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Solubility of Scandium Cesium Double Sulfate CsSc(SO4)2 in Sulfuric Acid Solutions
Cesium sulfatoscandate CsSc(SO 4 ) 2 (space group P , a = b = 5.0971(1) Å, c = 8.6924(5) Å, V = 195.580(2) Å 3 , Z = 1) has been crystallized from aqueous solutions in layered hexagonal prisms sized up to 50 µm and up to 2–5 µm thick. Its water solubility is 0.0104 mol/L at 25 ± 1°С. A way to reduce...
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| Published in: | Russian journal of inorganic chemistry 2023-12, Vol.68 (12), p.1818-1823 |
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| Main Authors: | , , , |
| Format: | Article |
| Language: | English |
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| container_end_page | 1823 |
| container_issue | 12 |
| container_start_page | 1818 |
| container_title | Russian journal of inorganic chemistry |
| container_volume | 68 |
| creator | Pasechnik, L. A. Medyankina, I. S. Tyutyunnik, A. P. Bamburov, V. G. |
| description | Cesium sulfatoscandate CsSc(SO
4
)
2
(space group
P
,
a
=
b
= 5.0971(1) Å,
c
= 8.6924(5) Å,
V
= 195.580(2) Å
3
,
Z
= 1) has been crystallized from aqueous solutions in layered hexagonal prisms sized up to 50 µm and up to 2–5 µm thick. Its water solubility is 0.0104 mol/L at 25 ± 1°С. A way to reduce the solubility of scandium as CsSc(SO
4
)
2
is to increase acidity to 3.5–5.5 М H
2
SO
4
and add Cs
2
SO
4
. Experimental evidence is supported by calculations that took into account changes in the ionic strength of the solution and the influence of the simultaneous presence of Cs
+
and
ions. The results will be useful for those who will study the behavior of rare-metal compounds having similar properties and their separation. |
| doi_str_mv | 10.1134/S0036023623602088 |
| format | article |
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4
)
2
(space group
P
,
a
=
b
= 5.0971(1) Å,
c
= 8.6924(5) Å,
V
= 195.580(2) Å
3
,
Z
= 1) has been crystallized from aqueous solutions in layered hexagonal prisms sized up to 50 µm and up to 2–5 µm thick. Its water solubility is 0.0104 mol/L at 25 ± 1°С. A way to reduce the solubility of scandium as CsSc(SO
4
)
2
is to increase acidity to 3.5–5.5 М H
2
SO
4
and add Cs
2
SO
4
. Experimental evidence is supported by calculations that took into account changes in the ionic strength of the solution and the influence of the simultaneous presence of Cs
+
and
ions. The results will be useful for those who will study the behavior of rare-metal compounds having similar properties and their separation.</description><identifier>ISSN: 0036-0236</identifier><identifier>EISSN: 1531-8613</identifier><identifier>DOI: 10.1134/S0036023623602088</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Aqueous solutions ; Cesium ; Chemistry ; Chemistry and Materials Science ; Crystallization ; Inorganic Chemistry ; Metal compounds ; Physicochemical Analysis of Inorganic Systems ; Prisms ; Scandium ; Solubility ; Sulfuric acid</subject><ispartof>Russian journal of inorganic chemistry, 2023-12, Vol.68 (12), p.1818-1823</ispartof><rights>Pleiades Publishing, Ltd. 2023. ISSN 0036-0236, Russian Journal of Inorganic Chemistry, 2023, Vol. 68, No. 12, pp. 1818–1823. © Pleiades Publishing, Ltd., 2023. Russian Text © The Author(s), 2023, published in Zhurnal Neorganicheskoi Khimii, 2023, Vol. 68, No. 12, pp. 1799–1804.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-3ef21969941ac0fa3bb5c6a272f2d9d2db6189694caca0790ecf67e1573ed2313</citedby><cites>FETCH-LOGICAL-c316t-3ef21969941ac0fa3bb5c6a272f2d9d2db6189694caca0790ecf67e1573ed2313</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>315,786,790,27957,27958</link.rule.ids></links><search><creatorcontrib>Pasechnik, L. A.</creatorcontrib><creatorcontrib>Medyankina, I. S.</creatorcontrib><creatorcontrib>Tyutyunnik, A. P.</creatorcontrib><creatorcontrib>Bamburov, V. G.</creatorcontrib><title>Solubility of Scandium Cesium Double Sulfate CsSc(SO4)2 in Sulfuric Acid Solutions</title><title>Russian journal of inorganic chemistry</title><addtitle>Russ. J. Inorg. Chem</addtitle><description>Cesium sulfatoscandate CsSc(SO
4
)
2
(space group
P
,
a
=
b
= 5.0971(1) Å,
c
= 8.6924(5) Å,
V
= 195.580(2) Å
3
,
Z
= 1) has been crystallized from aqueous solutions in layered hexagonal prisms sized up to 50 µm and up to 2–5 µm thick. Its water solubility is 0.0104 mol/L at 25 ± 1°С. A way to reduce the solubility of scandium as CsSc(SO
4
)
2
is to increase acidity to 3.5–5.5 М H
