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A Long‐Cycling Aqueous Zinc‐Ion Pouch Cell: NASICON‐Type Material and Surface Modification
Aqueous zinc‐ion batteries (ZIBs) have become the highest potential energy storage system for large‐scale applications owing to the high specific capacity, good safety and low cost. In this work, a NASICON‐type Na3V2(PO4)3 cathode modified by a uniform carbon layer (NVP/C) has been synthesized via a...
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Published in: | Chemistry, an Asian journal an Asian journal, 2020-05, Vol.15 (9), p.1430-1435 |
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description | Aqueous zinc‐ion batteries (ZIBs) have become the highest potential energy storage system for large‐scale applications owing to the high specific capacity, good safety and low cost. In this work, a NASICON‐type Na3V2(PO4)3 cathode modified by a uniform carbon layer (NVP/C) has been synthesized via a facile solid‐state method and exhibited significantly improved electrochemical performance when working in an aqueous ZIB. Specifically, the NVP/C cathode shows an excellent rate capacity (e. g., 48 mAh g−1 at 1.0 A g−1). Good cycle stability is also achieved (e. g., showing a capacity retention of 88% after 2000 cycles at 1.0 A g−1). Furthermore, the Zn2+ (de)intercalation mechanism in the NVP cathode has been determined by various ex‐situ techniques. In addition, a Zn||NVP/C pouch cell has been assembled, delivering a high capacity of 89 mAhg−1 at 0.2 A g−1 and exhibiting a superior long cycling stability.
A long‐cycling aqueous zinc‐ion pouch cell is reported by using the cathode material of the surface‐protected (a uniform carbon layer) NASICON‐type Na3V2(PO4)3 (NVP/C). Furthermore, the zinc storage mechanism has been systematically investigated. The NVP/C is fabricated by a facile solid‐state reaction, which is suitable for large‐scale applications. |
doi_str_mv | 10.1002/asia.202000162 |
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A long‐cycling aqueous zinc‐ion pouch cell is reported by using the cathode material of the surface‐protected (a uniform carbon layer) NASICON‐type Na3V2(PO4)3 (NVP/C). Furthermore, the zinc storage mechanism has been systematically investigated. The NVP/C is fabricated by a facile solid‐state reaction, which is suitable for large‐scale applications.</description><identifier>ISSN: 1861-4728</identifier><identifier>EISSN: 1861-471X</identifier><identifier>DOI: 10.1002/asia.202000162</identifier><identifier>PMID: 32167677</identifier><language>eng</language><publisher>Germany: Wiley Subscription Services, Inc</publisher><subject>aqueous zinc-ion batteries ; Cathodes ; Chemistry ; Cycles ; Electrochemical analysis ; Energy storage ; long cycling stability ; Na3V2(PO4)3 ; Potential energy ; pouch cells ; Stability ; Storage batteries ; Zinc ; Zn-storage mechanism</subject><ispartof>Chemistry, an Asian journal, 2020-05, Vol.15 (9), p.1430-1435</ispartof><rights>2020 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2020 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4102-989c49f79dd00628a02cbb9daed32c9831db2950db330e6d0c1d29e4f2cc95a53</citedby><cites>FETCH-LOGICAL-c4102-989c49f79dd00628a02cbb9daed32c9831db2950db330e6d0c1d29e4f2cc95a53</cites><orcidid>0000-0003-1125-0905</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fasia.202000162$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fasia.202000162$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>315,786,790,27957,27958,50923,51032</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/32167677$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Zhang, Xianghua</creatorcontrib><creatorcontrib>Chen, Haoliang</creatorcontrib><creatorcontrib>Liu, Weiling</creatorcontrib><creatorcontrib>Xiao, Ni</creatorcontrib><creatorcontrib>Zhang, Qi</creatorcontrib><creatorcontrib>Rui, Xianhong</creatorcontrib><creatorcontrib>Huang, Shaoming</creatorcontrib><title>A Long‐Cycling Aqueous Zinc‐Ion Pouch Cell: NASICON‐Type Material and Surface Modification</title><title>Chemistry, an Asian journal</title><addtitle>Chem Asian J</addtitle><description>Aqueous zinc‐ion batteries (ZIBs) have become the highest potential energy storage system for large‐scale applications owing to the high specific capacity, good safety and low cost. In this work, a NASICON‐type Na3V2(PO4)3 cathode modified by a uniform carbon layer (NVP/C) has been synthesized via a facile solid‐state method and exhibited significantly improved electrochemical performance when working in an aqueous ZIB. Specifically, the NVP/C cathode shows an excellent rate capacity (e. g., 48 mAh g−1 at 1.0 A g−1). Good cycle stability is also achieved (e. g., showing a capacity retention of 88% after 2000 cycles at 1.0 A g−1). Furthermore, the Zn2+ (de)intercalation mechanism in the NVP cathode has been determined by various ex‐situ techniques. In addition, a Zn||NVP/C pouch cell has been assembled, delivering a high capacity of 89 mAhg−1 at 0.2 A g−1 and exhibiting a superior long cycling stability.
