Loading…

Analytical Method for the Determination of Metolachlor, Acetochlor, Alachlor, Dimethenamid, and Their Corresponding Ethanesulfonic and Oxanillic Acid Degradates in Water Using SPE and LC/ESI-MS/MS

A Good Laboratory Practices (GLP) validated, multiresidue analytical method is presented for the determination of the chloroacetanilide herbicides metolachlor, acetochlor, and alachlor, the chloroacetamide herbicide dimethenamid, and their respective ethanesulfonic (ESA) and oxanillic (OA) acid degr...

Full description

Saved in:

Bibliographic Details
Published in:	Analytical chemistry (Washington) 2002-08, Vol.74 (15), p.3754-3759
Main Authors:	Yokley, Robert A, Mayer, Louis C, Huang, Sung-Ben, Vargo, John D
Format:	Article
Language:	English
Subjects:	Acetamides - analysis Acetanilides - analysis acetochlor alachlor Alkanesulfonates - analysis Analysis methods Analytical chemistry Applied sciences Chemistry Chromatographic methods and physical methods associated with chromatography Chromatography, High Pressure Liquid dimethenamid Exact sciences and technology Fresh Water - analysis Freshwater Herbicides - analysis Herbicides - standards metolachlor Natural water pollution Other chromatographic methods Oxamic Acid - analogs & derivatives Pollution Spectrometric and optical methods Spectrometry, Mass, Electrospray Ionization Toluidines - analysis Water Pollutants - analysis Water Pollutants - standards Water treatment and pollution
Citations:	Items that this one cites Items that cite this one
Online Access:	Get full text
Tags:	Add Tag No Tags, Be the first to tag this record!

cited_by	cdi_FETCH-LOGICAL-a410t-991252355742b0098aac782e8722b0ed8374db7909b01b866597ce16b8452c653
cites	cdi_FETCH-LOGICAL-a410t-991252355742b0098aac782e8722b0ed8374db7909b01b866597ce16b8452c653
container_end_page	3759
container_issue	15
container_start_page	3754
container_title	Analytical chemistry (Washington)
container_volume	74
creator	Yokley, Robert A Mayer, Louis C Huang, Sung-Ben Vargo, John D
description	A Good Laboratory Practices (GLP) validated, multiresidue analytical method is presented for the determination of the chloroacetanilide herbicides metolachlor, acetochlor, and alachlor, the chloroacetamide herbicide dimethenamid, and their respective ethanesulfonic (ESA) and oxanillic (OA) acid degradates in ground and surface water. A 50-mL water sample is subjected to purification using a C-18 SPE column. The four parent components and their eight ESA and OA degradates are isolated using 80/20 methanol/water (v/v) for elution. The eluate is reduced to
doi_str_mv	10.1021/ac020134q
format	article
fullrecord	<record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_16148993</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>16148993</sourcerecordid><originalsourceid>FETCH-LOGICAL-a410t-991252355742b0098aac782e8722b0ed8374db7909b01b866597ce16b8452c653</originalsourceid><addsrcrecordid>eNptktFu0zAUhiMEYmVwwQsg34CEtFDbSezksnRlTLRapXSCO8txnMXDsTvbkbb348Fw19LecOVzfL7zHx_9TpL3CH5BEKMpFxBDlOUPL5IJKjBMSVnil8kEQpilmEJ4lrzx_h5ChCAir5MzhBEtEMkmyZ-Z4fopKME1WMnQ2xZ01oHQS3Apg3SDMjwoa4DtdnWruei1dRdgJmL2Lz7eXqohikjDB9VeAG5asOmlcmBunZN-a02rzB1YhJ4b6UfdWaPEM3bzyI3SOmYzodo4-87xlgfpgTLgZwwcuPW73nq9eG5YzqeL-jpd1dNV_TZ51XHt5bvDeZ7cflts5t_T5c3V9Xy2THmOYEirCuECZ0VBc9xAWJWcC1piWVIcc9mWGc3bhlawaiBqSkKKigqJSFPmBRakyM6TT3vdrbMPo_SBDcoLqXXcxo6eIYLysqqyCH7eg8JZ753s2NapgbsnhiDbWcaOlkX2w0F0bAbZnsiDRxH4eAC4jzZ1jhuh_InLyrhSTiOX7jnlg3w81rn7zQjNaME265p9hdXVj19rwvBJlwvP7u3o4k_w_3ngX4RAuKI</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>16148993</pqid></control><display><type>article</type><title>Analytical