Octave-spanning emission across the visible spectrum from single crystalline 1,3,5,7-tetrakis-(p-methoxyphenyl)adamantane

Sustainable efficient light emitters based solely on elements-of-hope are needed to replace current compounds based on less-abundant materials. Functionalized diamondoids are a potential solution for this challenge, as a prototypical example offers efficient, octave-spanning emission across the visi...

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Published in:Optical materials express 2022-09, Vol.12 (9), p.3517
Main Authors: Müller, Marius J., Ziese, Ferdinand, Belz, Jürgen, Hüppe, Franziska, Gowrisankar, Saravanan, Bernhardt, Bastian, Schwan, Sebastian, Mollenhauer, Doreen, Schreiner, Peter R., Volz, Kerstin, Sanna, Simone, Chatterjee, Sangam
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Language:English
Subjects:
Crystal structure
Crystallinity
Diamonds
Emission
Emitters
Excitons
Phosphors
Quantum efficiency
Single crystals
Visible spectrum
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cited_by cdi_FETCH-LOGICAL-c225t-11ba265da1c294cab99d1baca09decf862f03f5093e41376790be8e799099da13
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container_issue 9
container_start_page 3517
container_title Optical materials express
container_volume 12
creator Müller, Marius J.
Ziese, Ferdinand
Belz, Jürgen
Hüppe, Franziska
Gowrisankar, Saravanan
Bernhardt, Bastian
Schwan, Sebastian
Mollenhauer, Doreen
Schreiner, Peter R.
Volz, Kerstin
Sanna, Simone
Chatterjee, Sangam
description Sustainable efficient light emitters based solely on elements-of-hope are needed to replace current compounds based on less-abundant materials. Functionalized diamondoids are a potential solution for this challenge, as a prototypical example offers efficient, octave-spanning emission across the visible spectrum in their single-crystalline form. Its large quantum efficiency increases towards higher-than-ambient temperatures to beyond 7%. The stability beyond 200 °C renders such functionalized diamondoids as sustainable phosphors for LED applications. Detailed structural and theoretical investigations suggest a crucial role of exciton states accompanied by structural modifications (self-trapped excitons) in the emission process.
doi_str_mv 10.1364/OME.461427
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subjects Crystal structure
Crystallinity
Diamonds
Emission
Emitters
Excitons
Phosphors
Quantum efficiency
Single crystals
Visible spectrum
title Octave-spanning emission across the visible spectrum from single crystalline 1,3,5,7-tetrakis-(p-methoxyphenyl)adamantane
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