Loading…
A novel cubic Zn‐citric acid‐based MOF as a highly efficient and reusable catalyst for the synthesis of pyranopyrazoles and 5‐substituted 1H‐tetrazoles
A highly stable and efficient heterogeneous catalyst was successfully prepared by hydrothermal reaction of Zinc nitrate with citric acid. To produce a novel Zn‐based MOF catalyst, Zn ions were coordinated with the ligand functional groups that can be regarded as an alpha‐hydroxy acid containing thre...
Saved in:
Published in: | Applied organometallic chemistry 2022-06, Vol.36 (6), p.n/a |
---|---|
Main Authors: | , , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
cited_by | cdi_FETCH-LOGICAL-c2936-8adb5b78ede8d8833c1df0c8d50496b25e6496c5917581263177b576602a2b9a3 |
---|---|
cites | cdi_FETCH-LOGICAL-c2936-8adb5b78ede8d8833c1df0c8d50496b25e6496c5917581263177b576602a2b9a3 |
container_end_page | n/a |
container_issue | 6 |
container_start_page | |
container_title | Applied organometallic chemistry |
container_volume | 36 |
creator | Koolivand, Mostafa Nikoorazm, Mohsen Ghorbani‐Choghamarani, Arash Mohammadi, Masoud |
description | A highly stable and efficient heterogeneous catalyst was successfully prepared by hydrothermal reaction of Zinc nitrate with citric acid. To produce a novel Zn‐based MOF catalyst, Zn ions were coordinated with the ligand functional groups that can be regarded as an alpha‐hydroxy acid containing three carboxylic acids (COOH) and one hydroxyl (OH) group attached to the three‐carbon skeleton. It was found that the Zn‐CA‐MOFs compound can participate as a catalyst in the synthesis of 5‐substituted 1H‐tetrazole and pyranopyrazole molecules, selectively and efficiently with high yield in a short period of time. As presented, the catalyst demonstrates excellent reusability and stability and can be recycled up to five times without significant loss of reactivity. Heterogeneity analysis showed that no leaching of active Zn species occurred during the recycling process of the heterogeneous Zn‐CA‐MOFs.
The synthesis, characterization, and catalytic activity of a novel cubic Zn‐citric acid‐based MOF have been described. A wide range of 5‐substituted 1H‐tetrazoles and pyranopyrazole molecules prepared in the moderate to high yields. |
doi_str_mv | 10.1002/aoc.6656 |
format | article |
fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2666683691</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2666683691</sourcerecordid><originalsourceid>FETCH-LOGICAL-c2936-8adb5b78ede8d8833c1df0c8d50496b25e6496c5917581263177b576602a2b9a3</originalsourceid><addsrcrecordid>eNp1kM1OAyEUhYnRxFpNfAQSN26mAlMYWDaNtSY13ejGzQQYxtKMQwVGM658BN_Ad_NJpD9b7-Ie7s13OckB4BKjEUaI3EinR4xRdgQGGAmRoSIXx2CACOMZYYiegrMQ1gghwfB4AH4msHXvpoG6U1bD5_b361vb6NNbalulSclgKviwnEEZoIQr-7Jqemjq2mpr2ghlW0FvuiBVY6CWUTZ9iLB2HsaVgaFvkwQboKvhpveyddv-6RoTdqc0WYROhWhjF5MRnqdFNPHAnIOTWjbBXBx0CJ5mt4_TebZY3t1PJ4tME5GzjMtKUVVwUxlecZ7nGlc10ryiaCyYItSwpJoKXFCOCctxUShaMIaIJErIfAiu9v9uvHvrTIjl2nW-TZYlYal4zgRO1PWe0t6F4E1dbrx9lb4vMSq38Zcp_nIbf0KzPfphG9P_y5WT5XTH_wEUWouc</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2666683691</pqid></control><display><type>article</type><title>A novel cubic Zn‐citric acid‐based MOF as a highly efficient and reusable catalyst for the synthesis of pyranopyrazoles and 5‐substituted 1H‐tetrazoles</title><source>Wiley</source><creator>Koolivand, Mostafa ; Nikoorazm, Mohsen ; Ghorbani‐Choghamarani, Arash ; Mohammadi, Masoud</creator><creatorcontrib>Koolivand, Mostafa ; Nikoorazm, Mohsen ; Ghorbani‐Choghamarani, Arash ; Mohammadi, Masoud</creatorcontrib><description>A highly stable and efficient heterogeneous catalyst was successfully prepared by hydrothermal reaction of Zinc nitrate with citric acid. To produce a novel Zn‐based MOF catalyst, Zn ions were coordinated with the ligand functional groups that can be regarded as an alpha‐hydroxy acid containing three carboxylic acids (COOH) and one hydroxyl (OH) group attached to the three‐carbon skeleton. It was found that the Zn‐CA‐MOFs compound can participate as a catalyst in the synthesis of 5‐substituted 1H‐tetrazole and pyranopyrazole molecules, selectively and efficiently with high yield in a short period of time. As presented, the catalyst demonstrates excellent reusability and stability and can be recycled up to five times without significant loss of reactivity. Heterogeneity analysis showed that no leaching of active Zn species occurred during the recycling process of the heterogeneous Zn‐CA‐MOFs.