Method for the Determination of Metolachlor, Acetochlor, Alachlor, Dimethenamid, and Their Corresponding Ethanesulfonic and Oxanillic Acid Degradates in Water Using SPE and LC/ESI-MS/MS</title><source>American Chemical Society:Jisc Collections:American Chemical Society Read & Publish Agreement 2022-2024 (Reading list)</source><creator>Yokley, Robert A ; Mayer, Louis C ; Huang, Sung-Ben ; Vargo, John D</creator><creatorcontrib>Yokley, Robert A ; Mayer, Louis C ; Huang, Sung-Ben ; Vargo, John D</creatorcontrib><description>A Good Laboratory Practices (GLP) validated, multiresidue analytical method is presented for the determination of the chloroacetanilide herbicides metolachlor, acetochlor, and alachlor, the chloroacetamide herbicide dimethenamid, and their respective ethanesulfonic (ESA) and oxanillic (OA) acid degradates in ground and surface water. A 50-mL water sample is subjected to purification using a C-18 SPE column. The four parent components and their eight ESA and OA degradates are isolated using 80/20 methanol/water (v/v) for elution. The eluate is reduced to <1.0 mL and reconstituted in 10/90 acetonitrile/water (v/v) to the desired final fraction volume. Final analysis is accomplished using liquid chromatography/electrospray ionization-mass spectrometry/mass spectrometry in the + (parent compounds) and − (ESA and OA degradates) ion modes by monitoring appropriate precursor/product ion pairs for each of the 12 analytes. The method limit of quantification is 0.10 ppb and the limit of detection is 0.125 ng injected for each analyte. Average procedural recovery data range from 95 to 105% for fortification levels of 0.10−100 ppb. The method validation study was performed following GLP guidelines.</description><identifier>ISSN: 0003-2700</identifier><identifier>EISSN: 1520-6882</identifier><identifier>DOI: 10.1021/ac020134q</identifier><identifier>PMID: 12175163</identifier><identifier>CODEN: ANCHAM</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>Acetamides - analysis ; Acetanilides - analysis ; acetochlor ; alachlor ; Alkanesulfonates - analysis ; Analysis methods ; Analytical chemistry ; Applied sciences ; Chemistry ; Chromatographic methods and physical methods associated with chromatography ; Chromatography, High Pressure Liquid ; dimethenamid ; Exact sciences and technology ; Fresh Water - analysis ; Freshwater ; Herbicides - analysis ; Herbicides - standards ; metolachlor ; Natural water pollution ; Other chromatographic methods ; Oxamic Acid - analogs & derivatives ; Pollution ; Spectrometric and optical methods ; Spectrometry, Mass, Electrospray Ionization ; Toluidines - analysis ; Water Pollutants - analysis ; Water Pollutants - standards ; Water treatment and pollution</subject><ispartof>Analytical chemistry (Washington), 2002-08, Vol.74 (15), p.3754-3759</ispartof><rights>Copyright © 2002 American Chemical Society</rights><rights>2002 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a410t-991252355742b0098aac782e8722b0ed8374db7909b01b866597ce16b8452c653</citedby><cites>FETCH-LOGICAL-a410t-991252355742b0098aac782e8722b0ed8374db7909b01b866597ce16b8452c653</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>315,786,790,27957,27958</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=13835547$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/12175163$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Yokley, Robert A</creatorcontrib><creatorcontrib>Mayer, Louis