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Liquid‐Free All‐Solid‐State Zinc Batteries and Encapsulation‐Free Flexible Batteries Enabled by In Situ Constructed Polymer Electrolyte
Zn batteries are usually considered as safe aqueous systems that are promising for flexible batteries. On the other hand, any liquids, including water, being encapsulated in a deformable battery may result in problems. Developing completely liquid‐free all‐solid‐state Zn batteries needs high‐quality...
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| Published in: | Angewandte Chemie International Edition 2020-12, Vol.59 (52), p.23836-23844 |
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| cites | cdi_FETCH-LOGICAL-c4108-3a5a374ae13392f7b1de6fc3e02d05a5eb598dcae22252ba7f2cd486101e58173 |
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| creator | Ma, Longtao Chen, Shengmei Li, Xinliang Chen, Ao Dong, Binbin Zhi, Chunyi |
| description | Zn batteries are usually considered as safe aqueous systems that are promising for flexible batteries. On the other hand, any liquids, including water, being encapsulated in a deformable battery may result in problems. Developing completely liquid‐free all‐solid‐state Zn batteries needs high‐quality solid‐state electrolytes (SSEs). Herein, we demonstrate in situ polymerized amorphous solid poly(1,3‐dioxolane) electrolytes, which show high Zn ion conductivity of 19.6 mS cm−1 at room temperature, low interfacial impedance, highly reversible Zn plating/stripping over 1800 h cycles, uniform and dendrite‐free Zn deposition, and non‐dry properties. The in‐plane interdigital‐structure device with the electrolyte completely exposed to the open atmosphere can be operated stably for over 30 days almost without weight loss or electrochemical performance decay. Furthermore, the sandwich‐structure device can normally operate over 40 min under exposure to fire. Meanwhile, the interfacial impedance and the capacity using in situ‐formed solid polymer electrolytes (SPEs) remain almost unchanged after various bending tests, a key criterion for flexible/wearable devices. Our study demonstrates an approach for SSEs that fulfill the requirement of no liquid and mechanical robustness for practical solid‐state Zn batteries.
In situ polymerized amorphous solid poly(1,3‐dioxolane) electrolytes are prepared and shown to be solid‐state electrolytes (SSEs) that fulfill the requirement of no liquid and mechanical robustness for practical solid‐state zinc batteries. The properties of the solid polymer electrolytes remain almost unchanged after various bending tests, a key criterion for flexible/wearable devices. |
| doi_str_mv | 10.1002/anie.202011788 |
| format | article |
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In situ polymerized amorphous solid poly(1,3‐dioxolane) electrolytes are prepared and shown to be solid‐state electrolytes (SSEs) that fulfill the requirement of no liquid and mechanical robustness for practical solid‐state zinc batteries. The properties of the solid polymer electrolytes remain almost unchanged after various bending tests, a key criterion for flexible/wearable devices.</description><edition>International ed. in English</edition><identifier>ISSN: 1433-7851</identifier><identifier>EISSN: 1521-3773</identifier><identifier>DOI: 10.1002/anie.202011788</identifier><identifier>PMID: 32935895</identifier><language>eng</language><publisher>Germany: Wiley Subscription Services, Inc</publisher><subject>Batteries ; Bending machines ; Dendritic structure ; Electrochemical analysis ; Electrochemistry ; Electrolytes ; Encapsulation ; Fire exposure ; flexible electronics ; Formability ; Impedance ; Molten salt electrolytes ; Polymers ; Room temperature ; Solid electrolytes ; solid-polymer electrolytes ; solid-state electrolytes ; Wearable technology ; Weight loss ; Zinc ; zinc batteries</subject><ispartof>Angewandte Chemie International Edition, 2020-12, Vol.59 (52), p.23836-23844</ispartof><rights>2020 Wiley‐VCH GmbH</rights><rights>2020 Wiley-VCH GmbH.