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Synthesis and thermal conversions of unsaturated cobalt(II) dicarboxylates as precursors of metallopolymer nanocomposites
The synthesis and IR spectroscopic and thermoanalytical study of cobalt(II) hydrogen salts with unsaturated dicarboxylic acids, such as maleic, itaconic, acetylenedicarboxylic, allylmalonic, glutaconic, and cis -, cis -muconic acids, were performed. Co 3 O 4 polymer based nanocomposites were prepare...
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| Published in: | Russian journal of inorganic chemistry 2015-08, Vol.60 (8), p.897-905 |
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| Main Authors: | , , , , , , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c321t-b28fb478323ba54657b333e59df1773549816553d2547e1295644383c46ce28b3 |
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| cites | cdi_FETCH-LOGICAL-c321t-b28fb478323ba54657b333e59df1773549816553d2547e1295644383c46ce28b3 |
| container_end_page | 905 |
| container_issue | 8 |
| container_start_page | 897 |
| container_title | Russian journal of inorganic chemistry |
| container_volume | 60 |
| creator | Semenov, S. A. Drobot, D. V. Musatova, V. Yu Pronin, A. S. Pomogailo, A. D. Dzhardimalieva, G. I. Popenko, V. I. |
| description | The synthesis and IR spectroscopic and thermoanalytical study of cobalt(II) hydrogen salts with unsaturated dicarboxylic acids, such as maleic, itaconic, acetylenedicarboxylic, allylmalonic, glutaconic, and
cis
-,
cis
-muconic acids, were performed. Co
3
O
4
polymer based nanocomposites were prepared through the thermal decomposition of the carboxylates synthesized. The size distribution of nanoparticles and their average diameter (
d
avg
) were determined. The formation enthalpies of cobalt hydrogen carboxylates (Δ
H
p
o
) were calculated using the PM3 semi-empirical quantum-chemical method. A correlation between
d
avg
and Δ
H
p
o
was established. The magnetic characteristics of the synthesized composites, namely the maximum residual magnetization and coercive force, were determined. The critical diameter of nanoparticles for their transition from multidomain to one-domain particles was found to be 3.8 nm. |
| doi_str_mv | 10.1134/S0036023615080161 |
| format | article |
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cis
-,
cis
-muconic acids, were performed. Co
3
O
4
polymer based nanocomposites were prepared through the thermal decomposition of the carboxylates synthesized. The size distribution of nanoparticles and their average diameter (
d
avg
) were determined. The formation enthalpies of cobalt hydrogen carboxylates (Δ
H
p
o
) were calculated using the PM3 semi-empirical quantum-chemical method. A correlation between
d
avg
and Δ
H
p
o
was established. The magnetic characteristics of the synthesized composites, namely the maximum residual magnetization and coercive force, were determined. The critical diameter of nanoparticles for their transition from multidomain to one-domain particles was found to be 3.8 nm.</description><identifier>ISSN: 0036-0236</identifier><identifier>EISSN: 1531-8613</identifier><identifier>DOI: 10.1134/S0036023615080161</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Carboxylates ; Chemistry ; Chemistry and Materials Science ; Coercive force ; Inorganic Chemistry ; Magnetization ; Nanocomposites ; Nanoparticles ; Quantum chemistry ; Synthesis ; Synthesis and Properties of Inorganic Compounds ; Unsaturated</subject><ispartof>Russian journal of inorganic chemistry, 2015-08, Vol.60 (8), p.897-905</ispartof><rights>Pleiades Publishing, Ltd. 2015</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c321t-b28fb478323ba54657b333e59df1773549816553d2547e1295644383c46ce28b3</citedby><cites>FETCH-LOGICAL-c321t-b28fb478323ba54657b333e59df1773549816553d2547e1295644383c46ce28b3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>315,786,790,27957,27958</link.rule.ids></links><search><creatorcontrib>Semenov, S. A.</creatorcontrib><creatorcontrib>Drobot, D. V.</creatorcontrib><creatorcontrib>Musatova, V. Yu</creatorcontrib><creatorcontrib>Pronin, A. S.</creatorcontrib><creatorcontrib>Pomogailo, A. D.</creatorcontrib><creatorcontrib>Dzhardimalieva, G. I.</creatorcontrib><creatorcontrib>Popenko, V. I.</creatorcontrib><title>Synthesis and thermal conversions of unsaturated cobalt(II) dicarboxylates as precursors of metallopolymer nanocomposites</title><title>Russian journal of inorganic chemistry</title><addtitle>Russ. J. Inorg. Chem</addtitle><description>The synthesis and IR spectroscopic and thermoanalytical study of cobalt(II) hydrogen salts with unsaturated dicarboxylic acids, such as maleic, itaconic, acetylenedicarboxylic, allylmalonic, glutaconic, and
cis
-,
cis
-muconic acids, were performed. Co
3
O
4
polymer based nanocomposites were prepared through the thermal decomposition of the carboxylates synthesized. The size distribution of nanoparticles and their average diameter (
d
avg
) were determined. The formation enthalpies of cobalt hydrogen carboxylates (Δ
H
p
o
) were calculated using the PM3 semi-empirical quantum-chemical method. A correlation between
d
avg
and Δ
H
p
o
