Synthesis and application of sugarcane bagasse cellulose mixed esters. Part I: Removal of Co2+ and Ni2+ from single spiked aqueous solutions in batch mode using sugarcane bagasse cellulose succinate phthalate

[Display omitted] Sugarcane bagasse cellulose mixed ester succinate phthalate (SBSPh) was synthesized by a novel one-pot reaction method. The effects of temperature, time and mole fraction of succinic anhydride (χSA) on the responses weight gain (wg), number of carboxylic acid groups (nT,COOH), and...

Full description

Saved in:
Bibliographic Details
Published in:Journal of colloid and interface science 2019-01, Vol.533, p.678-691
Main Authors: Elias, Megg Madonyk Cota, Ferreira, Gabriel Max Dias, de Almeida, Francine Tatiane Rezende, Rosa, Nathália Cristina Martins, Silva, Isabela Almeida, Filgueiras, Jefferson Gonçalves, de Azevedo, Eduardo Ribeiro, da Silva, Luis Henrique Mendes, Melo, Tânia Márcia Sacramento, Gil, Laurent Frédéric, Gurgel, Leandro Vinícius Alves
Format: Article
Language:English
Subjects:
13C Multiple Cross-Polarization solid-state NMR
Adsorption
Isothermal titration calorimetry
Metal ion
Mixed esters
Sugarcane bagasse
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-c344t-e71505c03cdb4672a6f2638afe1b571811a1510ffb575679333e19710e7860433
cites cdi_FETCH-LOGICAL-c344t-e71505c03cdb4672a6f2638afe1b571811a1510ffb575679333e19710e7860433
container_end_page 691
container_issue
container_start_page 678
container_title Journal of colloid and interface science
container_volume 533
creator Elias, Megg Madonyk Cota
Ferreira, Gabriel Max Dias
de Almeida, Francine Tatiane Rezende
Rosa, Nathália Cristina Martins
Silva, Isabela Almeida
Filgueiras, Jefferson Gonçalves
de Azevedo, Eduardo Ribeiro
da Silva, Luis Henrique Mendes
Melo, Tânia Márcia Sacramento
Gil, Laurent Frédéric
Gurgel, Leandro Vinícius Alves
description [Display omitted] Sugarcane bagasse cellulose mixed ester succinate phthalate (SBSPh) was synthesized by a novel one-pot reaction method. The effects of temperature, time and mole fraction of succinic anhydride (χSA) on the responses weight gain (wg), number of carboxylic acid groups (nT,COOH), and adsorption capacity (q) of Co2+ and Ni2+ were evaluated by a 23 experimental design. The chemical structure of the material was elucidated by Fourier transform infrared, 13C Multiple Cross-Polarization solid-state NMR spectroscopy and 1H NMR relaxometry. The best SBSPh synthesis condition (100 °C, 11 h, χSA of 0.2) yielded a wg of 59.1%, nT,COOH of 3.41 mmol g−1, and values of qCo2+ and qNi2+ of 0.348 and 0.346 mmol g−1, respectively. The Sips model fitted better the equilibrium data, and the maximum adsorption capacities (pH 5.75 and 25 °C) estimated by this model were 0.62 and 0.53 mmol g−1 for Co2+ and Ni2+, respectively. The ΔadsH° values estimated by isothermal titration calorimetry were 8.43 and 7.79 kJ mol−1 for Co2+ and Ni2+, respectively. Desorption and re-adsorption efficiencies were evaluated by a 22 experimental design, which showed that SBSPh adsorbent can be recovered and reused without significant loss of adsorption capacity.
