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One-step controlled electrodeposition nickel sulfides heterointerfaces favoring the desorption of hydroxyl groups for efficient hydrogen generation
The heterointerface engineering involving different components or phases represents a desirable strategy for enhancing the sluggish kinetics of hydrogen evolution reaction (HER). However, constructing desired heterointerfaces and elucidating the reaction mechanisms on the interface remains a conside...
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| Published in: | Rare metals 2024-09, Vol.43 (9), p.4377-4386 |
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| Main Authors: | , , , , , , , , |
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| container_end_page | 4386 |
| container_issue | 9 |
| container_start_page | 4377 |
| container_title | Rare metals |
| container_volume | 43 |
| creator | Li, Ru-Chun Zhang, Xin-Yue Qu, Ze-Yue Liu, Feng-Yi Xu, Quan-Qing Hu, Zhao-Xia Li, Jing-Wei Ghazzal, Mohamed-Nawfal Yu, Jin-Li |
| description | The heterointerface engineering involving different components or phases represents a desirable strategy for enhancing the sluggish kinetics of hydrogen evolution reaction (HER). However, constructing desired heterointerfaces and elucidating the reaction mechanisms on the interface remains a considerable challenge. In this work, we propose a straightforward electrochemical synthesis strategy to prepare the nickel sulfide-based heterointerfaces for HER. The mechanism of electrochemical synthesis is revealed, wherein metal-thiourea species can be formed at the cathode potential and subsequently oxidized to nickel sulfides at the anode potentials. Leveraging this mechanism, a range of nickel sulfides, including NiS, Ni
3
S
2
/NiS, Ni/Ni
3
S
2
and Ni
3
S
2
, have been successfully synthesized by tuning the potential range of cyclic voltammetry. Among these, the obtained Ni
3
S
2
/NiS@CC (CC: carbon cloth) exhibits the smallest overpotential of 84 mV at 10 mA·cm
−2
and high stability. Theoretical calculations further reveal that the combination of NiS and Ni
3
S
2
induces electron redistribution at the interface, and thus the Volmer process is effectively promoted with faster water dissociation and OH desorption kinetics. Significantly, the simplicity method coupled with a clear synthesis mechanism and outstanding HER performance highlights its promising potential for practical applications.
Graphical abstract |
| doi_str_mv | 10.1007/s12598-024-02806-6 |
| format | article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_3086898308</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>3086898308</sourcerecordid><originalsourceid>FETCH-LOGICAL-c200t-44b9dbe4117140395ca65550655a8e39ff55f3810266dabf7c978854c9032f5e3</originalsourceid><addsrcrecordid>eNp9kMtOwzAQRSMEEqXwA6wssTaMk9hxlqjiJSF1A2srdcatS7CDnSD6HfwwboPEjsU8NHPPjHSz7JLBNQOobiLLeS0p5GUKCYKKo2zGpKhoxSQ_Tj0Ao8BzdpqdxbgFKEshYJZ9Lx3SOGBPtHdD8F2HLcEOdepb7H20g_WOOKvfsCNx7IxtMZINDhi8dSmbRqeBaT59sG5Nhg2SpPChP4DekM2uDf5r15F18GOfpD4QNMZqi26Ytmt0JAWGZg-dZyem6SJe_NZ59np_97J4pM_Lh6fF7TPVOcBAy3JVtyssGatYCUXNdSM455BSI7GojeHcFJJBLkTbrEyl60pKXuoaitxwLObZ1XS3D_5jxDiorR-DSy9VAVLIWqaSVPmk0sHHGNCoPtj3JuwUA7U3X03mq2S-OpivRIKKCYr93hUMf6f_oX4AQoSLkA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>3086898308</pqid></control><display><type>article</type><title>One-step controlled electrodeposition nickel sulfides heterointerfaces favoring the desorption of hydroxyl groups for efficient hydrogen generation</title><source>Springer Link</source><creator>Li, Ru-Chun ; Zhang, Xin-Yue ; Qu, Ze-Yue ; Liu, Feng-Yi ; Xu, Quan-Qing ; Hu, Zhao-Xia ; Li, Jing-Wei ; Ghazzal, Mohamed-Nawfal ; Yu, Jin-Li</creator><creatorcontrib>Li, Ru-Chun ; Zhang, Xin-Yue ; Qu, Ze-Yue ; Liu, Feng-Yi ; Xu, Quan-Qing ; Hu, Zhao-Xia ; Li, Jing-Wei ; Ghazzal, Mohamed-Nawfal ; Yu, Jin-Li</creatorcontrib><description>The heterointerface engineering involving different components or phases represents a desirable strategy for enhancing the sluggish kinetics of hydrogen evolution reaction (HER). However, constructing desired heterointerfaces and elucidating the reaction mechanisms on the interface remains a considerable challenge. In this work, we propose a straightforward electrochemical synthesis strategy to prepare the nickel sulfide-based heterointerfaces for HER. The mechanism of electrochemical synthesis is revealed, wherein metal-thiourea species can be formed at the cathode potential and subsequently oxidized to nickel sulfides at the anode potentials. Leveraging this mechanism, a range of nickel sulfides, including NiS, Ni