The synthesis, characterization, and catalytic activity of a novel cubic Zn‐citric acid‐based MOF have been described. A wide range of 5‐substituted 1H‐tetrazoles and pyranopyrazole molecules prepared in the moderate to high yields.</description><identifier>ISSN: 0268-2605</identifier><identifier>EISSN: 1099-0739</identifier><identifier>DOI: 10.1002/aoc.6656</identifier><language>eng</language><publisher>Chichester: Wiley Subscription Services, Inc</publisher><subject>5‐substituted 1H‐tetrazoles ; Carboxylic acids ; Catalysts ; Chemical synthesis ; Chemistry ; Citric acid ; Functional groups ; Heterogeneity ; heterogeneous Zn catalyst ; Hydrothermal reactions ; Hydroxy acids ; Leaching ; Metal-organic frameworks ; pyranopyrazoles ; Substitutes ; Tetrazoles ; Zinc ; Zn‐CA‐MOFs</subject><ispartof>Applied organometallic chemistry, 2022-06, Vol.36 (6), p.n/a</ispartof><rights>2022 John Wiley & Sons, Ltd.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c2936-8adb5b78ede8d8833c1df0c8d50496b25e6496c5917581263177b576602a2b9a3</citedby><cites>FETCH-LOGICAL-c2936-8adb5b78ede8d8833c1df0c8d50496b25e6496c5917581263177b576602a2b9a3</cites><orcidid>0000-0003-4641-5909 ; 0000-0002-7212-1317 ; 0000-0002-4013-0868 ; 0000-0002-1043-3470</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Faoc.6656$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Faoc.6656$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>315,786,790,27957,27958,50923,51032</link.rule.ids></links><search><creatorcontrib>Koolivand, Mostafa</creatorcontrib><creatorcontrib>Nikoorazm, Mohsen</creatorcontrib><creatorcontrib>Ghorbani‐Choghamarani, Arash</creatorcontrib><creatorcontrib>Mohammadi, Masoud</creatorcontrib><title>A novel cubic Zn‐citric acid‐based MOF as a highly efficient and reusable catalyst for the synthesis of pyranopyrazoles and 5‐substituted 1H‐tetrazoles</title><title>Applied organometallic chemistry</title><description>A highly stable and efficient heterogeneous catalyst was successfully prepared by hydrothermal reaction of Zinc nitrate with citric acid. To produce a novel Zn‐based MOF catalyst, Zn ions were coordinated with the ligand functional groups that can be regarded as an alpha‐hydroxy acid containing three carboxylic acids (COOH) and one hydroxyl (OH) group attached to the three‐carbon skeleton. It was found that the Zn‐CA‐MOFs compound can participate as a catalyst in the synthesis of 5‐substituted 1H‐tetrazole and pyranopyrazole molecules, selectively and efficiently with high yield in a short period of time. As presented, the catalyst demonstrates excellent reusability and stability and can be recycled up to five times without significant loss of reactivity. Heterogeneity analysis showed that no leaching of active Zn species occurred during the recycling process of the heterogeneous Zn‐CA‐MOFs.
