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A reagentless thermal post-synthetic rearrangement of an allyloxy-tagged metal-organic framework
Direct heating of a metal-organic framework provides a simple, controllable way of effecting a covalent post-synthetic modification. Herein we report that an allyloxy-tagged zinc metal-organic framework undergoes a thermally-promoted aromatic Claisen rearrangement through which the framework connect...
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Published in: | Chemical communications (Cambridge, England) England), 2013-01, Vol.49 (10), p.990-992 |
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Main Authors: | , , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | Direct heating of a metal-organic framework provides a simple, controllable way of effecting a covalent post-synthetic modification. Herein we report that an allyloxy-tagged zinc metal-organic framework undergoes a thermally-promoted aromatic Claisen rearrangement through which the framework connectivity and porosity are maintained. |
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ISSN: | 1359-7345 1364-548X |
DOI: | 10.1039/c2cc38176a |