3
S
2
/NiS, Ni/Ni
3
S
2
and Ni
3
S
2
, have been successfully synthesized by tuning the potential range of cyclic voltammetry. Among these, the obtained Ni
3
S
2
/NiS@CC (CC: carbon cloth) exhibits the smallest overpotential of 84 mV at 10 mA·cm
−2
and high stability. Theoretical calculations further reveal that the combination of NiS and Ni
3
S
2
induces electron redistribution at the interface, and thus the Volmer process is effectively promoted with faster water dissociation and OH desorption kinetics. Significantly, the simplicity method coupled with a clear synthesis mechanism and outstanding HER performance highlights its promising potential for practical applications.
Graphical abstract</description><identifier>ISSN: 1001-0521</identifier><identifier>EISSN: 1867-7185</identifier><identifier>DOI: 10.1007/s12598-024-02806-6</identifier><language>eng</language><publisher>Beijing: Nonferrous Metals Society of China</publisher><subject>Biomaterials ; Chemical synthesis ; Chemistry and Materials Science ; Desorption ; Energy ; Hydrogen evolution reactions ; Hydrogen production ; Hydroxyl groups ; Kinetics ; Materials Engineering ; Materials Science ; Metallic Materials ; Nanoscale Science and Technology ; Nickel ; Nickel sulfide ; Original Article ; Physical Chemistry ; Reaction mechanisms ; Sulfides</subject><ispartof>Rare metals, 2024-09, Vol.43 (9), p.4377-4386</ispartof><rights>Youke Publishing Co.,Ltd 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c200t-44b9dbe4117140395ca65550655a8e39ff55f3810266dabf7c978854c9032f5e3</cites><orcidid>0000-0003-1892-0844 ; 0000-0002-2353-8773 ; 0009-0007-2080-8161</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>315,786,790,27957,27958</link.rule.ids></links><search><creatorcontrib>Li, Ru-Chun</creatorcontrib><creatorcontrib>Zhang, Xin-Yue</creatorcontrib><creatorcontrib>Qu, Ze-Yue</creatorcontrib><creatorcontrib>Liu, Feng-Yi</creatorcontrib><creatorcontrib>Xu, Quan-Qing</creatorcontrib><creatorcontrib>Hu, Zhao-Xia</creatorcontrib><creatorcontrib>Li, Jing-Wei</creatorcontrib><creatorcontrib>Ghazzal, Mohamed-Nawfal</creatorcontrib><creatorcontrib>Yu, Jin-Li</creatorcontrib><title>One-step controlled electrodeposition nickel sulfides heterointerfaces favoring the desorption of hydroxyl groups for efficient hydrogen generation</title><title>Rare metals</title><addtitle>Rare Met</addtitle><description>The heterointerface engineering involving different components or phases represents a desirable strategy for enhancing the sluggish kinetics of hydrogen evolution reaction (HER). However, constructing desired heterointerfaces and elucidating the reaction mechanisms on the interface remains a considerable challenge. In this work, we propose a straightforward electrochemical synthesis strategy to prepare the nickel sulfide-based heterointerfaces for HER. The mechanism of electrochemical synthesis is revealed, wherein metal-thiourea species can be formed at the cathode potential and subsequently oxidized to nickel sulfides at the anode potentials. Leveraging this mechanism, a range of nickel sulfides, including NiS, Ni
3
S
2
/NiS, Ni/Ni
3
S
2
and Ni
3
S
2
, have been successfully synthesized by tuning the potential range of cyclic voltammetry. Among these, the obtained Ni
3
S
2
/NiS@CC (CC: carbon cloth) exhibits the smallest overpotential of 84 mV at 10 mA·cm
−2
and high stability. Theoretical calculations further reveal that the combination of NiS and Ni
3
S
2
induces electron redistribution at the interface, and thus the Volmer process is effectively promoted with faster water dissociation and OH desorption kinetics. Significantly, the simplicity method coupled with a clear synthesis mechanism and outstanding HER performance highlights its promising potential for practical applications.
