Loading…
Fabrication of CdS Frame‐in‐Cage Particles for Efficient Photocatalytic Hydrogen Generation under Visible‐Light Irradiation
The design of advanced structures for semiconductor photocatalysts is an effective approach to enhance their performance toward solar‐to‐chemical energy conversion. Hollow and frame‐like structures show advantageous features for photocatalytic reactions with enlarged surface area, shortened charge‐t...
Saved in:
Published in: | Advanced materials (Weinheim) 2020-10, Vol.32 (39), p.e2004561-n/a |
---|---|
Main Authors: | , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
cited_by | cdi_FETCH-LOGICAL-c3871-d8d863ec81aebd4e28a76831230c344e2bbec1255960bc163b32c32601e6e06d3 |
---|---|
cites | cdi_FETCH-LOGICAL-c3871-d8d863ec81aebd4e28a76831230c344e2bbec1255960bc163b32c32601e6e06d3 |
container_end_page | n/a |
container_issue | 39 |
container_start_page | e2004561 |
container_title | Advanced materials (Weinheim) |
container_volume | 32 |
creator | Zhang, Peng Luan, Deyan Lou, Xiong Wen (David) |
description | The design of advanced structures for semiconductor photocatalysts is an effective approach to enhance their performance toward solar‐to‐chemical energy conversion. Hollow and frame‐like structures show advantageous features for photocatalytic reactions with enlarged surface area, shortened charge‐transfer distance, promoted light‐absorption ability, and enhanced mass‐transfer capability. Here, a facile two‐step sulfidation strategy is developed to fabricate unique CdS frame‐in‐cage particles for photocatalytic hydrogen generation. Cd‐based Prussian blue analog (Cd‐PBA) cubes are first converted to Cd‐PBA cube‐in‐CdS cage particles, which are further transformed to CdS frame‐in‐cage particles. Benefiting from the novel frame‐in‐cage structure, the obtained CdS photocatalyst exhibits high activity under visible‐light irradiation with the hydrogen generation rate of 13.6 mmol h−1 g−1, which is much enhanced compared with those of the CdS cubes and cages.
CdS frame‐in‐cage particles are fabricated through a two‐step sulfidation approach. With the advantages of the novel hollow structure, the CdS frame‐in‐cage particles exhibit enhanced photocatalytic activity toward H2 generation compared with CdS cubes and cages. |
doi_str_mv | 10.1002/adma.202004561 |
format | article |
fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_2435756609</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2447490565</sourcerecordid><originalsourceid>FETCH-LOGICAL-c3871-d8d863ec81aebd4e28a76831230c344e2bbec1255960bc163b32c32601e6e06d3</originalsourceid><addsrcrecordid>eNqFkc9qGzEQxkVJoY7Ta8-CXnJZdySt5N2jcWIn4BBD_1wXrTTrKKxXjrQm7K19gzxjnqRyXBrIJZcZBv2-j9F8hHxhMGEA_Ju2Wz3hwAFyqdgHMmKSsyyHUp6QEZRCZqXKi0_kNMZ7ACgVqBH5s9B1cEb3znfUN3Ruv9NF0Ft8_v3kulTmeoN0rUPvTIuRNj7Qy6ZxxmHX0_Wd730S63ZI7_RqsMFvsKNL7DAcPfedxUB_uejq9mC6cpu7nl6HoK17Ic7Ix0a3ET__62Pyc3H5Y36VrW6X1_PZKjOimLLMFrZQAk3BNNY2R17oqSoE4wKMyNNc12gYlzL9qzZMiVpwI7gChgpBWTEm50ffXfAPe4x9tXXRYNvqDv0-VjwXciqVSpcak69v0Hu_D13aLlH5NC9BKpmoyZEywccYsKl2wW11GCoG1SGR6pBI9T-RJCiPgkfX4vAOXc0ubmav2r9NzZL1</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2447490565</pqid></control><display><type>article</type><title>Fabrication of CdS Frame‐in‐Cage Particles for Efficient Photocatalytic Hydrogen Generation under Visible‐Light Irradiation</title><source>Wiley-Blackwell Journals</source><creator>Zhang, Peng ; Luan, Deyan ; Lou, Xiong Wen (David)</creator><creatorcontrib>Zhang, Peng ; Luan, Deyan ; Lou, Xiong Wen (David)</creatorcontrib><description>The design of advanced structures for semiconductor photocatalysts is an effective approach to enhance their performance toward solar‐to‐chemical energy conversion. Hollow and frame‐like structures show advantageous features for photocatalytic reactions with enlarged surface area, shortened charge‐transfer distance, promoted light‐absorption ability, and enhanced mass‐transfer capability. Here, a facile two‐step sulfidation strategy is developed to fabricate unique CdS frame‐in‐cage particles for photocatalytic hydrogen generation. Cd‐based Prussian blue analog (Cd‐PBA) cubes are first converted to Cd‐PBA cube‐in‐CdS cage particles, which are further transformed to CdS frame‐in‐cage particles. Benefiting from the novel frame‐in‐cage structure, the obtained CdS photocatalyst exhibits high activity under visible‐light irradiation with the hydrogen generation rate of 13.6 mmol h−1 g−1, which is much enhanced compared with those of the CdS cubes and cages.