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4108-3a5a374ae13392f7b1de6fc3e02d05a5eb598dcae22252ba7f2cd486101e58173</citedby><cites>FETCH-LOGICAL-c4108-3a5a374ae13392f7b1de6fc3e02d05a5eb598dcae22252ba7f2cd486101e58173</cites><orcidid>0000-0001-6766-5953 ; 0000-0002-2942-3221</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fanie.202011788$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fanie.202011788$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>315,786,790,27957,27958,50923,51032</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/32935895$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Ma, Longtao</creatorcontrib><creatorcontrib>Chen, Shengmei</creatorcontrib><creatorcontrib>Li, Xinliang</creatorcontrib><creatorcontrib>Chen, Ao</creatorcontrib><creatorcontrib>Dong, Binbin</creatorcontrib><creatorcontrib>Zhi, Chunyi</creatorcontrib><title>Liquid‐Free All‐Solid‐State Zinc Batteries and Encapsulation‐Free Flexible Batteries Enabled by In Situ Constructed Polymer Electrolyte</title><title>Angewandte Chemie International Edition</title><addtitle>Angew Chem Int Ed Engl</addtitle><description>Zn batteries are usually considered as safe aqueous systems that are promising for flexible batteries. On the other hand, any liquids, including water, being encapsulated in a deformable battery may result in problems. Developing completely liquid‐free all‐solid‐state Zn batteries needs high‐quality solid‐state electrolytes (SSEs). Herein, we demonstrate in situ polymerized amorphous solid poly(1,3‐dioxolane) electrolytes, which show high Zn ion conductivity of 19.6 mS cm−1 at room temperature, low interfacial impedance, highly reversible Zn plating/stripping over 1800 h cycles, uniform and dendrite‐free Zn deposition, and non‐dry properties. The in‐plane interdigital‐structure device with the electrolyte completely exposed to the open atmosphere can be operated stably for over 30 days almost without weight loss or electrochemical performance decay. Furthermore, the sandwich‐structure device can normally operate over 40 min under exposure to fire. Meanwhile, the interfacial impedance and the capacity using in situ‐formed solid polymer electrolytes (SPEs) remain almost unchanged after various bending tests, a key criterion for flexible/wearable devices. Our study demonstrates an approach for SSEs that fulfill the requirement of no liquid and mechanical robustness for practical solid‐state Zn batteries.
In situ polymerized amorphous solid poly(1,3‐dioxolane) electrolytes are prepared and shown to be solid‐state electrolytes (SSEs) that fulfill the requirement of no liquid and mechanical robustness for practical solid‐state zinc batteries. The properties of the solid polymer electrolytes remain almost unchanged after various bending tests, a key criterion for flexible/wearable devices.</description><subject>Batteries</subject><subject>Bending machines</subject><subject>Dendritic structure</subject><subject>Electrochemical analysis</subject><subject>Electrochemistry</subject><subject>Electrolytes</subject><subject>Encapsulation</subject><subject>Fire exposure</subject><subject>flexible electronics</subject><subject>Formability</subject><subject>Impedance</subject><subject>Molten salt electrolytes</subject><subject>Polymers</subject><subject>Room temperature</subject><subject>Solid electrolytes</subject><subject>solid-polymer electrolytes</subject><subject>solid-state electrolytes</subject><subject>Wearable technology</subject><subject>Weight loss</subject><subject>Zinc</subject><subject>zinc batteries</subject><issn>1433-7851</issn><issn>1521-3773</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNqF0T1vFDEQBmArAiUhpE2JLNHQ7OGP9dpbHqc9OOkEkQ4ampXXOys58nkvtldwHQ09_EV-CQ6XL9Gk8nj8zCtLg9AFJTNKCHurvYUZI4xQKpU6QqdUMFpwKfmzXJecF1IJeoJexHiVvVKkOkYnnNVcqFqcot9rez3Z_s-PX8sAgOfO5XIzun-tTdIJ8FfrDX6nU4JgIWLte9x4o3dxcjrZ0d_NLh18t52DR7bxOjd63O3xKrufG5smvBh9TGEyKT9cjm6_hYAbByaFfEnwEj0ftItwfnueoS_L5vPiQ7H-9H61mK8LU1KiCq6F5rLUQDmv2SA72kM1GA6E9URoAZ2oVW80MMYE67QcmOlLVVFCQSgq-Rl6c8jdhfF6gpjarY0GnNMexim2rCy5oLUUVaav_6NX4xR8_l1WVa3Kkgie1eygTBhjDDC0u2C3OuxbStqbZbU3y2rvl5UHXt3GTt0W-nt-t50M6gP4Zh3sn4hr5x9XzUP4XxHZpt4</recordid><startdate>20201221</startdate><enddate>20201221</enddate><creator>Ma, Longtao</creator><creator>Chen, Shengmei</creator><creator>Li, Xinliang</creator><creator>Chen, Ao</creator><creator>Dong, Binbin</creator><creator>Zhi, Chunyi</creator><general>Wiley Subscription Services, Inc</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7TM</scope><scope>K9.