta, O.</au><au>Recca, A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Influence of a selected hardener on the phase separation in epoxy/thermoplastic polymer blends</atitle><jtitle>Journal of applied polymer science</jtitle><addtitle>J. Appl. Polym. Sci</addtitle><date>2004-10-05</date><risdate>2004</risdate><volume>94</volume><issue>1</issue><spage>361</spage><epage>371</epage><pages>361-371</pages><issn>0021-8995</issn><eissn>1097-4628</eissn><coden>JAPNAB</coden><notes>Ministero dell'Università e della Ricerca Scientifica e Tecnologica (MURST) of Italy</notes><notes>ArticleID:APP20927</notes><notes>ark:/67375/WNG-MS1X2VRX-7</notes><notes>istex:D9C7C8B7AB666202D9BFF95569634830D84C073E</notes><notes>ObjectType-Article-2</notes><notes>SourceType-Scholarly Journals-1</notes><notes>ObjectType-Feature-1</notes><notes>content type line 23</notes><abstract>Low molecular weight thermoplastic PES : PEES (polyethersulfone : polyetherethersulfone) copolymer, bearing amine reactive end groups, was blended with a diglycidyl ether of bisphenol A (EPON828) epoxy resins. 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subjects | Applied sciences differential scanning calorimetry (DSC) epoxy resin Exact sciences and technology interpenetrating networks (IPN) Physicochemistry of polymers Polymer industry, paints, wood Technology of polymers thermoplastics viscoelastic properties viscoelastic properties, differential scanning calorimetry (DSC) |
title | Influence of a selected hardener on the phase separation in epoxy/thermoplastic polymer blends |
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