Organic–Inorganic Hybrid Heterometallic Halides with Low-Dimensional Structures and Red Photoluminescence Emissions

In recent years, although low-dimensional hybrid lead halides have received great attention due to the fascinating photoluminescent (PL) properties, the research is still on the early stage and only limited phases have been explored and characterized. Here, by introducing heterometals as mixed struc...

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Published in:Inorganic chemistry 2019-08, Vol.58 (15), p.10304-10312
Main Authors: Yue, Cheng-Yang, Sun, Chen, Li, Dong-Yang, Dong, Yu-Han, Wang, Chun-Lei, Zhao, Hui-Fang, Jiang, Hao, Jing, Zhi-Hong, Lei, Xiao-Wu
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container_end_page 10312
container_issue 15
container_start_page 10304
container_title Inorganic chemistry
container_volume 58
creator Yue, Cheng-Yang
Sun, Chen
Li, Dong-Yang
Dong, Yu-Han
Wang, Chun-Lei
Zhao, Hui-Fang
Jiang, Hao
Jing, Zhi-Hong
Lei, Xiao-Wu
description In recent years, although low-dimensional hybrid lead halides have received great attention due to the fascinating photoluminescent (PL) properties, the research is still on the early stage and only limited phases have been explored and characterized. Here, by introducing heterometals as mixed structural compositions and optical activity centers, we prepared a series of low-dimensional hybrid heterometallic halides, namely as, [(Me)-DABCO]2Cu2PbI6, [(Me)2-DABCO]2M5Pb2I13 (M = Cu and Ag) and [(Me)2-DABCO]­Ag2PbBr6 (Me = methyl group, DABCO = 1,4-diazabicyclo[2.2.2]­octane). These hybrid halides feature a low-dimensional 0D [Cu2PbI6]2– cluster, a 1D [M5Pb2I13]4– chain, and a 2D [Ag2PbBr6]2– layer, respectively, on the basis of corner-, edge- and face-sharing connecting of [MX4] tetrahedrons, [PbX5] quadrangular pyramids, and [PbX6] octahedrons. Under the photoexcitation, these hybrid heterometallic halides exhibit deep-red luminescent emissions from 711 to 801 nm with the largest Stocks shift of 395 nm. The temperature-dependent PL emissions, PL lifetime, and theoretical calculations are also investigated to probe into the intrinsic nature of photoluminescent emissions. This work affords new types of hybrid halides by introducing different metal centers to probe into the structural evolution and photoluminescent properties.
doi_str_mv 10.1021/acs.inorgchem.9b01472
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title Organic–Inorganic Hybrid Heterometallic Halides with Low-Dimensional Structures and Red Photoluminescence Emissions
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