C</creatorcontrib><creatorcontrib>Huang, Sung-Ben</creatorcontrib><creatorcontrib>Vargo, John D</creatorcontrib><title>Analytical Method for the Determination of Metolachlor, Acetochlor, Alachlor, Dimethenamid, and Their Corresponding Ethanesulfonic and Oxanillic Acid Degradates in Water Using SPE and LC/ESI-MS/MS</title><title>Analytical chemistry (Washington)</title><addtitle>Anal. Chem</addtitle><description>A Good Laboratory Practices (GLP) validated, multiresidue analytical method is presented for the determination of the chloroacetanilide herbicides metolachlor, acetochlor, and alachlor, the chloroacetamide herbicide dimethenamid, and their respective ethanesulfonic (ESA) and oxanillic (OA) acid degradates in ground and surface water. A 50-mL water sample is subjected to purification using a C-18 SPE column. The four parent components and their eight ESA and OA degradates are isolated using 80/20 methanol/water (v/v) for elution. The eluate is reduced to <1.0 mL and reconstituted in 10/90 acetonitrile/water (v/v) to the desired final fraction volume. Final analysis is accomplished using liquid chromatography/electrospray ionization-mass spectrometry/mass spectrometry in the + (parent compounds) and − (ESA and OA degradates) ion modes by monitoring appropriate precursor/product ion pairs for each of the 12 analytes. The method limit of quantification is 0.10 ppb and the limit of detection is 0.125 ng injected for each analyte. Average procedural recovery data range from 95 to 105% for fortification levels of 0.10−100 ppb. The method validation study was performed following GLP guidelines.</description><subject>Acetamides - analysis</subject><subject>Acetanilides - analysis</subject><subject>acetochlor</subject><subject>alachlor</subject><subject>Alkanesulfonates - analysis</subject><subject>Analysis methods</subject><subject>Analytical chemistry</subject><subject>Applied sciences</subject><subject>Chemistry</subject><subject>Chromatographic methods and physical methods associated with chromatography</subject><subject>Chromatography, High Pressure Liquid</subject><subject>dimethenamid</subject><subject>Exact sciences and technology</subject><subject>Fresh Water - analysis</subject><subject>Freshwater</subject><subject>Herbicides - analysis</subject><subject>Herbicides - standards</subject><subject>metolachlor</subject><subject>Natural water pollution</subject><subject>Other chromatographic methods</subject><subject>Oxamic Acid - analogs & derivatives</subject><subject>Pollution</subject><subject>Spectrometric and optical methods</subject><subject>Spectrometry, Mass, Electrospray Ionization</subject><subject>Toluidines - analysis</subject><subject>Water Pollutants - analysis</subject><subject>Water Pollutants - standards</subject><subject>Water treatment and pollution</subject><issn>0003-2700</issn><issn>1520-6882</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2002</creationdate><recordtype>article</recordtype><recordid>eNptktFu0zAUhiMEYmVwwQsg34CEtFDbSezksnRlTLRapXSCO8txnMXDsTvbkbb348Fw19LecOVzfL7zHx_9TpL3CH5BEKMpFxBDlOUPL5IJKjBMSVnil8kEQpilmEJ4lrzx_h5ChCAir5MzhBEtEMkmyZ-Z4fopKME1WMnQ2xZ01oHQS3Apg3SDMjwoa4DtdnWruei1dRdgJmL2Lz7eXqohikjDB9VeAG5asOmlcmBunZN-a02rzB1YhJ4b6UfdWaPEM3bzyI3SOmYzodo4-87xlgfpgTLgZwwcuPW73nq9eG5YzqeL-jpd1dNV_TZ51XHt5bvDeZ7cflts5t_T5c3V9Xy2THmOYEirCuECZ0VBc9xAWJWcC1piWVIcc9mWGc3bhlawaiBqSkKKigqJSFPmBRakyM6TT3vdrbMPo_SBDcoLqXXcxo6eIYLysqqyCH7eg8JZ753s2NapgbsnhiDbWcaOlkX2w0F0bAbZnsiDRxH4eAC4jzZ1jhuh_InLyrhSTiOX7jnlg3w81rn7zQjNaME265p9hdXVj19rwvBJlwvP7u3o4k_w_3ngX4RAuKI</recordid><startdate>20020801</startdate><enddate>20020801</enddate><creator>Yokley, Robert