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Design Strategy Towards Horizontally Oriented Luminescent Tetradentate‐Ligand‐Containing Gold(III) Systems
Phosphorescent dopants are promising candidates for organic light‐emitting diodes (OLEDs). Although it has been established that the out‐coupling efficiency and overall performances of vacuum‐deposited OLEDs can be significantly improved by a horizontal orientation of the dopants, no horizontally or...
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Published in: | Angewandte Chemie International Edition 2020-11, Vol.59 (47), p.21023-21031 |
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description | Phosphorescent dopants are promising candidates for organic light‐emitting diodes (OLEDs). Although it has been established that the out‐coupling efficiency and overall performances of vacuum‐deposited OLEDs can be significantly improved by a horizontal orientation of the dopants, no horizontally oriented gold(III) complexes have been reported to date. Herein, a novel class of tetradentate C^C^N^N ligand‐containing gold(III) complexes with a preferential horizontal orientation successfully generated through a one‐pot reaction is reported. These complexes demonstrate high photoluminescence quantum yields of 70 % and a high horizontal dipole ratio of 0.87 in solid‐state thin films. Green‐emitting OLEDs based on these complexes operate with a maximum external quantum efficiency of 20.6 % with an estimated out‐coupling efficiency of around 30 %. A promising device stability has been achieved in the vacuum‐deposited OLEDs, with operational half‐lifetimes of around 37 500 h at 100 cd m−2.
A novel class of tetradentate C^C^N^N ligand‐containing gold(III) complexes with a preferential horizontal orientation has been obtained through a one‐pot reaction. A high maximum external quantum efficiency of 20.6 % has been realized in the vacuum‐deposited gold(III)‐based OLEDs, with operational half‐lifetimes of around 37 500 h at 100 cd m−2. |
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A novel class of tetradentate C^C^N^N ligand‐containing gold(III) complexes with a preferential horizontal orientation has been obtained through a one‐pot reaction. A high maximum external quantum efficiency of 20.6 % has been realized in the vacuum‐deposited gold(III)‐based OLEDs, with operational half‐lifetimes of around 37 500 h at 100 cd m−2.</description><edition>International ed. in English</edition><identifier>ISSN: 1433-7851</identifier><identifier>EISSN: 1521-3773</identifier><identifier>DOI: 10.1002/anie.202006911</identifier><language>eng</language><publisher>Weinheim: Wiley Subscription Services, Inc</publisher><subject>Coordination compounds ; Coupling ; Dipoles ; Dopants ; Efficiency ; Gold ; Horizontal orientation ; Ligands ; luminescence ; nitrogen heterocycles ; operational stability ; Organic light emitting diodes ; organic light-emitting devices ; Phosphorescence ; Photoluminescence ; Photons ; Quantum efficiency ; Thin films ; Vacuum</subject><ispartof>Angewandte Chemie International Edition, 2020-11, Vol.59 (47), p.21023-21031</ispartof><rights>2020 Wiley‐VCH GmbH</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3871-27a56d37d023baa9edb2ba44313761a376448dcbf073570e3d9ac555d96234593</citedby><cites>FETCH-LOGICAL-c3871-27a56d37d023baa9edb2ba44313761a376448dcbf073570e3d9ac555d96234593</cites><orcidid>0000-0003-1965-9908 ; 0000-0001-7472-2645 ; 0000-0003-3435-3616 ; 0000-0002-6118-702X ; 0000-0002-0656-3002 ; 0000-0001-9334-9348 ; 0000-0001-8349-4429 ; 0000-0001-6849-317X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fanie.202006911$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fanie.202006911$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>315,786,790,27957,27958,50923,51032</link.rule.ids></links><search><creatorcontrib>Tang, Man‐Chung</creatorcontrib><creatorcontrib>Li, Lok‐Kwan</creatorcontrib><creatorcontrib>Lai, Shiu‐Lun</creatorcontrib><creatorcontrib>Cheung, Wai‐Lung</creatorcontrib><creatorcontrib>Ng, Maggie</creatorcontrib><creatorcontrib>Wong, Chun‐Yin</creatorcontrib><creatorcontrib>Chan, Mei‐Yee</creatorcontrib><creatorcontrib>Yam, Vivian Wing‐Wah</creatorcontrib><title>Design Strategy Towards Horizontally Oriented Luminescent Tetradentate‐Ligand‐Containing Gold(III) Systems</title><title>Angewandte Chemie International Edition</title><description>Phosphorescent dopants are promising candidates for organic light‐emitting diodes (OLEDs). Although it has been established that the out‐coupling efficiency and overall performances of vacuum‐deposited OLEDs can be significantly improved by a horizontal orientation of the dopants, no horizontally oriented gold(III) complexes have been reported to date. Herein, a novel class of tetradentate C^C^N^N ligand‐containing gold(III) complexes with a preferential horizontal orientation successfully generated through a one‐pot reaction is reported. These complexes demonstrate high photoluminescence quantum yields of 70 % and a high horizontal dipole ratio of 0.87 in solid‐state thin films. Green‐emitting OLEDs based on these complexes operate with a maximum external quantum efficiency of 20.6 % with an estimated out‐coupling efficiency of around 30 %. A promising device stability has been achieved in the vacuum‐deposited OLEDs, with operational half‐lifetimes of around 37 500 h at 100 cd m−2.