A long‐cycling aqueous zinc‐ion pouch cell is reported by using the cathode material of the surface‐protected (a uniform carbon layer) NASICON‐type Na3V2(PO4)3 (NVP/C). Furthermore, the zinc storage mechanism has been systematically investigated. The NVP/C is fabricated by a facile solid‐state reaction, which is suitable for large‐scale applications.</description><subject>aqueous zinc-ion batteries</subject><subject>Cathodes</subject><subject>Chemistry</subject><subject>Cycles</subject><subject>Electrochemical analysis</subject><subject>Energy storage</subject><subject>long cycling stability</subject><subject>Na3V2(PO4)3</subject><subject>Potential energy</subject><subject>pouch cells</subject><subject>Stability</subject><subject>Storage batteries</subject><subject>Zinc</subject><subject>Zn-storage mechanism</subject><issn>1861-4728</issn><issn>1861-471X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNqFkMtKxDAUhoMo3rcuJeDGzYwnSds07krxMjBeYEYQNzVNUo10mrGZIrPzEXxGn8QMoyO4cXXCyXd-zvkQOiDQJwD0RHor-xQoAJCErqFtkiakF3Fyv75603QL7Xj_AhBTEOkm2mKUJDzhfBs9ZnjomqfP9498rmrbPOHstTOu8_jBNiq0B67Bt65Tzzg3dX2Kr7PRIL-5Dj_j-dTgKzkzrZU1lo3Go66tpApNp21llZxZ1-yhjUrW3ux_1110d342zi97w5uLQZ4NeyoiQHsiFSoSFRdaAyQ0lUBVWQotjWZUiZQRXVIRgy4ZA5NoUERTYaKKKiViGbNddLzMnbYuXOBnxcR6FVaWzeKcgjLOGeMxTwJ69Ad9cV3bhO0CJXiUQBovqP6SUq3zvjVVMW3tRLbzgkCxcF8s3Bcr92Hg8Du2KydGr_Af2QEQS-DN1mb-T1wRPGe_4V_5e5FO</recordid><startdate>20200504</startdate><enddate>20200504</enddate><creator>Zhang, Xianghua</creator><creator>Chen, Haoliang</creator><creator>Liu, Weiling</creator><creator>Xiao, Ni</creator><creator>Zhang, Qi</creator><creator>Rui, Xianhong</creator><creator>Huang, Shaoming</creator><general>Wiley Subscription Services, Inc</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>K9.</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0003-1125-0905</orcidid></search><sort><creationdate>20200504</creationdate><title>A Long‐Cycling Aqueous Zinc‐Ion Pouch Cell: NASICON‐Type Material and Surface Modification</title><author>Zhang, Xianghua ; Chen, Haoliang ; Liu, Weiling ; Xiao, Ni ; Zhang, Qi ; Rui, Xianhong ; Huang, Shaoming</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4102-989c49f79dd00628a02cbb9daed32c9831db2950db330e6d0c1d29e4f2cc95a53</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>aqueous zinc-ion batteries</topic><topic>Cathodes</topic><topic>Chemistry</topic><topic>Cycles</topic><topic>Electrochemical analysis</topic><topic>Energy storage</topic><topic>long cycling stability</topic><topic>Na3V2(PO4)3</topic><topic>Potential energy</topic><topic>pouch cells</topic><topic>Stability</topic><topic>Storage batteries</topic><topic>Zinc</topic><topic>Zn-storage mechanism</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhang, Xianghua</creatorcontrib><creatorcontrib>Chen, Haoliang</creatorcontrib><creatorcontrib>Liu, Weiling</creatorcontrib><creatorcontrib>Xiao, Ni</creatorcontrib><creatorcontrib>Zhang, Qi</creatorcontrib><creatorcontrib>Rui, Xianhong</creatorcontrib><creatorcontrib>Huang, Shaoming</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><jtitle>Chemistry, an