doi_str_mv 10.1016/j.jcis.2018.08.109
format article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_2101923835</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0021979718310324</els_id><sourcerecordid>2101923835</sourcerecordid><originalsourceid>FETCH-LOGICAL-c344t-e71505c03cdb4672a6f2638afe1b571811a1510ffb575679333e19710e7860433</originalsourceid><addsrcrecordid>eNp9UU1v1DAQtRBILIU_wMlHJJRgx-t8IC5oBaVSBajA2fI6k10vThw8TtX-S35SJyznXuzx6L2Z9_wYey1FKYWs353Kk_NYVkK2pWip1z1hGzp10UihnrKNEJUsuqZrnrMXiCchpNS627C_P-6nfAT0yO3UczvPwTubfZx4HDguB5ucnYDv7cEiAncQwhIiVaO_g54DZkhY8u82ZX71nt_AGG9tWMm7WL39N_Srp2JIceTop0MAjrP_TVz7Z4G4IMcYlnUjcj_RouyOfIw98GWFP6oBF-f8ZDPw-ZiPNlD1kj0bbEB49f--YL8-f_q5-1Jcf7u82n28LpzabnMBjdRCO6Fcv9_WTWXroapVaweQe93IVkortRTDQC9dN51SCmRHnwlNW4utUhfszXnunCL5wGxGj6syUkqmTEW5dJVqlSZodYa6FBETDGZOfrTp3khh1vjMyazxmTU-I1rqdUT6cCYBmbj1kAw6D5OD3idw2fTRP0Z_AOyOptg</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2101923835</pqid></control><display><type>article</type><title>Synthesis and application of sugarcane bagasse cellulose mixed esters. Part I: Removal of Co2+ and Ni2+ from single spiked aqueous solutions in batch mode using sugarcane bagasse cellulose succinate phthalate</title><source>ScienceDirect Freedom Collection 2022-2024</source><creator>Elias, Megg Madonyk Cota ; Ferreira, Gabriel Max Dias ; de Almeida, Francine Tatiane Rezende ; Rosa, Nathália Cristina Martins ; Silva, Isabela Almeida ; Filgueiras, Jefferson Gonçalves ; de Azevedo, Eduardo Ribeiro ; da Silva, Luis Henrique Mendes ; Melo, Tânia Márcia Sacramento ; Gil, Laurent Frédéric ; Gurgel, Leandro Vinícius Alves</creator><creatorcontrib>Elias, Megg Madonyk Cota ; Ferreira, Gabriel Max Dias ; de Almeida, Francine Tatiane Rezende ; Rosa, Nathália Cristina Martins ; Silva, Isabela Almeida ; Filgueiras, Jefferson Gonçalves ; de Azevedo, Eduardo Ribeiro ; da Silva, Luis Henrique Mendes ; Melo, Tânia Márcia Sacramento ; Gil, Laurent Frédéric ; Gurgel, Leandro Vinícius Alves</creatorcontrib><description>[Display omitted] Sugarcane bagasse cellulose mixed ester succinate phthalate (SBSPh) was synthesized by a novel one-pot reaction method. The effects of temperature, time and mole fraction of succinic anhydride (χSA) on the responses weight gain (wg), number of carboxylic acid groups (nT,COOH), and adsorption capacity (q) of Co2+ and Ni2+ were evaluated by a 23 experimental design. The chemical structure of the material was elucidated by Fourier transform infrared, 13C Multiple Cross-Polarization solid-state NMR spectroscopy and 1H NMR relaxometry. The best SBSPh synthesis condition (100 °C, 11 h, χSA of 0.2) yielded a wg of 59.1%, nT,COOH of 3.41 mmol g−1, and values of qCo2+ and qNi2+ of 0.348 and 0.346 mmol g−1, respectively. The Sips model fitted better the equilibrium data, and the maximum adsorption capacities (pH 5.75 and 25 °C) estimated by this model were 0.62 and 0.53 mmol g−1 for Co2+ and Ni2+, respectively. The ΔadsH° values estimated by isothermal titration calorimetry were 8.43 and 7.79 kJ mol−1 for Co2+ and Ni2+, respectively. Desorption and re-adsorption efficiencies were evaluated by a 22 experimental design, which showed that SBSPh adsorbent can be recovered and reused without significant loss of adsorption capacity.