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Influence of electrochemical copolymerization conditions of 3-methylthiophene and biphenyl on the morphology and nanomechanical properties of the films
ABSTRACT The aim of this work is to synthesize novel 3‐methylthiophene (3MTh)/biphenyl (Biph) copolymer films by electropolymerization and study their mechanical properties through nanoindentation. The morphology, the chemical structure as well as the electrical conductivity of the copolymer films d...
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Published in: | Journal of applied polymer science 2015-10, Vol.132 (38), p.np-n/a |
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creator | Triantou, Despina Soulis, Spyridon Perivoliotis, Dimitris Charitidis, Costas |
description | ABSTRACT
The aim of this work is to synthesize novel 3‐methylthiophene (3MTh)/biphenyl (Biph) copolymer films by electropolymerization and study their mechanical properties through nanoindentation. The morphology, the chemical structure as well as the electrical conductivity of the copolymer films depended strongly on the electropolymerization conditions. It was found that the polymer deposition follow an instantaneous, two‐dimensional nucleation and growth mechanism leading to homogenous films. The copolymer films had higher Young modulus and nanohardness than poly(3‐methylthiophene) (3PMTh), indicating that the incorporation of Biph units within the P3MTh chain leads to a more densely packed structure and a more brittle polymer. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015, 132, 42575. |
doi_str_mv | 10.1002/app.42575 |
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The aim of this work is to synthesize novel 3‐methylthiophene (3MTh)/biphenyl (Biph) copolymer films by electropolymerization and study their mechanical properties through nanoindentation. The morphology, the chemical structure as well as the electrical conductivity of the copolymer films depended strongly on the electropolymerization conditions. It was found that the polymer deposition follow an instantaneous, two‐dimensional nucleation and growth mechanism leading to homogenous films. The copolymer films had higher Young modulus and nanohardness than poly(3‐methylthiophene) (3PMTh), indicating that the incorporation of Biph units within the P3MTh chain leads to a more densely packed structure and a more brittle polymer. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015, 132, 42575.</description><identifier>ISSN: 0021-8995</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/app.42575</identifier><identifier>CODEN: JAPNAB</identifier><language>eng</language><publisher>Hoboken: Blackwell Publishing Ltd</publisher><subject>conducting polymers ; Copolymerization ; Copolymers ; Deposition ; Electrical resistivity ; Materials science ; Morphology ; nanostructured polymers ; Nucleation ; Polymerization ; Polymers ; Resistivity</subject><ispartof>Journal of applied polymer science, 2015-10, Vol.132 (38), p.np-n/a</ispartof><rights>2015 Wiley Periodicals, Inc.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4385-60c1babc2194b8d05b8ebccf64ee2f67420676c961c8f0e2604dbac5f0959f0b3</citedby><cites>FETCH-LOGICAL-c4385-60c1babc2194b8d05b8ebccf64ee2f67420676c961c8f0e2604dbac5f0959f0b3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fapp.42575$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fapp.42575$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>315,786,790,27957,27958,50923,51032</link.rule.ids></links><search><creatorcontrib>Triantou, Despina</creatorcontrib><creatorcontrib>Soulis, Spyridon</creatorcontrib><creatorcontrib>Perivoliotis, Dimitris</creatorcontrib><creatorcontrib>Charitidis, Costas</creatorcontrib><title>Influence of electrochemical copolymerization conditions of 3-methylthiophene and biphenyl on the morphology and nanomechanical properties of the films</title><title>Journal of applied polymer science</title><addtitle>J. Appl. Polym. Sci</addtitle><description>ABSTRACT
The aim of this work is to synthesize novel 3‐methylthiophene (3MTh)/biphenyl (Biph) copolymer films by electropolymerization and study their mechanical properties through nanoindentation. The morphology, the chemical structure as well as the electrical conductivity of the copolymer films depended strongly on the electropolymerization conditions. It was found that the polymer deposition follow an instantaneous, two‐dimensional nucleation and growth mechanism leading to homogenous films. The copolymer films had higher Young modulus and nanohardness than poly(3‐methylthiophene) (3PMTh), indicating that the incorporation of Biph units within the P3MTh chain leads to a more densely packed structure and a more brittle polymer. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015, 132, 42575.