Quest for the Ncb-type Metal–Organic Framework Platform: A Bifunctional Ligand Approach Meets Net Topology Needs

Quest for the Ncb-type Metal–Organic Framework Platform: A Bifunctional Ligand Approach Meets Net Topology Needs

A custom-designed bifunctional ligand was used to connect an in situ formed Co3(OH) cluster affording a porous metal–organic framework, which represents the first case of ncb-type networks constructed from a single kind of ditopic ligand. Noticeably, the activated MOF shows high volumetric C2H2 upta...

Full description

Saved in:
Bibliographic Details
Published in:Inorganic chemistry 2017-07, Vol.56 (13), p.7328-7331
Main Authors: Chen, Di-Ming, Zhang, Nan-Nan, Tian, Jia-Yue, Liu, Chun-Sen, Du, Miao
Format: Article
Language:eng
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:A custom-designed bifunctional ligand was used to connect an in situ formed Co3(OH) cluster affording a porous metal–organic framework, which represents the first case of ncb-type networks constructed from a single kind of ditopic ligand. Noticeably, the activated MOF shows high volumetric C2H2 uptake and excellent adsorption selectivity for C2H2/CO2 separation at room temperature with a low sorption heat.
ISSN:0020-1669
1520-510X