A novel class of tetradentate C^C^N^N ligand‐containing gold(III) complexes with a preferential horizontal orientation has been obtained through a one‐pot reaction. A high maximum external quantum efficiency of 20.6 % has been realized in the vacuum‐deposited gold(III)‐based OLEDs, with operational half‐lifetimes of around 37 500 h at 100 cd m−2.</description><subject>Coordination compounds</subject><subject>Coupling</subject><subject>Dipoles</subject><subject>Dopants</subject><subject>Efficiency</subject><subject>Gold</subject><subject>Horizontal orientation</subject><subject>Ligands</subject><subject>luminescence</subject><subject>nitrogen heterocycles</subject><subject>operational stability</subject><subject>Organic light emitting diodes</subject><subject>organic light-emitting devices</subject><subject>Phosphorescence</subject><subject>Photoluminescence</subject><subject>Photons</subject><subject>Quantum efficiency</subject><subject>Thin films</subject><subject>Vacuum</subject><issn>1433-7851</issn><issn>1521-3773</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNqFkE9LwzAYh4MoOKdXzwUv89CZv017HHNuheIOm-eSNlnJaNOZdIx68iP4Gf0kZkwUvHh58ws8z8vLD4BbBMcIQvwgjFZjDDGEUYLQGRgghlFIOCfnPlNCQh4zdAmunNt6Po5hNADmUTldmWDVWdGpqg_W7UFY6YJFa_VbazpR132wtFqZTskg2zfaKFf6X7BW3pE-efHz_SPTlTDSh-nR0kabKpi3tRylaXofrHrXqcZdg4uNqJ26-X6H4OVptp4uwmw5T6eTLCxJzFGIuWCRJFxCTAohEiULXAhKCSI8QsIPSmNZFhvICeNQEZmIkjEmkwgTyhIyBKPT3p1tX_fKdXmj_dV1LYxq9y7HlMCIIxJDj979Qbft3hp_nadYzCllEHlqfKJK2zpn1SbfWd0I2-cI5sf682P9-U_9XkhOwkHXqv-HzifP6ezX_QIHpIsx</recordid><startdate>20201116</startdate><enddate>20201116</enddate><creator>Tang, Man‐Chung</creator><creator>Li, Lok‐Kwan</creator><creator>Lai, Shiu‐Lun</creator><creator>Cheung, Wai‐Lung</creator><creator>Ng, Maggie</creator><creator>Wong, Chun‐Yin</creator><creator>Chan, Mei‐Yee</creator><creator>Yam, Vivian Wing‐Wah</creator><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7TM</scope><scope>K9.</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0003-1965-9908</orcidid><orcidid>https://orcid.org/0000-0001-7472-2645</orcidid><orcidid>https://orcid.org/0000-0003-3435-3616</orcidid><orcidid>https://orcid.org/0000-0002-6118-702X</orcidid><orcidid>https://orcid.org/0000-0002-0656-3002</orcidid><orcidid>https://orcid.org/0000-0001-9334-9348</orcidid><orcidid>https://orcid.org/0000-0001-8349-4429</orcidid><orcidid>https://orcid.org/0000-0001-6849-317X</orcidid></search><sort><creationdate>20201116</creationdate><title>Design Strategy Towards Horizontally Oriented Luminescent Tetradentate‐Ligand‐Containing Gold(III) Systems</title><author>Tang, Man‐Chung ; Li, Lok‐Kwan ; Lai, Shiu‐Lun ; Cheung, Wai‐Lung ; Ng, Maggie ; Wong, Chun‐Yin ; Chan, Mei‐Yee ; Yam, Vivian Wing‐Wah</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3871-27a56d37d023baa9edb2ba44313761a376448dcbf073570e3d9ac555d96234593</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Coordination compounds</topic><topic>Coupling</topic><topic>Dipoles</topic><topic>Dopants</topic><topic>Efficiency</topic><topic>Gold</topic><topic>Horizontal orientation</topic><topic>Ligands</topic><topic>luminescence</topic><topic>nitrogen heterocycles</topic><topic>operational stability</topic><topic>Organic light emitting diodes</topic><topic>organic light-emitting devices</topic><topic>Phosphorescence</topic><topic>Photoluminescence</topic><topic>Photons</topic><topic>Quantum efficiency</topic><topic>Thin films</topic><topic>Vacuum</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Tang, Man‐Chung</creatorcontrib><creatorcontrib>Li, Lok‐Kwan</creatorcontrib><creatorcontrib>Lai, Shiu‐Lun</creatorcontrib><creatorcontrib>Cheung, Wai‐Lung</creatorcontrib><creatorcontrib>Ng, Maggie</creatorcontrib><creatorcontrib>Wong, Chun‐Yin</creatorcontrib><creatorcontrib>Chan, Mei‐Yee</creatorcontrib><creatorcontrib>Yam, Vivian