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Generalized Dependence of the Viscosity of Particulate-Filled Polymer Composite Materials with Different Types of Structures
Models describing the rheological properties of particulate-filled polymer composite materials are analyzed from the point of view of their structure. A mathematical model relating the relative viscosity to the parameters of the disperse structure is proposed on the example of a model system based o...
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Published in: | Theoretical foundations of chemical engineering 2023-08, Vol.57 (4), p.515-523 |
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container_title | Theoretical foundations of chemical engineering |
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creator | Simonov-Emel’yanov, I. D. Surikov, P. V. |
description | Models describing the rheological properties of particulate-filled polymer composite materials are analyzed from the point of view of their structure. A mathematical model relating the relative viscosity to the parameters of the disperse structure is proposed on the example of a model system based on low-density polyethylene containing glass microspheres. The rheological properties of particulate-filled composite materials are considered for the first time from the standpoint of the formation of a heterogeneity by particles of a dispersed filler in space and the construction of a polymer matrix in the free space in the form of three functional components (Θ,
B
, and
M
). The use of this approach in technological practice makes it possible to estimate the melt viscosity from the parameters of a given type of structure (dependent on the content of dispersed filler) of a particulate-filled polymer composite material. |
doi_str_mv | 10.1134/S0040579523040437 |
format | article |
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B
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M
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B
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M
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B
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subjects | Chemistry Chemistry and Materials Science Composite materials Fillers Heterogeneity Industrial Chemistry/Chemical Engineering Low density polyethylenes Mathematical models Microspheres Parameters Particulate composites Polymer matrix composites Polymers Rheological properties Skeletal composites Viscosity |
title | Generalized Dependence of the Viscosity of Particulate-Filled Polymer Composite Materials with Different Types of Structures |
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