Graphical abstract</description><subject>Biomaterials</subject><subject>Chemical synthesis</subject><subject>Chemistry and Materials Science</subject><subject>Desorption</subject><subject>Energy</subject><subject>Hydrogen evolution reactions</subject><subject>Hydrogen production</subject><subject>Hydroxyl groups</subject><subject>Kinetics</subject><subject>Materials Engineering</subject><subject>Materials Science</subject><subject>Metallic Materials</subject><subject>Nanoscale Science and Technology</subject><subject>Nickel</subject><subject>Nickel sulfide</subject><subject>Original Article</subject><subject>Physical Chemistry</subject><subject>Reaction mechanisms</subject><subject>Sulfides</subject><issn>1001-0521</issn><issn>1867-7185</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNp9kMtOwzAQRSMEEqXwA6wssTaMk9hxlqjiJSF1A2srdcatS7CDnSD6HfwwboPEjsU8NHPPjHSz7JLBNQOobiLLeS0p5GUKCYKKo2zGpKhoxSQ_Tj0Ao8BzdpqdxbgFKEshYJZ9Lx3SOGBPtHdD8F2HLcEOdepb7H20g_WOOKvfsCNx7IxtMZINDhi8dSmbRqeBaT59sG5Nhg2SpPChP4DekM2uDf5r15F18GOfpD4QNMZqi26Ytmt0JAWGZg-dZyem6SJe_NZ59np_97J4pM_Lh6fF7TPVOcBAy3JVtyssGatYCUXNdSM455BSI7GojeHcFJJBLkTbrEyl60pKXuoaitxwLObZ1XS3D_5jxDiorR-DSy9VAVLIWqaSVPmk0sHHGNCoPtj3JuwUA7U3X03mq2S-OpivRIKKCYr93hUMf6f_oX4AQoSLkA</recordid><startdate>20240901</startdate><enddate>20240901</enddate><creator>Li, Ru-Chun</creator><creator>Zhang, Xin-Yue</creator><creator>Qu, Ze-Yue</creator><creator>Liu, Feng-Yi</creator><creator>Xu, Quan-Qing</creator><creator>Hu, Zhao-Xia</creator><creator>Li, Jing-Wei</creator><creator>Ghazzal, Mohamed-Nawfal</creator><creator>Yu, Jin-Li</creator><general>Nonferrous Metals Society of China</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0003-1892-0844</orcidid><orcidid>https://orcid.org/0000-0002-2353-8773</orcidid><orcidid>https://orcid.org/0009-0007-2080-8161</orcidid></search><sort><creationdate>20240901</creationdate><title>One-step controlled electrodeposition nickel sulfides heterointerfaces favoring the desorption of hydroxyl groups for efficient hydrogen generation</title><author>Li, Ru-Chun ; Zhang, Xin-Yue ; Qu, Ze-Yue ; Liu, Feng-Yi ; Xu, Quan-Qing ; Hu, Zhao-Xia ; Li, Jing-Wei ; Ghazzal, Mohamed-Nawfal ; Yu, Jin-Li</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c200t-44b9dbe4117140395ca65550655a8e39ff55f3810266dabf7c978854c9032f5e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Biomaterials</topic><topic>Chemical synthesis</topic><topic>Chemistry and Materials Science</topic><topic>Desorption</topic><topic>Energy</topic><topic>Hydrogen evolution reactions</topic><topic>Hydrogen production</topic><topic>Hydroxyl groups</topic><topic>Kinetics</topic><topic>Materials Engineering</topic><topic>Materials Science</topic><topic>Metallic Materials</topic><topic>Nanoscale Science and Technology</topic><topic>Nickel</topic><topic>Nickel sulfide</topic><topic>Original Article</topic><topic>Physical Chemistry</topic><topic>Reaction mechanisms</topic><topic>Sulfides</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Li, Ru-Chun</creatorcontrib><creatorcontrib>Zhang, Xin-Yue</creatorcontrib><creatorcontrib>Qu, Ze-Yue</creatorcontrib><creatorcontrib>Liu, Feng-Yi</creatorcontrib><creatorcontrib>Xu, Quan-Qing</creatorcontrib><creatorcontrib>Hu, Zhao-Xia</creatorcontrib><creatorcontrib>Li, Jing-Wei</creatorcontrib><creatorcontrib>Ghazzal, Mohamed-Nawfal</creatorcontrib><creatorcontrib>Yu, Jin-Li</creatorcontrib><collection>CrossRef</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Rare