Wing‐Wah</creatorcontrib><collection>CrossRef</collection><collection>Nucleic Acids Abstracts</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><jtitle>Angewandte Chemie International Edition</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Tang, Man‐Chung</au><au>Li, Lok‐Kwan</au><au>Lai, Shiu‐Lun</au><au>Cheung, Wai‐Lung</au><au>Ng, Maggie</au><au>Wong, Chun‐Yin</au><au>Chan, Mei‐Yee</au><au>Yam, Vivian Wing‐Wah</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Design Strategy Towards Horizontally Oriented Luminescent Tetradentate‐Ligand‐Containing Gold(III) Systems</atitle><jtitle>Angewandte Chemie International Edition</jtitle><date>2020-11-16</date><risdate>2020</risdate><volume>59</volume><issue>47</issue><spage>21023</spage><epage>21031</epage><pages>21023-21031</pages><issn>1433-7851</issn><eissn>1521-3773</eissn><notes>These authors contributed equally to this work.</notes><notes>ObjectType-Article-1</notes><notes>SourceType-Scholarly Journals-1</notes><notes>ObjectType-Feature-2</notes><notes>content type line 23</notes><abstract>Phosphorescent dopants are promising candidates for organic light‐emitting diodes (OLEDs). Although it has been established that the out‐coupling efficiency and overall performances of vacuum‐deposited OLEDs can be significantly improved by a horizontal orientation of the dopants, no horizontally oriented gold(III) complexes have been reported to date. Herein, a novel class of tetradentate C^C^N^N ligand‐containing gold(III) complexes with a preferential horizontal orientation successfully generated through a one‐pot reaction is reported. These complexes demonstrate high photoluminescence quantum yields of 70 % and a high horizontal dipole ratio of 0.87 in solid‐state thin films. Green‐emitting OLEDs based on these complexes operate with a maximum external quantum efficiency of 20.6 % with an estimated out‐coupling efficiency of around 30 %. A promising device stability has been achieved in the vacuum‐deposited OLEDs, with operational half‐lifetimes of around 37 500 h at 100 cd m−2.
A novel class of tetradentate C^C^N^N ligand‐containing gold(III) complexes with a preferential horizontal orientation has been obtained through a one‐pot reaction. A high maximum external quantum efficiency of 20.6 % has been realized in the vacuum‐deposited gold(III)‐based OLEDs, with operational half‐lifetimes of around 37 500 h at 100 cd m−2.</abstract><cop>Weinheim</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/anie.202006911</doi><tpages>9</tpages><edition>International ed. in English</edition><orcidid>https://orcid.org/0000-0003-1965-9908</orcidid><orcidid>https://orcid.org/0000-0001-7472-2645</orcidid><orcidid>https://orcid.org/0000-0003-3435-3616</orcidid><orcidid>https://orcid.org/0000-0002-6118-702X</orcidid><orcidid>https://orcid.org/0000-0002-0656-3002</orcidid><orcidid>https://orcid.org/0000-0001-9334-9348</orcidid><orcidid>https://orcid.org/0000-0001-8349-4429</orcidid><orcidid>https://orcid.org/0000-0001-6849-317X</orcidid></addata></record> |
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subjects | Coordination compounds Coupling Dipoles Dopants Efficiency Gold Horizontal orientation Ligands luminescence nitrogen heterocycles operational stability Organic light emitting diodes organic light-emitting devices Phosphorescence Photoluminescence Photons Quantum efficiency Thin films Vacuum |
title | Design Strategy Towards Horizontally Oriented Luminescent Tetradentate‐Ligand‐Containing Gold(III) Systems |
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