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Single‐crystal‐to‐single‐crystal transformation of a two‐dimensional noninterpenetrated layer to a microporous three‐dimensional fourfold interpenetrated MOF triggered by DMF
We have demonstrated a single‐crystal‐to‐single‐crystal (SCSC) transformation from a two‐dimensional noninterpenetrated layer to a microporous three‐dimensional fourfold interpenetrated MOF. The centrosymmetric [Co2(μ2‐OH)(EIBA)3]n (SNUT‐25) transforms into a microporous [Co(EIBA)2]n (SNUT‐26), whic...
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Published in: | Applied organometallic chemistry 2024-08, Vol.38 (8), p.n/a |
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description | We have demonstrated a single‐crystal‐to‐single‐crystal (SCSC) transformation from a two‐dimensional noninterpenetrated layer to a microporous three‐dimensional fourfold interpenetrated MOF. The centrosymmetric [Co2(μ2‐OH)(EIBA)3]n (SNUT‐25) transforms into a microporous [Co(EIBA)2]n (SNUT‐26), which is triggered by the reaction time with DMF that acts as a structure‐directing agent (HEIBA = 4‐(2‐ethyl‐1H‐imidazol‐1‐yl)benzoic acid; DMF = N,N′‐dimethylformamide). Despite the distinct structure and coordination arrangements of SNUT‐25 in contrast to SNUT‐26, both Co‐MOFs were synthesized using the same ligand. Fascinatingly, upon introducing a specific quantity of DMF combined with a negligible proportion of nitric acid, SNUT‐25 will progressively and completely transform into SNUT‐26. Under the synergistic induction of solvent molecules and temperature, SNUT‐25 changed from the original two‐dimensional layered structure to the three‐dimensional pore structure of SNUT‐26. In addition, SNUT‐25 and SNUT‐26 are efficient photocatalysts for the degradation of organic dye methyl blue (MB) under visible light irradiation. Surprisingly, the degradation rates of both SNUT‐25 and SNUT‐26 can reach over 96%. In addition, SNUT‐25 and SNUT‐26 also exhibited high electrocatalytic oxygen evolution reaction.
We have successfully recorded the single crystal to single crystal (SCSC) transition from two‐dimensional non interpenetrating layers (SNUT‐25) to microporous three‐dimensional quadruple interpenetrating MOFs (SNUT‐26). Both SNUT‐25 and SNUT‐26 exhibit excellent electrocatalytic and photocatalytic performance. |
doi_str_mv | 10.1002/aoc.7590 |
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We have successfully recorded the single crystal to single crystal (SCSC) transition from two‐dimensional non interpenetrating layers (SNUT‐25) to microporous three‐dimensional quadruple interpenetrating MOFs (SNUT‐26). Both SNUT‐25 and SNUT‐26 exhibit excellent electrocatalytic and photocatalytic performance.