</description><identifier>ISSN: 0021-9797</identifier><identifier>EISSN: 1095-7103</identifier><identifier>DOI: 10.1016/j.jcis.2018.08.109</identifier><language>eng</language><publisher>Elsevier Inc</publisher><subject>13C Multiple Cross-Polarization solid-state NMR ; Adsorption ; Isothermal titration calorimetry ; Metal ion ; Mixed esters ; Sugarcane bagasse</subject><ispartof>Journal of colloid and interface science, 2019-01, Vol.533, p.678-691</ispartof><rights>2018 Elsevier Inc.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c344t-e71505c03cdb4672a6f2638afe1b571811a1510ffb575679333e19710e7860433</citedby><cites>FETCH-LOGICAL-c344t-e71505c03cdb4672a6f2638afe1b571811a1510ffb575679333e19710e7860433</cites><orcidid>0000-0002-8262-1091</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>315,786,790,27957,27958</link.rule.ids></links><search><creatorcontrib>Elias, Megg Madonyk Cota</creatorcontrib><creatorcontrib>Ferreira, Gabriel Max Dias</creatorcontrib><creatorcontrib>de Almeida, Francine Tatiane Rezende</creatorcontrib><creatorcontrib>Rosa, Nathália Cristina Martins</creatorcontrib><creatorcontrib>Silva, Isabela Almeida</creatorcontrib><creatorcontrib>Filgueiras, Jefferson Gonçalves</creatorcontrib><creatorcontrib>de Azevedo, Eduardo Ribeiro</creatorcontrib><creatorcontrib>da Silva, Luis Henrique Mendes</creatorcontrib><creatorcontrib>Melo, Tânia Márcia Sacramento</creatorcontrib><creatorcontrib>Gil, Laurent Frédéric</creatorcontrib><creatorcontrib>Gurgel, Leandro Vinícius Alves</creatorcontrib><title>Synthesis and application of sugarcane bagasse cellulose mixed esters. Part I: Removal of Co2+ and Ni2+ from single spiked aqueous solutions in batch mode using sugarcane bagasse cellulose succinate phthalate</title><title>Journal of colloid and interface science</title><description>[Display omitted] Sugarcane bagasse cellulose mixed ester succinate phthalate (SBSPh) was synthesized by a novel one-pot reaction method. The effects of temperature, time and mole fraction of succinic anhydride (χSA) on the responses weight gain (wg), number of carboxylic acid groups (nT,COOH), and adsorption capacity (q) of Co2+ and Ni2+ were evaluated by a 23 experimental design. The chemical structure of the material was elucidated by Fourier transform infrared, 13C Multiple Cross-Polarization solid-state NMR spectroscopy and 1H NMR relaxometry. The best SBSPh synthesis condition (100 °C, 11 h, χSA of 0.2) yielded a wg of 59.1%, nT,COOH of 3.41 mmol g−1, and values of qCo2+ and qNi2+ of 0.348 and 0.346 mmol g−1, respectively. The Sips model fitted better the equilibrium data, and the maximum adsorption capacities (pH 5.75 and 25 °C) estimated by this model were 0.62 and 0.53 mmol g−1 for Co2+ and Ni2+, respectively. The ΔadsH° values estimated by isothermal titration calorimetry were 8.43 and 7.79 kJ mol−1 for Co2+ and Ni2+, respectively. Desorption and re-adsorption efficiencies were evaluated by a 22 experimental design, which showed that SBSPh adsorbent can be recovered and reused without significant loss of adsorption capacity.</description><subject>13C Multiple Cross-Polarization solid-state NMR</subject><subject>Adsorption</subject><subject>Isothermal titration calorimetry</subject><subject>Metal ion</subject><subject>Mixed esters</subject><subject>Sugarcane