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Electrosynthesis of nanocomposites of Ag, Au, Pd nanoparticles with aluminum(III), zinc(II), and titanium(IV) oxide-hydroxides
The two-step electrosyntheses of metal nanoparticles (MNP) (M = Pd, Ag, Au) nanocomposites with aluminum(III), zinc(II), titanium(IV) oxide-hydroxides were carried out. It has been shown that the first step of the oxide-hydroxides synthesis in an undivided cell using soluble Al, Zn, or Ti anodes and...
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| Published in: | Journal of solid state electrochemistry 2022-10, Vol.26 (10), p.2271-2285 |
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| cites | cdi_FETCH-LOGICAL-c319t-9a4142f91762963c92312cf4aad778145bcb41b0427f804a066aa4809a55f763 |
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| container_title | Journal of solid state electrochemistry |
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| creator | Fazleeva, Rezeda R. Nasretdinova, Gulnaz R. Evtyugin, Vladimir G. Gubaidullin, Aidar T. Yanilkin, Vitaliy V. |
| description | The two-step electrosyntheses of metal nanoparticles (MNP) (M = Pd, Ag, Au) nanocomposites with aluminum(III), zinc(II), titanium(IV) oxide-hydroxides were carried out. It has been shown that the first step of the oxide-hydroxides synthesis in an undivided cell using soluble Al, Zn, or Ti anodes and dissolved atmospheric oxygen as reagent proceeds efficiently at controlled potentials of oxygen reduction to a superoxide ion in medium DMSO/0.1 M Bu
4
NCl with a current yield of 141% (Al), 102% (Zn), 110% (Ti), and formation of an amorphous phase. The second step consists of mediated electrosynthesis of MNPs in the obtained solutions of oxide-hydroxides and is carried out using methylviologen as a mediator and cetyltrimethylammonium chloride (CTAC) as a stabilizer. MNPs obtained in the solution bulk quantitatively or partially bound to the oxide-hydroxides. PdNPs are combined with one common CTAC shell and are agglomerates of smaller nanoparticles (~ Pd = 6 ± 2 nm). Ag and Au NPs are individual; their size (amorphous part) is higher, depends on the oxide-hydroxide component in nanocomposites, although this component does not affect the size of metal crystallites. Obtained nanocomposites exhibit catalytic activity in the reaction of
p
-nitrophenol reduction by sodium borohydride, which increases with increasing of CTAC concentration. |
| doi_str_mv | 10.1007/s10008-022-05248-1 |
| format | article |
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4
NCl with a current yield of 141% (Al), 102% (Zn), 110% (Ti), and formation of an amorphous phase. The second step consists of mediated electrosynthesis of MNPs in the obtained solutions of oxide-hydroxides and is carried out using methylviologen as a mediator and cetyltrimethylammonium chloride (CTAC) as a stabilizer. MNPs obtained in the solution bulk quantitatively or partially bound to the oxide-hydroxides. PdNPs are combined with one common CTAC shell and are agglomerates of smaller nanoparticles (~ Pd = 6 ± 2 nm). Ag and Au NPs are individual; their size (amorphous part) is higher, depends on the oxide-hydroxide component in nanocomposites, although this component does not affect the size of metal crystallites. Obtained nanocomposites exhibit catalytic activity in the reaction of
p
-nitrophenol reduction by sodium borohydride, which increases with increasing of CTAC concentration.</description><identifier>ISSN: 1432-8488</identifier><identifier>EISSN: 1433-0768</identifier><identifier>DOI: 10.1007/s10008-022-05248-1</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Aluminum ; Analytical Chemistry ; Anodic dissolution ; Catalytic activity ; Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Condensed Matter Physics ; Crystallites ; Dissolution ; Electrochemistry ; Energy Storage ; Gold ; Hydroxides ; Nanocomposites ; Nanoparticles ; Nitrophenol ; Original Paper ; Oxygen ; Palladium ; Physical Chemistry ; Reagents ; Silver ; Titanium ; Titanium dioxide ; Zinc</subject><ispartof>Journal of solid state electrochemistry, 2022-10, Vol.26 (10), p.2271-2285</ispartof><rights>The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2022</rights><rights>The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2022.