</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0001-6766-5953</orcidid><orcidid>https://orcid.org/0000-0002-2942-3221</orcidid></search><sort><creationdate>20201221</creationdate><title>Liquid‐Free All‐Solid‐State Zinc Batteries and Encapsulation‐Free Flexible Batteries Enabled by In Situ Constructed Polymer Electrolyte</title><author>Ma, Longtao ; Chen, Shengmei ; Li, Xinliang ; Chen, Ao ; Dong, Binbin ; Zhi, Chunyi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4108-3a5a374ae13392f7b1de6fc3e02d05a5eb598dcae22252ba7f2cd486101e58173</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Batteries</topic><topic>Bending machines</topic><topic>Dendritic structure</topic><topic>Electrochemical analysis</topic><topic>Electrochemistry</topic><topic>Electrolytes</topic><topic>Encapsulation</topic><topic>Fire exposure</topic><topic>flexible electronics</topic><topic>Formability</topic><topic>Impedance</topic><topic>Molten salt electrolytes</topic><topic>Polymers</topic><topic>Room temperature</topic><topic>Solid electrolytes</topic><topic>solid-polymer electrolytes</topic><topic>solid-state electrolytes</topic><topic>Wearable technology</topic><topic>Weight loss</topic><topic>Zinc</topic><topic>zinc batteries</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ma, Longtao</creatorcontrib><creatorcontrib>Chen, Shengmei</creatorcontrib><creatorcontrib>Li, Xinliang</creatorcontrib><creatorcontrib>Chen, Ao</creatorcontrib><creatorcontrib>Dong, Binbin</creatorcontrib><creatorcontrib>Zhi, Chunyi</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Nucleic Acids Abstracts</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><jtitle>Angewandte Chemie International Edition</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ma, Longtao</au><au>Chen, Shengmei</au><au>Li, Xinliang</au><au>Chen, Ao</au><au>Dong, Binbin</au><au>Zhi, Chunyi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Liquid‐Free All‐Solid‐State Zinc Batteries and Encapsulation‐Free Flexible Batteries Enabled by In Situ Constructed Polymer Electrolyte</atitle><jtitle>Angewandte Chemie International Edition</jtitle><addtitle>Angew Chem Int Ed Engl</addtitle><date>2020-12-21</date><risdate>2020</risdate><volume>59</volume><issue>52</issue><spage>23836</spage><epage>23844</epage><pages>23836-23844</pages><issn>1433-7851</issn><eissn>1521-3773</eissn><notes>ObjectType-Article-1</notes><notes>SourceType-Scholarly Journals-1</notes><notes>ObjectType-Feature-2</notes><notes>content type line 23</notes><abstract>Zn batteries are usually considered as safe aqueous systems that are promising for flexible batteries. On the other hand, any liquids, including water, being encapsulated in a deformable battery may result in problems. Developing completely liquid‐free all‐solid‐state Zn batteries needs high‐quality solid‐state electrolytes (SSEs). Herein, we demonstrate in situ polymerized amorphous solid poly(1,3‐dioxolane) electrolytes, which show high Zn ion conductivity of 19.6 mS cm−1 at room temperature, low interfacial impedance, highly reversible Zn plating/stripping over 1800 h cycles, uniform and dendrite‐free Zn deposition, and non‐dry properties. The in‐plane interdigital‐structure device with the electrolyte completely exposed to the open atmosphere can be operated stably for over 30 days almost without weight loss or electrochemical performance decay. Furthermore, the sandwich‐structure device can normally operate over 40 min under exposure to fire. Meanwhile, the interfacial impedance and the capacity using in situ‐formed solid polymer electrolytes (SPEs) remain almost unchanged after various bending tests, a key criterion for flexible/wearable devices. Our study demonstrates an approach for SSEs that fulfill the requirement of no liquid and mechanical robustness for practical solid‐state Zn batteries.
In situ polymerized amorphous solid poly(1,3‐dioxolane) electrolytes are prepared and shown to be solid‐state electrolytes (SSEs) that fulfill the requirement of no liquid and mechanical robustness for practical solid‐state zinc batteries. The properties of the solid polymer electrolytes remain almost unchanged after various bending tests, a key criterion for flexible/wearable devices.</abstract><cop>Germany</cop><pub>Wiley Subscription Services, Inc</pub><pmid>32935895</pmid><doi>10.1002/anie.202011788</doi><tpages>9</tpages><edition>International ed. in English</edition><orcidid>https://orcid.org/0000-0001-6766-5953</orcidid><orcidid>https://orcid.org/0000-0002-2942-3221</orcidid></addata></record> |
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| ispartof | Angewandte Chemie International Edition, 2020-12, Vol.59 (52), p.23836-23844 |
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| subjects | Batteries Bending machines Dendritic structure Electrochemical analysis Electrochemistry Electrolytes Encapsulation Fire exposure flexible electronics Formability Impedance Molten salt electrolytes Polymers Room temperature Solid electrolytes solid-polymer electrolytes solid-state electrolytes Wearable technology Weight loss Zinc zinc batteries |
| title | Liquid‐Free All‐Solid‐State Zinc Batteries and Encapsulation‐Free Flexible Batteries Enabled by In Situ Constructed Polymer Electrolyte |
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