was established. The magnetic characteristics of the synthesized composites, namely the maximum residual magnetization and coercive force, were determined. The critical diameter of nanoparticles for their transition from multidomain to one-domain particles was found to be 3.8 nm.</description><subject>Carboxylates</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Coercive force</subject><subject>Inorganic Chemistry</subject><subject>Magnetization</subject><subject>Nanocomposites</subject><subject>Nanoparticles</subject><subject>Quantum chemistry</subject><subject>Synthesis</subject><subject>Synthesis and Properties of Inorganic Compounds</subject><subject>Unsaturated</subject><issn>0036-0236</issn><issn>1531-8613</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNp9kE1LxDAQhoMouH78AG85rodqpkna7FHEjwXBw-q5pGmqXdKkZlqx_96s603wNAPv8wzMS8gFsCsALq43jPGC5bwAyRSDAg7IAiSHTBXAD8liF2e7_JicIG4ZE4KVakHmzezHd4sdUu0bmtbYa0dN8J82Yhc80tDSyaMep6hH26So1m5crteXtOmMjnX4ml1K0gGkQ7Rmihjij9bbUTsXhuDm3kbqtQ8m9EPALuFn5KjVDu357zwlr_d3L7eP2dPzw_r25ikzPIcxq3PV1qJUPOe1lqKQZc05t3LVtFCWXIqVgkJK3uRSlBbylSyE4IobURibq5qfkuX-7hDDx2RxrPoOjXVOexsmrKAUogSVzITCHjUxIEbbVkPseh3nCli1q7n6U3Ny8r2DifVvNlbbMEWfPvpH-gbTGYA5</recordid><startdate>20150801</startdate><enddate>20150801</enddate><creator>Semenov, S. A.</creator><creator>Drobot, D. V.</creator><creator>Musatova, V. Yu</creator><creator>Pronin, A. S.</creator><creator>Pomogailo, A. D.</creator><creator>Dzhardimalieva, G. I.</creator><creator>Popenko, V. I.</creator><general>Pleiades Publishing</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20150801</creationdate><title>Synthesis and thermal conversions of unsaturated cobalt(II) dicarboxylates as precursors of metallopolymer nanocomposites</title><author>Semenov, S. A. ; Drobot, D. V. ; Musatova, V. Yu ; Pronin, A. S. ; Pomogailo, A. D. ; Dzhardimalieva, G. I. ; Popenko, V. I.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c321t-b28fb478323ba54657b333e59df1773549816553d2547e1295644383c46ce28b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Carboxylates</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Coercive force</topic><topic>Inorganic Chemistry</topic><topic>Magnetization</topic><topic>Nanocomposites</topic><topic>Nanoparticles</topic><topic>Quantum chemistry</topic><topic>Synthesis</topic><topic>Synthesis and Properties of Inorganic Compounds</topic><topic>Unsaturated</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Semenov, S. A.</creatorcontrib><creatorcontrib>Drobot, D. V.</creatorcontrib><creatorcontrib>Musatova, V. Yu</creatorcontrib><creatorcontrib>Pronin, A. S.</creatorcontrib><creatorcontrib>Pomogailo, A. D.</creatorcontrib><creatorcontrib>Dzhardimalieva, G. I.</creatorcontrib><creatorcontrib>Popenko, V. I.</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Russian journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Semenov, S. A.</au><au>Drobot, D. V.</au><au>Musatova, V. Yu</au><au>Pronin, A. S.</au><au>Pomogailo, A. D.</au><au>Dzhardimalieva, G. I.</au><au>Popenko, V. I.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and thermal conversions of unsaturated cobalt(II) dicarboxylates as precursors of metallopolymer nanocomposites</atitle><jtitle>Russian journal of inorganic chemistry</jtitle><stitle>Russ. J. Inorg. Chem</stitle><date>2015-08-01</date><risdate>2015</risdate><volume>60</volume><issue>8</issue><spage>897</spage><epage>905</epage><pages>897-905</pages><issn>0036-0236</issn><eissn>1531-8613</eissn><notes>ObjectType-Article-1</notes><notes>SourceType-Scholarly Journals-1</notes><notes>ObjectType-Feature-2</notes><notes>content type line 23</notes><abstract>The synthesis and IR spectroscopic and thermoanalytical study of cobalt(II) hydrogen salts with unsaturated dicarboxylic acids, such as maleic, itaconic, acetylenedicarboxylic, allylmalonic, glutaconic, and
cis
-,
cis
-muconic acids, were performed. Co
3
O
4
polymer based nanocomposites were prepared through the thermal decomposition of the carboxylates synthesized. The size distribution of nanoparticles and their average diameter (
d
avg
) were determined. The formation enthalpies of cobalt hydrogen carboxylates (Δ
H
p
o
) were calculated using the PM3 semi-empirical quantum-chemical method. A correlation between
d
avg
and Δ
H
p
o
was established. The magnetic characteristics of the synthesized composites, namely the maximum residual magnetization and coercive force, were determined. The critical diameter of nanoparticles for their transition from multidomain to one-domain particles was found to be 3.8 nm.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0036023615080161</doi><tpages>9</tpages></addata></record> |
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| ispartof | Russian journal of inorganic chemistry, 2015-08, Vol.60 (8), p.897-905 |
| issn | 0036-0236 1531-8613 |
| language | eng |
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| source | Springer Link |
| subjects | Carboxylates Chemistry Chemistry and Materials Science Coercive force Inorganic Chemistry Magnetization Nanocomposites Nanoparticles Quantum chemistry Synthesis Synthesis and Properties of Inorganic Compounds Unsaturated |
| title | Synthesis and thermal conversions of unsaturated cobalt(II) dicarboxylates as precursors of metallopolymer nanocomposites |
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