</description><subject>conducting polymers</subject><subject>Copolymerization</subject><subject>Copolymers</subject><subject>Deposition</subject><subject>Electrical resistivity</subject><subject>Materials science</subject><subject>Morphology</subject><subject>nanostructured polymers</subject><subject>Nucleation</subject><subject>Polymerization</subject><subject>Polymers</subject><subject>Resistivity</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNp1kc9u1DAQxi1UJJaFA28QiQscsrWd2EmOy6qUlVZQ8VfqxXK8Y-Li2KmdFaQv0tfF2QUOSD3NaOb3zYzmQ-gFwSuCMT2Xw7AqKavYI7QguKnyktP6DC1Sj-R107An6GmMNxgTwjBfoPut0_YATkHmdQYW1Bi86qA3StpM-cHbqYdg7uRovEsFtzdzFme8yHsYu8mOnfFDBw4y6fZZa-Z8slnixw6y3oeh89Z_n45tJ53vQXXSHVcMwQ8QRgPHiTOvje3jM_RYSxvh-Z-4RF_eXnzevMt3Hy63m_UuV2VRs5xjRVrZKkqasq33mLU1tEppXgJQzauSYl5x1XCiao2BclzuW6mYxg1rNG6LJXp1mpvuuD1AHEVvogJrpQN_iIJU6YmcpV8l9OV_6I0_BJeuE4Q3BeUVLepEvT5RKvgYA2gxBNPLMAmCxWyRSBaJo0WJPT-xP42F6WFQrK-u_iryk8LEEX79U8jwQ_CqSOS395fimtXk-uPXT-JN8RtiPaXj</recordid><startdate>20151010</startdate><enddate>20151010</enddate><creator>Triantou, Despina</creator><creator>Soulis, Spyridon</creator><creator>Perivoliotis, Dimitris</creator><creator>Charitidis, Costas</creator><general>Blackwell Publishing Ltd</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><scope>FR3</scope><scope>KR7</scope></search><sort><creationdate>20151010</creationdate><title>Influence of electrochemical copolymerization conditions of 3-methylthiophene and biphenyl on the morphology and nanomechanical properties of the films</title><author>Triantou, Despina ; Soulis, Spyridon ; Perivoliotis, Dimitris ; Charitidis, Costas</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4385-60c1babc2194b8d05b8ebccf64ee2f67420676c961c8f0e2604dbac5f0959f0b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>conducting polymers</topic><topic>Copolymerization</topic><topic>Copolymers</topic><topic>Deposition</topic><topic>Electrical resistivity</topic><topic>Materials science</topic><topic>Morphology</topic><topic>nanostructured polymers</topic><topic>Nucleation</topic><topic>Polymerization</topic><topic>Polymers</topic><topic>Resistivity</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Triantou, Despina</creatorcontrib><creatorcontrib>Soulis, Spyridon</creatorcontrib><creatorcontrib>Perivoliotis, Dimitris</creatorcontrib><creatorcontrib>Charitidis, Costas</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Engineering Research Database</collection><collection>Civil Engineering Abstracts</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Triantou, Despina</au><au>Soulis, Spyridon</au><au>Perivoliotis, Dimitris</au><au>Charitidis, Costas</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Influence of electrochemical copolymerization conditions of 3-methylthiophene and biphenyl on the morphology and nanomechanical properties of the films</atitle><jtitle>Journal of applied polymer science</jtitle><addtitle>J. Appl. Polym. Sci</addtitle><date>2015-10-10</date><risdate>2015</risdate><volume>132</volume><issue>38</issue><spage>np</spage><epage>n/a</epage><pages>np-n/a</pages><issn>0021-8995</issn><eissn>1097-4628</eissn><coden>JAPNAB</coden><notes>ArticleID:APP42575</notes><notes>ark:/67375/WNG-Z581ZRVS-B</notes><notes>istex:3EF63633C2FF4F4A7076011F07043595B8FB2D2E</notes><notes>ObjectType-Article-1</notes><notes>SourceType-Scholarly Journals-1</notes><notes>ObjectType-Feature-2</notes><notes>content type line 23</notes><abstract>ABSTRACT
The aim of this work is to synthesize novel 3‐methylthiophene (3MTh)/biphenyl (Biph) copolymer films by electropolymerization and study their mechanical properties through nanoindentation. The morphology, the chemical structure as well as the electrical conductivity of the copolymer films depended strongly on the electropolymerization conditions. It was found that the polymer deposition follow an instantaneous, two‐dimensional nucleation and growth mechanism leading to homogenous films. The copolymer films had higher Young modulus and nanohardness than poly(3‐methylthiophene) (3PMTh), indicating that the incorporation of Biph units within the P3MTh chain leads to a more densely packed structure and a more brittle polymer. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015, 132, 42575.</abstract><cop>Hoboken</cop><pub>Blackwell Publishing Ltd</pub><doi>10.1002/app.42575</doi><tpages>11</tpages></addata></record> |
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subjects | conducting polymers Copolymerization Copolymers Deposition Electrical resistivity Materials science Morphology nanostructured polymers Nucleation Polymerization Polymers Resistivity |
title | Influence of electrochemical copolymerization conditions of 3-methylthiophene and biphenyl on the morphology and nanomechanical properties of the films |
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