2
SO
4
and add Cs
2
SO
4
. Experimental evidence is supported by calculations that took into account changes in the ionic strength of the solution and the influence of the simultaneous presence of Cs
+
and
ions. The results will be useful for those who will study the behavior of rare-metal compounds having similar properties and their separation.</description><subject>Aqueous solutions</subject><subject>Cesium</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Crystallization</subject><subject>Inorganic Chemistry</subject><subject>Metal compounds</subject><subject>Physicochemical Analysis of Inorganic Systems</subject><subject>Prisms</subject><subject>Scandium</subject><subject>Solubility</subject><subject>Sulfuric acid</subject><issn>0036-0236</issn><issn>1531-8613</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp1kE9LxDAUxIMouK5-AG8BL3qo5iXZpD0u9S8sLFg9lzRNJEu3WZPmsN_e1hU8iKeBN7-ZB4PQJZBbAMbvKkKYIJQJOgnJ8yM0gwWDLBfAjtFssrPJP0VnMW4I4ZzIfIZeK9-lxnVu2GNvcaVV37q0xaWJk9z71HQGV6mzajC4jJW-rtb8hmLXf19TcBovtWvxVDQ438dzdGJVF83Fj87R--PDW_mcrdZPL-VylWkGYsiYsRQKURQclCZWsaZZaKGopJa2RUvbRkA--lwrrYgsiNFWSAMLyUxLGbA5ujr07oL_TCYO9can0I8va1oQSXOQko8UHCgdfIzB2HoX3FaFfQ2knqar_0w3ZughE0e2_zDht_n_0BcZLm5c</recordid><startdate>20231201</startdate><enddate>20231201</enddate><creator>Pasechnik, L. A.</creator><creator>Medyankina, I. S.</creator><creator>Tyutyunnik, A. P.</creator><creator>Bamburov, V. G.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20231201</creationdate><title>Solubility of Scandium Cesium Double Sulfate CsSc(SO4)2 in Sulfuric Acid Solutions</title><author>Pasechnik, L. A. ; Medyankina, I. S. ; Tyutyunnik, A. P. ; Bamburov, V. G.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-3ef21969941ac0fa3bb5c6a272f2d9d2db6189694caca0790ecf67e1573ed2313</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Aqueous solutions</topic><topic>Cesium</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Crystallization</topic><topic>Inorganic Chemistry</topic><topic>Metal compounds</topic><topic>Physicochemical Analysis of Inorganic Systems</topic><topic>Prisms</topic><topic>Scandium</topic><topic>Solubility</topic><topic>Sulfuric acid</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Pasechnik, L. A.</creatorcontrib><creatorcontrib>Medyankina, I. S.</creatorcontrib><creatorcontrib>Tyutyunnik, A. P.</creatorcontrib><creatorcontrib>Bamburov, V. G.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Pasechnik, L. A.</au><au>Medyankina, I. S.</au><au>Tyutyunnik, A. P.</au><au>Bamburov, V. G.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Solubility of Scandium Cesium Double Sulfate CsSc(SO4)2 in Sulfuric Acid Solutions</atitle><jtitle>Russian journal of inorganic chemistry</jtitle><stitle>Russ. J. Inorg. Chem</stitle><date>2023-12-01</date><risdate>2023</risdate><volume>68</volume><issue>12</issue><spage>1818</spage><epage>1823</epage><pages>1818-1823</pages><issn>0036-0236</issn><eissn>1531-8613</eissn><abstract>Cesium sulfatoscandate CsSc(SO
4
)
2
(space group
P
,
a
=
b
= 5.0971(1) Å,
c
= 8.6924(5) Å,
V
= 195.580(2) Å
3
,
Z
= 1) has been crystallized from aqueous solutions in layered hexagonal prisms sized up to 50 µm and up to 2–5 µm thick. Its water solubility is 0.0104 mol/L at 25 ± 1°С. A way to reduce the solubility of scandium as CsSc(SO
4
)
2
is to increase acidity to 3.5–5.5 М H
2
SO
4
and add Cs
2
SO
4
. Experimental evidence is supported by calculations that took into account changes in the ionic strength of the solution and the influence of the simultaneous presence of Cs
+
and
ions. The results will be useful for those who will study the behavior of rare-metal compounds having similar properties and their separation.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0036023623602088</doi><tpages>6</tpages></addata></record> |
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| identifier | ISSN: 0036-0236 |
| ispartof | Russian journal of inorganic chemistry, 2023-12, Vol.68 (12), p.1818-1823 |
| issn | 0036-0236 1531-8613 |
| language | eng |
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| source | Springer Link |
| subjects | Aqueous solutions Cesium Chemistry Chemistry and Materials Science Crystallization Inorganic Chemistry Metal compounds Physicochemical Analysis of Inorganic Systems Prisms Scandium Solubility Sulfuric acid |
| title | Solubility of Scandium Cesium Double Sulfate CsSc(SO4)2 in Sulfuric Acid Solutions |
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