metals</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Li, Ru-Chun</au><au>Zhang, Xin-Yue</au><au>Qu, Ze-Yue</au><au>Liu, Feng-Yi</au><au>Xu, Quan-Qing</au><au>Hu, Zhao-Xia</au><au>Li, Jing-Wei</au><au>Ghazzal, Mohamed-Nawfal</au><au>Yu, Jin-Li</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>One-step controlled electrodeposition nickel sulfides heterointerfaces favoring the desorption of hydroxyl groups for efficient hydrogen generation</atitle><jtitle>Rare metals</jtitle><stitle>Rare Met</stitle><date>2024-09-01</date><risdate>2024</risdate><volume>43</volume><issue>9</issue><spage>4377</spage><epage>4386</epage><pages>4377-4386</pages><issn>1001-0521</issn><eissn>1867-7185</eissn><abstract>The heterointerface engineering involving different components or phases represents a desirable strategy for enhancing the sluggish kinetics of hydrogen evolution reaction (HER). However, constructing desired heterointerfaces and elucidating the reaction mechanisms on the interface remains a considerable challenge. In this work, we propose a straightforward electrochemical synthesis strategy to prepare the nickel sulfide-based heterointerfaces for HER. The mechanism of electrochemical synthesis is revealed, wherein metal-thiourea species can be formed at the cathode potential and subsequently oxidized to nickel sulfides at the anode potentials. Leveraging this mechanism, a range of nickel sulfides, including NiS, Ni
3
S
2
/NiS, Ni/Ni
3
S
2
and Ni
3
S
2
, have been successfully synthesized by tuning the potential range of cyclic voltammetry. Among these, the obtained Ni
3
S
2
/NiS@CC (CC: carbon cloth) exhibits the smallest overpotential of 84 mV at 10 mA·cm
−2
and high stability. Theoretical calculations further reveal that the combination of NiS and Ni
3
S
2
induces electron redistribution at the interface, and thus the Volmer process is effectively promoted with faster water dissociation and OH desorption kinetics. Significantly, the simplicity method coupled with a clear synthesis mechanism and outstanding HER performance highlights its promising potential for practical applications.
Graphical abstract</abstract><cop>Beijing</cop><pub>Nonferrous Metals Society of China</pub><doi>10.1007/s12598-024-02806-6</doi><tpages>10</tpages><orcidid>https://orcid.org/0000-0003-1892-0844</orcidid><orcidid>https://orcid.org/0000-0002-2353-8773</orcidid><orcidid>https://orcid.org/0009-0007-2080-8161</orcidid></addata></record> |
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| language | eng |
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| subjects | Biomaterials Chemical synthesis Chemistry and Materials Science Desorption Energy Hydrogen evolution reactions Hydrogen production Hydroxyl groups Kinetics Materials Engineering Materials Science Metallic Materials Nanoscale Science and Technology Nickel Nickel sulfide Original Article Physical Chemistry Reaction mechanisms Sulfides |
| title | One-step controlled electrodeposition nickel sulfides heterointerfaces favoring the desorption of hydroxyl groups for efficient hydrogen generation |
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