</description><identifier>ISSN: 0268-2605</identifier><identifier>EISSN: 1099-0739</identifier><identifier>DOI: 10.1002/aoc.7590</identifier><language>eng</language><publisher>Chichester: Wiley Subscription Services, Inc</publisher><subject>Benzoic acid ; Chemical synthesis ; crystal structure ; Crystals ; Dimensional changes ; Dimethylformamide ; electrocatalytic ; Light irradiation ; Metal-organic frameworks ; Molecular structure ; Nitric acid ; Oxygen evolution reactions ; photocatalytic activity ; Photodegradation ; solvothermal ; syntheses</subject><ispartof>Applied organometallic chemistry, 2024-08, Vol.38 (8), p.n/a</ispartof><rights>2024 John Wiley & Sons Ltd.</rights><rights>2024 John Wiley & Sons, Ltd.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c1840-e90075c1fc5370f71138f0998064283ed519808cc01bad79375491eb7728cd813</cites><orcidid>0009-0003-3131-0562 ; 0009-0005-4307-7459 ; 0009-0004-8263-6295 ; 0009-0002-7373-8391 ; 0000-0003-2645-0512 ; 0009-0007-5092-6935 ; 0000-0001-7876-4674 ; 0000-0001-7869-8021 ; 0000-0002-2668-7475</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Faoc.7590$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Faoc.7590$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>315,786,790,27957,27958,50923,51032</link.rule.ids></links><search><creatorcontrib>Huang, Pei‐Pei</creatorcontrib><creatorcontrib>Wu, Ting‐Ting</creatorcontrib><creatorcontrib>Tuo, Meng‐Qi</creatorcontrib><creatorcontrib>Pan, Hui‐Bin</creatorcontrib><creatorcontrib>Yue, Si‐Yu</creatorcontrib><creatorcontrib>Huang, Pei</creatorcontrib><creatorcontrib>Gao, Yan‐Hong</creatorcontrib><creatorcontrib>Lu, Jiu‐Fu</creatorcontrib><creatorcontrib>Jin, Ling‐Xia</creatorcontrib><title>Single‐crystal‐to‐single‐crystal transformation of a two‐dimensional noninterpenetrated layer to a microporous three‐dimensional fourfold interpenetrated MOF triggered by DMF</title><title>Applied organometallic chemistry</title><description>We have demonstrated a single‐crystal‐to‐single‐crystal (SCSC) transformation from a two‐dimensional noninterpenetrated layer to a microporous three‐dimensional fourfold interpenetrated MOF. The centrosymmetric [Co2(μ2‐OH)(EIBA)3]n (SNUT‐25) transforms into a microporous [Co(EIBA)2]n (SNUT‐26), which is triggered by the reaction time with DMF that acts as a structure‐directing agent (HEIBA = 4‐(2‐ethyl‐1H‐imidazol‐1‐yl)benzoic acid; DMF = N,N′‐dimethylformamide). Despite the distinct structure and coordination arrangements of SNUT‐25 in contrast to SNUT‐26, both Co‐MOFs were synthesized using the same ligand. Fascinatingly, upon introducing a specific quantity of DMF combined with a negligible proportion of nitric acid, SNUT‐25 will progressively and completely transform into SNUT‐26. Under the synergistic induction of solvent molecules and temperature, SNUT‐25 changed from the original two‐dimensional layered structure to the three‐dimensional pore structure of SNUT‐26. In addition, SNUT‐25 and SNUT‐26 are efficient photocatalysts for the degradation of organic dye methyl blue (MB) under visible light irradiation. Surprisingly, the degradation rates of both SNUT‐25 and SNUT‐26 can reach over 96%. In addition, SNUT‐25 and SNUT‐26 also exhibited high electrocatalytic oxygen evolution reaction.