bagasse</subject><issn>0021-9797</issn><issn>1095-7103</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp9UU1v1DAQtRBILIU_wMlHJJRgx-t8IC5oBaVSBajA2fI6k10vThw8TtX-S35SJyznXuzx6L2Z9_wYey1FKYWs353Kk_NYVkK2pWip1z1hGzp10UihnrKNEJUsuqZrnrMXiCchpNS627C_P-6nfAT0yO3UczvPwTubfZx4HDguB5ucnYDv7cEiAncQwhIiVaO_g54DZkhY8u82ZX71nt_AGG9tWMm7WL39N_Srp2JIceTop0MAjrP_TVz7Z4G4IMcYlnUjcj_RouyOfIw98GWFP6oBF-f8ZDPw-ZiPNlD1kj0bbEB49f--YL8-f_q5-1Jcf7u82n28LpzabnMBjdRCO6Fcv9_WTWXroapVaweQe93IVkortRTDQC9dN51SCmRHnwlNW4utUhfszXnunCL5wGxGj6syUkqmTEW5dJVqlSZodYa6FBETDGZOfrTp3khh1vjMyazxmTU-I1rqdUT6cCYBmbj1kAw6D5OD3idw2fTRP0Z_AOyOptg</recordid><startdate>20190101</startdate><enddate>20190101</enddate><creator>Elias, Megg Madonyk Cota</creator><creator>Ferreira, Gabriel Max Dias</creator><creator>de Almeida, Francine Tatiane Rezende</creator><creator>Rosa, Nathália Cristina Martins</creator><creator>Silva, Isabela Almeida</creator><creator>Filgueiras, Jefferson Gonçalves</creator><creator>de Azevedo, Eduardo Ribeiro</creator><creator>da Silva, Luis Henrique Mendes</creator><creator>Melo, Tânia Márcia Sacramento</creator><creator>Gil, Laurent Frédéric</creator><creator>Gurgel, Leandro Vinícius Alves</creator><general>Elsevier Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-8262-1091</orcidid></search><sort><creationdate>20190101</creationdate><title>Synthesis and application of sugarcane bagasse cellulose mixed esters. Part I: Removal of Co2+ and Ni2+ from single spiked aqueous solutions in batch mode using sugarcane bagasse cellulose succinate phthalate</title><author>Elias, Megg Madonyk Cota ; Ferreira, Gabriel Max Dias ; de Almeida, Francine Tatiane Rezende ; Rosa, Nathália Cristina Martins ; Silva, Isabela Almeida ; Filgueiras, Jefferson Gonçalves ; de Azevedo, Eduardo Ribeiro ; da Silva, Luis Henrique Mendes ; Melo, Tânia Márcia Sacramento ; Gil, Laurent Frédéric ; Gurgel, Leandro Vinícius Alves</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c344t-e71505c03cdb4672a6f2638afe1b571811a1510ffb575679333e19710e7860433</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>13C Multiple Cross-Polarization solid-state NMR</topic><topic>Adsorption</topic><topic>Isothermal titration calorimetry</topic><topic>Metal ion</topic><topic>Mixed esters</topic><topic>Sugarcane bagasse</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Elias, Megg Madonyk Cota</creatorcontrib><creatorcontrib>Ferreira, Gabriel Max Dias</creatorcontrib><creatorcontrib>de Almeida, Francine Tatiane Rezende</creatorcontrib><creatorcontrib>Rosa, Nathália Cristina Martins</creatorcontrib><creatorcontrib>Silva, Isabela Almeida</creatorcontrib><creatorcontrib>Filgueiras, Jefferson Gonçalves</creatorcontrib><creatorcontrib>de Azevedo, Eduardo Ribeiro</creatorcontrib><creatorcontrib>da Silva, Luis Henrique Mendes</creatorcontrib><creatorcontrib>Melo, Tânia Márcia Sacramento</creatorcontrib><creatorcontrib>Gil, Laurent Frédéric</creatorcontrib><creatorcontrib>Gurgel, Leandro Vinícius Alves</creatorcontrib><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Journal of colloid and interface science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Elias, Megg Madonyk Cota</au><au>Ferreira, Gabriel Max Dias</au><au>de Almeida, Francine Tatiane Rezende</au><au>Rosa, Nathália Cristina Martins</au><au>Silva, Isabela Almeida</au><au>Filgueiras, Jefferson Gonçalves</au><au>de Azevedo, Eduardo Ribeiro</au><au>da Silva, Luis Henrique Mendes</au><au>Melo, Tânia Márcia Sacramento</au><au>Gil, Laurent Frédéric</au><au>Gurgel, Leandro Vinícius Alves</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and application of sugarcane bagasse cellulose mixed esters. Part I: Removal of Co2+ and Ni2+ from single spiked aqueous solutions