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-9a4142f91762963c92312cf4aad778145bcb41b0427f804a066aa4809a55f763</citedby><cites>FETCH-LOGICAL-c319t-9a4142f91762963c92312cf4aad778145bcb41b0427f804a066aa4809a55f763</cites><orcidid>0000-0003-2218-8465 ; 0000-0002-8114-7025 ; 0000-0002-4276-2666 ; 0000-0002-5087-9901</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>315,786,790,27957,27958</link.rule.ids></links><search><creatorcontrib>Fazleeva, Rezeda R.</creatorcontrib><creatorcontrib>Nasretdinova, Gulnaz R.</creatorcontrib><creatorcontrib>Evtyugin, Vladimir G.</creatorcontrib><creatorcontrib>Gubaidullin, Aidar T.</creatorcontrib><creatorcontrib>Yanilkin, Vitaliy V.</creatorcontrib><title>Electrosynthesis of nanocomposites of Ag, Au, Pd nanoparticles with aluminum(III), zinc(II), and titanium(IV) oxide-hydroxides</title><title>Journal of solid state electrochemistry</title><addtitle>J Solid State Electrochem</addtitle><description>The two-step electrosyntheses of metal nanoparticles (MNP) (M = Pd, Ag, Au) nanocomposites with aluminum(III), zinc(II), titanium(IV) oxide-hydroxides were carried out. It has been shown that the first step of the oxide-hydroxides synthesis in an undivided cell using soluble Al, Zn, or Ti anodes and dissolved atmospheric oxygen as reagent proceeds efficiently at controlled potentials of oxygen reduction to a superoxide ion in medium DMSO/0.1 M Bu
4
NCl with a current yield of 141% (Al), 102% (Zn), 110% (Ti), and formation of an amorphous phase. The second step consists of mediated electrosynthesis of MNPs in the obtained solutions of oxide-hydroxides and is carried out using methylviologen as a mediator and cetyltrimethylammonium chloride (CTAC) as a stabilizer. MNPs obtained in the solution bulk quantitatively or partially bound to the oxide-hydroxides. PdNPs are combined with one common CTAC shell and are agglomerates of smaller nanoparticles (~ Pd = 6 ± 2 nm). Ag and Au NPs are individual; their size (amorphous part) is higher, depends on the oxide-hydroxide component in nanocomposites, although this component does not affect the size of metal crystallites. Obtained nanocomposites exhibit catalytic activity in the reaction of
p
-nitrophenol reduction by sodium borohydride, which increases with increasing of CTAC concentration.</description><subject>Aluminum</subject><subject>Analytical Chemistry</subject><subject>Anodic dissolution</subject><subject>Catalytic activity</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Condensed Matter Physics</subject><subject>Crystallites</subject><subject>Dissolution</subject><subject>Electrochemistry</subject><subject>Energy Storage</subject><subject>Gold</subject><subject>Hydroxides</subject><subject>Nanocomposites</subject><subject>Nanoparticles</subject><subject>Nitrophenol</subject><subject>Original Paper</subject><subject>Oxygen</subject><subject>Palladium</subject><subject>Physical Chemistry</subject><subject>Reagents</subject><subject>Silver</subject><subject>Titanium</subject><subject>Titanium dioxide</subject><subject>Zinc</subject><issn>1432-8488</issn><issn>1433-0768</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp9kMFLwzAYxYMoOKf_gKeClw0WTdK0SY9jTB0M9DC8hixtt4w2rUmKzoN_u1krePOSPPLe-77wA-AWo3uMEHtw4UQcIkIgSgjlEJ-BEaZxDBFL-XmvCeSU80tw5dwBIcxSjEbge1kVytvGHY3fF067qCkjI02jmrptnPZF_zLfzaJ5N4te895spfVaVcH70H4fyaqrtenqyWq1ms6iL23UpFfS5JHXXhp9Mt-mUfOp8wLuj7ntlbsGF6WsXHHze4_B5nG5WTzD9cvTajFfQxXjzMNMUkxJmYVPkyyNVUZiTFRJpcwZ45gmW7WleIsoYSVHVKI0lZJylMkkKVkaj8HdMLa1zXtXOC8OTWdN2CgIQwljMcMkpMiQUoGHs0UpWqtraY8CI3HCLAbMImAWPWaBQykeSi6Eza6wf6P_af0Al7V-yA</recordid><startdate>20221001</startdate><enddate>20221001</enddate><creator>Fazleeva, Rezeda R.</creator><creator>Nasretdinova, Gulnaz R.</creator><creator>Evtyugin, Vladimir G.</creator><creator>Gubaidullin, Aidar T.</creator><creator>Yanilkin, Vitaliy V.</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0003-2218-8465</orcidid><orcidid>https://orcid.org/0000-0002-8114-7025</orcidid><orcidid>https://orcid.org/0000-0002-4276-2666</orcidid><orcidid>https://orcid.org/0000-0002-5087-9901</orcidid></search><sort><creationdate>20221001</creationdate><title>Electrosynthesis of nanocomposites of Ag, Au, Pd nanoparticles with aluminum(III), zinc(II), and titanium(IV) oxide-hydroxides</title><author>Fazleeva, Rezeda R. ; Nasretdinova, Gulnaz R. ; Evtyugin, Vladimir G. ; Gubaidullin, Aidar T. ; Yanilkin, Vitaliy V.