We have successfully recorded the single crystal to single crystal (SCSC) transition from two‐dimensional non interpenetrating layers (SNUT‐25) to microporous three‐dimensional quadruple interpenetrating MOFs (SNUT‐26). Both SNUT‐25 and SNUT‐26 exhibit excellent electrocatalytic and photocatalytic performance.</description><subject>Benzoic acid</subject><subject>Chemical synthesis</subject><subject>crystal structure</subject><subject>Crystals</subject><subject>Dimensional changes</subject><subject>Dimethylformamide</subject><subject>electrocatalytic</subject><subject>Light irradiation</subject><subject>Metal-organic frameworks</subject><subject>Molecular structure</subject><subject>Nitric acid</subject><subject>Oxygen evolution reactions</subject><subject>photocatalytic activity</subject><subject>Photodegradation</subject><subject>solvothermal</subject><subject>syntheses</subject><issn>0268-2605</issn><issn>1099-0739</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNp1kUtOwzAQhi0EEqUgcQRLbNikjPOys6wKBaRWXQDryHXGJVUaB9sVyo4jcB6Ow0lwKatKbOalb0a__RNyyWDEAOIbadSIZwUckQGDooiAJ8UxGUCciyjOITslZ86tAaDIWTogX091u2rw--NT2d552YTKmxDcwZx6K1unjd1IX5uWGk0l9e87tKo32LowDFRr2rr1aDtsMWx4rGgje7TUm8BvamVNZ6zZOupfLeLBtjZbq01T0cMb88U0CKhXK7ShW_b0dj49JydaNg4v_vKQvEzvnicP0Wxx_zgZzyLFRAoRFgA8U0yrLOGgOWOJ0OFnBORpLBKsMhZqoRSwpax4kfAsLRguOY-FqgRLhuRqf7ez5m2LzpfrIDPIdWUCXIhU5GkWqOs9FV7onEVddrbeSNuXDMqdM2Vwptw5E9Boj77XDfb_cuV4MfnlfwCKu5mY</recordid><startdate>202408</startdate><enddate>202408</enddate><creator>Huang, Pei‐Pei</creator><creator>Wu, Ting‐Ting</creator><creator>Tuo, Meng‐Qi</creator><creator>Pan, Hui‐Bin</creator><creator>Yue, Si‐Yu</creator><creator>Huang, Pei</creator><creator>Gao, Yan‐Hong</creator><creator>Lu, Jiu‐Fu</creator><creator>Jin, Ling‐Xia</creator><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><orcidid>https://orcid.org/0009-0003-3131-0562</orcidid><orcidid>https://orcid.org/0009-0005-4307-7459</orcidid><orcidid>https://orcid.org/0009-0004-8263-6295</orcidid><orcidid>https://orcid.org/0009-0002-7373-8391</orcidid><orcidid>https://orcid.org/0000-0003-2645-0512</orcidid><orcidid>https://orcid.org/0009-0007-5092-6935</orcidid><orcidid>https://orcid.org/0000-0001-7876-4674</orcidid><orcidid>https://orcid.org/0000-0001-7869-8021</orcidid><orcidid>https://orcid.org/0000-0002-2668-7475</orcidid></search><sort><creationdate>202408</creationdate><title>Single‐crystal‐to‐single‐crystal transformation of a two‐dimensional noninterpenetrated layer to a microporous three‐dimensional fourfold interpenetrated MOF triggered by DMF</title><author>Huang, Pei‐Pei ; Wu, Ting‐Ting ; Tuo, Meng‐Qi ; Pan, Hui‐Bin ; Yue, Si‐Yu ; Huang, Pei ; Gao, Yan‐Hong ; Lu, Jiu‐Fu ; Jin, Ling‐Xia</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c1840-e90075c1fc5370f71138f0998064283ed519808cc01bad79375491eb7728cd813</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Benzoic acid</topic><topic>Chemical synthesis</topic><topic>crystal structure</topic><topic>Crystals</topic><topic>Dimensional changes</topic><topic>Dimethylformamide</topic><topic>electrocatalytic</topic><topic>Light irradiation</topic><topic>Metal-organic frameworks</topic><topic>Molecular structure</topic><topic>Nitric acid</topic><topic>Oxygen evolution reactions</topic><topic>photocatalytic activity</topic><topic>Photodegradation</topic><topic>solvothermal</topic><topic>syntheses</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Huang, Pei‐Pei</creatorcontrib><creatorcontrib>Wu, Ting‐Ting</creatorcontrib><creatorcontrib>Tuo, Meng‐Qi</creatorcontrib><creatorcontrib>Pan, Hui‐Bin</creatorcontrib><creatorcontrib>Yue, Si‐Yu</creatorcontrib><creatorcontrib>Huang, Pei</creatorcontrib><creatorcontrib>Gao, Yan‐Hong</creatorcontrib><creatorcontrib>Lu, Jiu‐Fu</creatorcontrib><creatorcontrib>Jin, Ling‐Xia</creatorcontrib><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Applied