A</creator><creator>Mayer, Louis C</creator><creator>Huang, Sung-Ben</creator><creator>Vargo, John D</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QH</scope><scope>7TV</scope><scope>7UA</scope><scope>C1K</scope><scope>F1W</scope><scope>H97</scope><scope>L.G</scope></search><sort><creationdate>20020801</creationdate><title>Analytical Method for the Determination of Metolachlor, Acetochlor, Alachlor, Dimethenamid, and Their Corresponding Ethanesulfonic and Oxanillic Acid Degradates in Water Using SPE and LC/ESI-MS/MS</title><author>Yokley, Robert A ; Mayer, Louis C ; Huang, Sung-Ben ; Vargo, John D</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a410t-991252355742b0098aac782e8722b0ed8374db7909b01b866597ce16b8452c653</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2002</creationdate><topic>Acetamides - analysis</topic><topic>Acetanilides - analysis</topic><topic>acetochlor</topic><topic>alachlor</topic><topic>Alkanesulfonates - analysis</topic><topic>Analysis methods</topic><topic>Analytical chemistry</topic><topic>Applied sciences</topic><topic>Chemistry</topic><topic>Chromatographic methods and physical methods associated with chromatography</topic><topic>Chromatography, High Pressure Liquid</topic><topic>dimethenamid</topic><topic>Exact sciences and technology</topic><topic>Fresh Water - analysis</topic><topic>Freshwater</topic><topic>Herbicides - analysis</topic><topic>Herbicides - standards</topic><topic>metolachlor</topic><topic>Natural water pollution</topic><topic>Other chromatographic methods</topic><topic>Oxamic Acid - analogs & derivatives</topic><topic>Pollution</topic><topic>Spectrometric and optical methods</topic><topic>Spectrometry, Mass, Electrospray Ionization</topic><topic>Toluidines - analysis</topic><topic>Water Pollutants - analysis</topic><topic>Water Pollutants - standards</topic><topic>Water treatment and pollution</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yokley, Robert A</creatorcontrib><creatorcontrib>Mayer, Louis C</creatorcontrib><creatorcontrib>Huang, Sung-Ben</creatorcontrib><creatorcontrib>Vargo, John D</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Aqualine</collection><collection>Pollution Abstracts</collection><collection>Water Resources Abstracts</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ASFA: Aquatic Sciences and Fisheries Abstracts</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) 3: Aquatic Pollution & Environmental Quality</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) Professional</collection><jtitle>Analytical chemistry (Washington)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yokley, Robert A</au><au>Mayer, Louis C</au><au>Huang, Sung-Ben</au><au>Vargo, John D</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Analytical Method for the Determination of Metolachlor, Acetochlor, Alachlor, Dimethenamid, and Their Corresponding Ethanesulfonic and Oxanillic Acid Degradates in Water Using SPE and LC/ESI-MS/MS</atitle><jtitle>Analytical chemistry (Washington)</jtitle><addtitle>Anal. Chem</addtitle><date>2002-08-01</date><risdate>2002</risdate><volume>74</volume><issue>15</issue><spage>3754</spage><epage>3759</epage><pages>3754-3759</pages><issn>0003-2700</issn><eissn>1520-6882</eissn><coden>ANCHAM</coden><notes>istex:2707123CCB749A33EBFEC60423873BEDF877392B</notes><notes>ark:/67375/TPS-B09GKXP6-2</notes><notes>ObjectType-Article-2</notes><notes>SourceType-Scholarly