CdS frame‐in‐cage particles are fabricated through a two‐step sulfidation approach. With the advantages of the novel hollow structure, the CdS frame‐in‐cage particles exhibit enhanced photocatalytic activity toward H2 generation compared with CdS cubes and cages.</description><identifier>ISSN: 0935-9648</identifier><identifier>EISSN: 1521-4095</identifier><identifier>DOI: 10.1002/adma.202004561</identifier><language>eng</language><publisher>Weinheim: Wiley Subscription Services, Inc</publisher><subject>Cages ; CdS ; Charge transfer ; Chemical energy ; Cubes ; Energy conversion ; frames ; H 2 generation ; Hydrogen production ; Light irradiation ; Materials science ; Photocatalysis ; Photocatalysts ; Pigments ; Prussian blue analogs ; Sulfidation</subject><ispartof>Advanced materials (Weinheim), 2020-10, Vol.32 (39), p.e2004561-n/a</ispartof><rights>2020 Wiley‐VCH GmbH</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3871-d8d863ec81aebd4e28a76831230c344e2bbec1255960bc163b32c32601e6e06d3</citedby><cites>FETCH-LOGICAL-c3871-d8d863ec81aebd4e28a76831230c344e2bbec1255960bc163b32c32601e6e06d3</cites><orcidid>0000-0002-5557-4437</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fadma.202004561$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fadma.202004561$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>315,786,790,27957,27958,50923,51032</link.rule.ids></links><search><creatorcontrib>Zhang, Peng</creatorcontrib><creatorcontrib>Luan, Deyan</creatorcontrib><creatorcontrib>Lou, Xiong Wen (David)</creatorcontrib><title>Fabrication of CdS Frame‐in‐Cage Particles for Efficient Photocatalytic Hydrogen Generation under Visible‐Light Irradiation</title><title>Advanced materials (Weinheim)</title><description>The design of advanced structures for semiconductor photocatalysts is an effective approach to enhance their performance toward solar‐to‐chemical energy conversion. Hollow and frame‐like structures show advantageous features for photocatalytic reactions with enlarged surface area, shortened charge‐transfer distance, promoted light‐absorption ability, and enhanced mass‐transfer capability. Here, a facile two‐step sulfidation strategy is developed to fabricate unique CdS frame‐in‐cage particles for photocatalytic hydrogen generation. Cd‐based Prussian blue analog (Cd‐PBA) cubes are first converted to Cd‐PBA cube‐in‐CdS cage particles, which are further transformed to CdS frame‐in‐cage particles. Benefiting from the novel frame‐in‐cage structure, the obtained CdS photocatalyst exhibits high activity under visible‐light irradiation with the hydrogen generation rate of 13.6 mmol h−1 g−1, which is much enhanced compared with those of the CdS cubes and cages.
CdS frame‐in‐cage particles are fabricated through a two‐step sulfidation approach. With the advantages of the novel hollow structure, the CdS frame‐in‐cage particles exhibit enhanced photocatalytic activity toward H2 generation compared with CdS cubes and cages.</description><subject>Cages</subject><subject>CdS</subject><subject>Charge transfer</subject><subject>Chemical energy</subject><subject>Cubes</subject><subject>Energy conversion</subject><subject>frames</subject><subject>H 2 generation</subject><subject>Hydrogen production</subject><subject>Light irradiation</subject><subject>Materials science</subject><subject>Photocatalysis</subject><subject>Photocatalysts</subject><subject>Pigments</subject><subject>Prussian blue analogs</subject><subject>Sulfidation</subject><issn>0935-9648</issn><issn>1521-4095</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNqFkc9qGzEQxkVJoY7Ta8-CXnJZdySt5N2jcWIn4BBD_1wXrTTrKKxXjrQm7K19gzxjnqRyXBrIJZcZBv2-j9F8hHxhMGEA_Ju2Wz3hwAFyqdgHMmKSsyyHUp6QEZRCZqXKi0_kNMZ7ACgVqBH5s9B1cEb3znfUN3Ruv9NF0Ft8_v3kulTmeoN0rUPvTIuRNj7Qy6ZxxmHX0_Wd730S63ZI7_RqsMFvsKNL7DAcPfedxUB_uejq9mC6cpu7nl6HoK17Ic7Ix0a3ET__62Pyc3H5Y36VrW6X1_PZKjOimLLMFrZQAk3BNNY2R17oqSoE4wKMyNNc12gYlzL9qzZMiVpwI7gChgpBWTEm50ffXfAPe4x9tXXRYNvqDv0-VjwXciqVSpcak69v0Hu_D13aLlH5NC9BKpmoyZEywccYsKl2wW11GCoG1SGR6pBI9T-RJCiPgkfX4vAOXc0ubmav2r9NzZL1</recordid><startdate>20201001</startdate><enddate>20201001</enddate><creator>Zhang, Peng</creator><creator>Luan, Deyan</creator><creator>Lou, Xiong Wen (David)</creator><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-5557-4437</orcidid></search><sort><creationdate>20201001</creationdate><title>Fabrication of CdS Frame‐in‐Cage Particles for Efficient Photocatalytic Hydrogen Generation under Visible‐Light Irradiation</title><author>Zhang, Peng ; Luan, Deyan ; Lou, Xiong Wen (David)</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3871-d8d863ec81aebd4e28a76831230c344e2bbec1255960bc163b32c32601e6e06d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Cages</topic><topic>CdS</topic><topic>Charge transfer</topic><topic>Chemical energy</topic><topic>Cubes</topic><topic>Energy conversion</topic><topic>frames</topic><topic>H 2 generation</topic><topic>Hydrogen production</topic><topic>Light irradiation</topic><topic>Materials science</topic><topic>Photocatalysis</topic><topic>Photocatalysts</topic><topic>Pigments</topic><topic>Prussian blue analogs</topic><topic>Sulfidation</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhang, Peng</creatorcontrib><creatorcontrib>Luan, Deyan</creatorcontrib><creatorcontrib>Lou, Xiong Wen (David)</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>MEDLINE - Academic</collection><jtitle>Advanced materials (Weinheim)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhang, Peng</au><au>Luan, Deyan</au><au>Lou, Xiong Wen (David)</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Fabrication of CdS Frame‐in‐Cage Particles for Efficient Photocatalytic Hydrogen Generation under Visible‐Light Irradiation</atitle><jtitle>Advanced materials (Weinheim)</jtitle><date>2020-10-01</date><risdate>2020</risdate><volume>32</volume><issue>39</issue><spage>e2004561</spage><epage>n/a</epage><pages>e2004561-n/a</pages><issn>0935-9648</issn><eissn>1521-4095</eissn><notes>ObjectType-Article-1</notes><notes>SourceType-Scholarly Journals-1</notes><notes>ObjectType-Feature-2</notes><notes>content type line 23</notes><abstract>The design of advanced structures for semiconductor photocatalysts is an effective approach to enhance their performance toward solar‐to‐chemical energy conversion. Hollow and frame‐like structures show advantageous features for photocatalytic reactions with enlarged surface area, shortened charge‐transfer distance, promoted light‐absorption ability, and enhanced mass‐transfer capability. Here, a facile two‐step sulfidation strategy is developed to fabricate unique CdS frame‐in‐cage particles for photocatalytic hydrogen generation. Cd‐based Prussian blue analog (Cd‐PBA) cubes are first converted to Cd‐PBA cube‐in‐CdS cage particles, which are further transformed to CdS frame‐in‐cage particles. Benefiting from the novel frame‐in‐cage structure, the obtained CdS photocatalyst exhibits high activity under visible‐light irradiation with the hydrogen generation rate of 13.6 mmol h−1 g−1, which is much enhanced compared with those of the CdS cubes and cages.
CdS frame‐in‐cage particles are fabricated through a two‐step sulfidation approach. With the advantages of the novel hollow structure, the CdS frame‐in‐cage particles exhibit enhanced photocatalytic activity toward H2 generation compared with CdS cubes and cages.</abstract><cop>Weinheim</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/adma.202004561</doi><tpages>6</tpages><orcidid>https://orcid.org/0000-0002-5557-4437</orcidid></addata></record> |
fulltext | fulltext |
identifier | ISSN: 0935-9648 |
ispartof | Advanced materials (Weinheim), 2020-10, Vol.32 (39), p.e2004561-n/a |
issn | 0935-9648 1521-4095 |
language | eng |
recordid | cdi_proquest_miscellaneous_2435756609 |
source | Wiley-Blackwell Journals |
subjects | Cages CdS Charge transfer Chemical energy Cubes Energy conversion frames H 2 generation Hydrogen production Light irradiation Materials science Photocatalysis Photocatalysts Pigments Prussian blue analogs Sulfidation |
title | Fabrication of CdS Frame‐in‐Cage Particles for Efficient Photocatalytic Hydrogen Generation under Visible‐Light Irradiation |
url | http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-09-21T03%3A03%3A08IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Fabrication%20of%20CdS%20Frame%E2%80%90in%E2%80%90Cage%20Particles%20for%20Efficient%20Photocatalytic%20Hydrogen%20Generation%20under%20Visible%E2%80%90Light%20Irradiation&rft.jtitle=Advanced%20materials%20(Weinheim)&rft.au=Zhang,%20Peng&rft.date=2020-10-01&rft.volume=32&rft.issue=39&rft.spage=e2004561&rft.epage=n/a&rft.pages=e2004561-n/a&rft.issn=0935-9648&rft.eissn=1521-4095&rft_id=info:doi/10.1002/adma.202004561&rft_dat=%3Cproquest_cross%3E2447490565%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c3871-d8d863ec81aebd4e28a76831230c344e2bbec1255960bc163b32c32601e6e06d3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=2447490565&rft_id=info:pmid/&rfr_iscdi=true |