organometallic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Huang, Pei‐Pei</au><au>Wu, Ting‐Ting</au><au>Tuo, Meng‐Qi</au><au>Pan, Hui‐Bin</au><au>Yue, Si‐Yu</au><au>Huang, Pei</au><au>Gao, Yan‐Hong</au><au>Lu, Jiu‐Fu</au><au>Jin, Ling‐Xia</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Single‐crystal‐to‐single‐crystal transformation of a two‐dimensional noninterpenetrated layer to a microporous three‐dimensional fourfold interpenetrated MOF triggered by DMF</atitle><jtitle>Applied organometallic chemistry</jtitle><date>2024-08</date><risdate>2024</risdate><volume>38</volume><issue>8</issue><epage>n/a</epage><issn>0268-2605</issn><eissn>1099-0739</eissn><abstract>We have demonstrated a single‐crystal‐to‐single‐crystal (SCSC) transformation from a two‐dimensional noninterpenetrated layer to a microporous three‐dimensional fourfold interpenetrated MOF. The centrosymmetric [Co2(μ2‐OH)(EIBA)3]n (SNUT‐25) transforms into a microporous [Co(EIBA)2]n (SNUT‐26), which is triggered by the reaction time with DMF that acts as a structure‐directing agent (HEIBA = 4‐(2‐ethyl‐1H‐imidazol‐1‐yl)benzoic acid; DMF = N,N′‐dimethylformamide). Despite the distinct structure and coordination arrangements of SNUT‐25 in contrast to SNUT‐26, both Co‐MOFs were synthesized using the same ligand. Fascinatingly, upon introducing a specific quantity of DMF combined with a negligible proportion of nitric acid, SNUT‐25 will progressively and completely transform into SNUT‐26. Under the synergistic induction of solvent molecules and temperature, SNUT‐25 changed from the original two‐dimensional layered structure to the three‐dimensional pore structure of SNUT‐26. In addition, SNUT‐25 and SNUT‐26 are efficient photocatalysts for the degradation of organic dye methyl blue (MB) under visible light irradiation. Surprisingly, the degradation rates of both SNUT‐25 and SNUT‐26 can reach over 96%. In addition, SNUT‐25 and SNUT‐26 also exhibited high electrocatalytic oxygen evolution reaction.
We have successfully recorded the single crystal to single crystal (SCSC) transition from two‐dimensional non interpenetrating layers (SNUT‐25) to microporous three‐dimensional quadruple interpenetrating MOFs (SNUT‐26). Both SNUT‐25 and SNUT‐26 exhibit excellent electrocatalytic and photocatalytic performance.</abstract><cop>Chichester</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/aoc.7590</doi><tpages>11</tpages><orcidid>https://orcid.org/0009-0003-3131-0562</orcidid><orcidid>https://orcid.org/0009-0005-4307-7459</orcidid><orcidid>https://orcid.org/0009-0004-8263-6295</orcidid><orcidid>https://orcid.org/0009-0002-7373-8391</orcidid><orcidid>https://orcid.org/0000-0003-2645-0512</orcidid><orcidid>https://orcid.org/0009-0007-5092-6935</orcidid><orcidid>https://orcid.org/0000-0001-7876-4674</orcidid><orcidid>https://orcid.org/0000-0001-7869-8021</orcidid><orcidid>https://orcid.org/0000-0002-2668-7475</orcidid></addata></record> |
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subjects | Benzoic acid Chemical synthesis crystal structure Crystals Dimensional changes Dimethylformamide electrocatalytic Light irradiation Metal-organic frameworks Molecular structure Nitric acid Oxygen evolution reactions photocatalytic activity Photodegradation solvothermal syntheses |
title | Single‐crystal‐to‐single‐crystal transformation of a two‐dimensional noninterpenetrated layer to a microporous three‐dimensional fourfold interpenetrated MOF triggered by DMF |
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