Journals-1</notes><notes>ObjectType-Feature-1</notes><notes>content type line 23</notes><abstract>A Good Laboratory Practices (GLP) validated, multiresidue analytical method is presented for the determination of the chloroacetanilide herbicides metolachlor, acetochlor, and alachlor, the chloroacetamide herbicide dimethenamid, and their respective ethanesulfonic (ESA) and oxanillic (OA) acid degradates in ground and surface water. A 50-mL water sample is subjected to purification using a C-18 SPE column. The four parent components and their eight ESA and OA degradates are isolated using 80/20 methanol/water (v/v) for elution. The eluate is reduced to <1.0 mL and reconstituted in 10/90 acetonitrile/water (v/v) to the desired final fraction volume. Final analysis is accomplished using liquid chromatography/electrospray ionization-mass spectrometry/mass spectrometry in the + (parent compounds) and − (ESA and OA degradates) ion modes by monitoring appropriate precursor/product ion pairs for each of the 12 analytes. The method limit of quantification is 0.10 ppb and the limit of detection is 0.125 ng injected for each analyte. Average procedural recovery data range from 95 to 105% for fortification levels of 0.10−100 ppb. The method validation study was performed following GLP guidelines.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><pmid>12175163</pmid><doi>10.1021/ac020134q</doi><tpages>6</tpages></addata></record>
fulltext	fulltext
identifier	ISSN: 0003-2700
ispartof	Analytical chemistry (Washington), 2002-08, Vol.74 (15), p.3754-3759
issn	0003-2700 1520-6882
language	eng
recordid	cdi_proquest_miscellaneous_16148993
source	American Chemical Society:Jisc Collections:American Chemical Society Read & Publish Agreement 2022-2024 (Reading list)
subjects	Acetamides - analysis Acetanilides - analysis acetochlor alachlor Alkanesulfonates - analysis Analysis methods Analytical chemistry Applied sciences Chemistry Chromatographic methods and physical methods associated with chromatography Chromatography, High Pressure Liquid dimethenamid Exact sciences and technology Fresh Water - analysis Freshwater Herbicides - analysis Herbicides - standards metolachlor Natural water pollution Other chromatographic methods Oxamic Acid - analogs & derivatives Pollution Spectrometric and optical methods Spectrometry, Mass, Electrospray Ionization Toluidines - analysis Water Pollutants - analysis Water Pollutants - standards Water treatment and pollution
title	Analytical Method for the Determination of Metolachlor, Acetochlor, Alachlor, Dimethenamid, and Their Corresponding Ethanesulfonic and Oxanillic Acid Degradates in Water Using SPE and LC/ESI-MS/MS
url	http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-09-22T14%3A20%3A53IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Analytical%20Method%20for%20the%20Determination%20of%20Metolachlor,%20Acetochlor,%20Alachlor,%20Dimethenamid,%20and%20Their%20Corresponding%20Ethanesulfonic%20and%20Oxanillic%20Acid%20Degradates%20in%20Water%20Using%20SPE%20and%20LC/ESI-MS/MS&rft.jtitle=Analytical%20chemistry%20(Washington)&rft.au=Yokley,%20Robert%20A&rft.date=2002-08-01&rft.volume=74&rft.issue=15&rft.spage=3754&rft.epage=3759&rft.pages=3754-3759&rft.issn=0003-2700&rft.eissn=1520-6882&rft.coden=ANCHAM&rft_id=info:doi/10.1021/ac020134q&rft_dat=%3Cproquest_cross%3E16148993%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-a410t-991252355742b0098aac782e8722b0ed8374db7909b01b866597ce16b8452c653%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=16148993&rft_id=info:pmid/12175163&rfr_iscdi=true