in batch mode using sugarcane bagasse cellulose succinate phthalate</atitle><jtitle>Journal of colloid and interface science</jtitle><date>2019-01-01</date><risdate>2019</risdate><volume>533</volume><spage>678</spage><epage>691</epage><pages>678-691</pages><issn>0021-9797</issn><eissn>1095-7103</eissn><notes>ObjectType-Article-1</notes><notes>SourceType-Scholarly Journals-1</notes><notes>ObjectType-Feature-2</notes><notes>content type line 23</notes><abstract>[Display omitted] Sugarcane bagasse cellulose mixed ester succinate phthalate (SBSPh) was synthesized by a novel one-pot reaction method. The effects of temperature, time and mole fraction of succinic anhydride (χSA) on the responses weight gain (wg), number of carboxylic acid groups (nT,COOH), and adsorption capacity (q) of Co2+ and Ni2+ were evaluated by a 23 experimental design. The chemical structure of the material was elucidated by Fourier transform infrared, 13C Multiple Cross-Polarization solid-state NMR spectroscopy and 1H NMR relaxometry. The best SBSPh synthesis condition (100 °C, 11 h, χSA of 0.2) yielded a wg of 59.1%, nT,COOH of 3.41 mmol g−1, and values of qCo2+ and qNi2+ of 0.348 and 0.346 mmol g−1, respectively. The Sips model fitted better the equilibrium data, and the maximum adsorption capacities (pH 5.75 and 25 °C) estimated by this model were 0.62 and 0.53 mmol g−1 for Co2+ and Ni2+, respectively. The ΔadsH° values estimated by isothermal titration calorimetry were 8.43 and 7.79 kJ mol−1 for Co2+ and Ni2+, respectively. Desorption and re-adsorption efficiencies were evaluated by a 22 experimental design, which showed that SBSPh adsorbent can be recovered and reused without significant loss of adsorption capacity.</abstract><pub>Elsevier Inc</pub><doi>10.1016/j.jcis.2018.08.109</doi><tpages>14</tpages><orcidid>https://orcid.org/0000-0002-8262-1091</orcidid><oa>free_for_read</oa></addata></record>
fulltext fulltext
identifier ISSN: 0021-9797
ispartof Journal of colloid and interface science, 2019-01, Vol.533, p.678-691
issn 0021-9797
1095-7103
language eng
recordid cdi_proquest_miscellaneous_2101923835
source ScienceDirect Freedom Collection 2022-2024
subjects 13C Multiple Cross-Polarization solid-state NMR
Adsorption
Isothermal titration calorimetry
Metal ion
Mixed esters
Sugarcane bagasse
title Synthesis and application of sugarcane bagasse cellulose mixed esters. Part I: Removal of Co2+ and Ni2+ from single spiked aqueous solutions in batch mode using sugarcane bagasse cellulose succinate phthalate
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-09-21T14%3A39%3A40IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Synthesis%20and%20application%20of%20sugarcane%20bagasse%20cellulose%20mixed%20esters.%20Part%20I:%20Removal%20of%20Co2+%20and%20Ni2+%20from%20single%20spiked%20aqueous%20solutions%20in%20batch%20mode%20using%20sugarcane%20bagasse%20cellulose%20succinate%20phthalate&rft.jtitle=Journal%20of%20colloid%20and%20interface%20science&rft.au=Elias,%20Megg%20Madonyk%20Cota&rft.date=2019-01-01&rft.volume=533&rft.spage=678&rft.epage=691&rft.pages=678-691&rft.issn=0021-9797&rft.eissn=1095-7103&rft_id=info:doi/10.1016/j.jcis.2018.08.109&rft_dat=%3Cproquest_cross%3E2101923835%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c344t-e71505c03cdb4672a6f2638afe1b571811a1510ffb575679333e19710e7860433%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=2101923835&rft_id=info:pmid/&rfr_iscdi=true