Asian journal</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhang, Xianghua</au><au>Chen, Haoliang</au><au>Liu, Weiling</au><au>Xiao, Ni</au><au>Zhang, Qi</au><au>Rui, Xianhong</au><au>Huang, Shaoming</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A Long‐Cycling Aqueous Zinc‐Ion Pouch Cell: NASICON‐Type Material and Surface Modification</atitle><jtitle>Chemistry, an Asian journal</jtitle><addtitle>Chem Asian J</addtitle><date>2020-05-04</date><risdate>2020</risdate><volume>15</volume><issue>9</issue><spage>1430</spage><epage>1435</epage><pages>1430-1435</pages><issn>1861-4728</issn><eissn>1861-471X</eissn><notes>These authors contributed equally to this work.</notes><notes>ObjectType-Article-1</notes><notes>SourceType-Scholarly Journals-1</notes><notes>ObjectType-Feature-2</notes><notes>content type line 23</notes><abstract>Aqueous zinc‐ion batteries (ZIBs) have become the highest potential energy storage system for large‐scale applications owing to the high specific capacity, good safety and low cost. In this work, a NASICON‐type Na3V2(PO4)3 cathode modified by a uniform carbon layer (NVP/C) has been synthesized via a facile solid‐state method and exhibited significantly improved electrochemical performance when working in an aqueous ZIB. Specifically, the NVP/C cathode shows an excellent rate capacity (e. g., 48 mAh g−1 at 1.0 A g−1). Good cycle stability is also achieved (e. g., showing a capacity retention of 88% after 2000 cycles at 1.0 A g−1). Furthermore, the Zn2+ (de)intercalation mechanism in the NVP cathode has been determined by various ex‐situ techniques. In addition, a Zn||NVP/C pouch cell has been assembled, delivering a high capacity of 89 mAhg−1 at 0.2 A g−1 and exhibiting a superior long cycling stability.
A long‐cycling aqueous zinc‐ion pouch cell is reported by using the cathode material of the surface‐protected (a uniform carbon layer) NASICON‐type Na3V2(PO4)3 (NVP/C). Furthermore, the zinc storage mechanism has been systematically investigated. The NVP/C is fabricated by a facile solid‐state reaction, which is suitable for large‐scale applications.</abstract><cop>Germany</cop><pub>Wiley Subscription Services, Inc</pub><pmid>32167677</pmid><doi>10.1002/asia.202000162</doi><tpages>6</tpages><orcidid>https://orcid.org/0000-0003-1125-0905</orcidid></addata></record> |
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subjects | aqueous zinc-ion batteries Cathodes Chemistry Cycles Electrochemical analysis Energy storage long cycling stability Na3V2(PO4)3 Potential energy pouch cells Stability Storage batteries Zinc Zn-storage mechanism |
title | A Long‐Cycling Aqueous Zinc‐Ion Pouch Cell: NASICON‐Type Material and Surface Modification |
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