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-9a4142f91762963c92312cf4aad778145bcb41b0427f804a066aa4809a55f763</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Aluminum</topic><topic>Analytical Chemistry</topic><topic>Anodic dissolution</topic><topic>Catalytic activity</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Condensed Matter Physics</topic><topic>Crystallites</topic><topic>Dissolution</topic><topic>Electrochemistry</topic><topic>Energy Storage</topic><topic>Gold</topic><topic>Hydroxides</topic><topic>Nanocomposites</topic><topic>Nanoparticles</topic><topic>Nitrophenol</topic><topic>Original Paper</topic><topic>Oxygen</topic><topic>Palladium</topic><topic>Physical Chemistry</topic><topic>Reagents</topic><topic>Silver</topic><topic>Titanium</topic><topic>Titanium dioxide</topic><topic>Zinc</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Fazleeva, Rezeda R.</creatorcontrib><creatorcontrib>Nasretdinova, Gulnaz R.</creatorcontrib><creatorcontrib>Evtyugin, Vladimir G.</creatorcontrib><creatorcontrib>Gubaidullin, Aidar T.</creatorcontrib><creatorcontrib>Yanilkin, Vitaliy V.</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of solid state electrochemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Fazleeva, Rezeda R.</au><au>Nasretdinova, Gulnaz R.</au><au>Evtyugin, Vladimir G.</au><au>Gubaidullin, Aidar T.</au><au>Yanilkin, Vitaliy V.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Electrosynthesis of nanocomposites of Ag, Au, Pd nanoparticles with aluminum(III), zinc(II), and titanium(IV) oxide-hydroxides</atitle><jtitle>Journal of solid state electrochemistry</jtitle><stitle>J Solid State Electrochem</stitle><date>2022-10-01</date><risdate>2022</risdate><volume>26</volume><issue>10</issue><spage>2271</spage><epage>2285</epage><pages>2271-2285</pages><issn>1432-8488</issn><eissn>1433-0768</eissn><abstract>The two-step electrosyntheses of metal nanoparticles (MNP) (M = Pd, Ag, Au) nanocomposites with aluminum(III), zinc(II), titanium(IV) oxide-hydroxides were carried out. It has been shown that the first step of the oxide-hydroxides synthesis in an undivided cell using soluble Al, Zn, or Ti anodes and dissolved atmospheric oxygen as reagent proceeds efficiently at controlled potentials of oxygen reduction to a superoxide ion in medium DMSO/0.1 M Bu
4
NCl with a current yield of 141% (Al), 102% (Zn), 110% (Ti), and formation of an amorphous phase. The second step consists of mediated electrosynthesis of MNPs in the obtained solutions of oxide-hydroxides and is carried out using methylviologen as a mediator and cetyltrimethylammonium chloride (CTAC) as a stabilizer. MNPs obtained in the solution bulk quantitatively or partially bound to the oxide-hydroxides. PdNPs are combined with one common CTAC shell and are agglomerates of smaller nanoparticles (~ Pd = 6 ± 2 nm). Ag and Au NPs are individual; their size (amorphous part) is higher, depends on the oxide-hydroxide component in nanocomposites, although this component does not affect the size of metal crystallites. Obtained nanocomposites exhibit catalytic activity in the reaction of
p
-nitrophenol reduction by sodium borohydride, which increases with increasing of CTAC concentration.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s10008-022-05248-1</doi><tpages>15</tpages><orcidid>https://orcid.org/0000-0003-2218-8465</orcidid><orcidid>https://orcid.org/0000-0002-8114-7025</orcidid><orcidid>https://orcid.org/0000-0002-4276-2666</orcidid><orcidid>https://orcid.org/0000-0002-5087-9901</orcidid></addata></record> |
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| subjects | Aluminum Analytical Chemistry Anodic dissolution Catalytic activity Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Condensed Matter Physics Crystallites Dissolution Electrochemistry Energy Storage Gold Hydroxides Nanocomposites Nanoparticles Nitrophenol Original Paper Oxygen Palladium Physical Chemistry Reagents Silver Titanium Titanium dioxide Zinc |
| title | Electrosynthesis of nanocomposites of Ag, Au, Pd nanoparticles with aluminum(III), zinc(II), and titanium(IV) oxide-hydroxides |
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