The synthesis, characterization, and catalytic activity of a novel cubic Zn‐citric acid‐based MOF have been described. A wide range of 5‐substituted 1H‐tetrazoles and pyranopyrazole molecules prepared in the moderate to high yields.</description><subject>5‐substituted 1H‐tetrazoles</subject><subject>Carboxylic acids</subject><subject>Catalysts</subject><subject>Chemical synthesis</subject><subject>Chemistry</subject><subject>Citric acid</subject><subject>Functional groups</subject><subject>Heterogeneity</subject><subject>heterogeneous Zn catalyst</subject><subject>Hydrothermal reactions</subject><subject>Hydroxy acids</subject><subject>Leaching</subject><subject>Metal-organic frameworks</subject><subject>pyranopyrazoles</subject><subject>Substitutes</subject><subject>Tetrazoles</subject><subject>Zinc</subject><subject>Zn‐CA‐MOFs</subject><issn>0268-2605</issn><issn>1099-0739</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp1kM1OAyEUhYnRxFpNfAQSN26mAlMYWDaNtSY13ejGzQQYxtKMQwVGM658BN_Ad_NJpD9b7-Ie7s13OckB4BKjEUaI3EinR4xRdgQGGAmRoSIXx2CACOMZYYiegrMQ1gghwfB4AH4msHXvpoG6U1bD5_b361vb6NNbalulSclgKviwnEEZoIQr-7Jqemjq2mpr2ghlW0FvuiBVY6CWUTZ9iLB2HsaVgaFvkwQboKvhpveyddv-6RoTdqc0WYROhWhjF5MRnqdFNPHAnIOTWjbBXBx0CJ5mt4_TebZY3t1PJ4tME5GzjMtKUVVwUxlecZ7nGlc10ryiaCyYItSwpJoKXFCOCctxUShaMIaIJErIfAiu9v9uvHvrTIjl2nW-TZYlYal4zgRO1PWe0t6F4E1dbrx9lb4vMSq38Zcp_nIbf0KzPfphG9P_y5WT5XTH_wEUWouc</recordid><startdate>202206</startdate><enddate>202206</enddate><creator>Koolivand, Mostafa</creator><creator>Nikoorazm, Mohsen</creator><creator>Ghorbani‐Choghamarani, Arash</creator><creator>Mohammadi, Masoud</creator><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0003-4641-5909</orcidid><orcidid>https://orcid.org/0000-0002-7212-1317</orcidid><orcidid>https://orcid.org/0000-0002-4013-0868</orcidid><orcidid>https://orcid.org/0000-0002-1043-3470</orcidid></search><sort><creationdate>202206</creationdate><title>A novel cubic Zn‐citric acid‐based MOF as a highly efficient and reusable catalyst for the synthesis of pyranopyrazoles and 5‐substituted 1H‐tetrazoles</title><author>Koolivand, Mostafa ; Nikoorazm, Mohsen ; Ghorbani‐Choghamarani, Arash ; Mohammadi, Masoud</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2936-8adb5b78ede8d8833c1df0c8d50496b25e6496c5917581263177b576602a2b9a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>5‐substituted 1H‐tetrazoles</topic><topic>Carboxylic acids</topic><topic>Catalysts</topic><topic>Chemical synthesis</topic><topic>Chemistry</topic><topic>Citric acid</topic><topic>Functional groups</topic><topic>Heterogeneity</topic><topic>heterogeneous Zn catalyst</topic><topic>Hydrothermal reactions</topic><topic>Hydroxy acids</topic><topic>Leaching</topic><topic>Metal-organic frameworks</topic><topic>pyranopyrazoles</topic><topic>Substitutes</topic><topic>Tetrazoles</topic><topic>Zinc</topic><topic>Zn‐CA‐MOFs</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Koolivand, Mostafa</creatorcontrib><creatorcontrib>Nikoorazm, Mohsen</creatorcontrib><creatorcontrib>Ghorbani‐Choghamarani, Arash</creatorcontrib><creatorcontrib>Mohammadi, Masoud</creatorcontrib><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Applied organometallic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Koolivand, Mostafa</au><au>Nikoorazm, Mohsen</au><au>Ghorbani‐Choghamarani, Arash</au><au>Mohammadi, Masoud</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A novel cubic Zn‐citric acid‐based MOF as a highly efficient and reusable catalyst for the synthesis of pyranopyrazoles and 5‐substituted 1H‐tetrazoles</atitle><jtitle>Applied organometallic chemistry</jtitle><date>2022-06</date><risdate>2022</risdate><volume>36</volume><issue>6</issue><epage>n/a</epage><issn>0268-2605</issn><eissn>1099-0739</eissn><notes>Funding information</notes><notes>Bu‐Ali Sina University; Ilam University</notes><abstract>A highly stable and efficient heterogeneous catalyst was successfully prepared by hydrothermal reaction of Zinc nitrate with citric acid. To produce a novel Zn‐based MOF catalyst, Zn ions were coordinated with the ligand functional groups that can be regarded as an alpha‐hydroxy acid containing three carboxylic acids (COOH) and one hydroxyl (OH) group attached to the three‐carbon skeleton. It was found that the Zn‐CA‐MOFs compound can participate as a catalyst in the synthesis of 5‐substituted 1H‐tetrazole and pyranopyrazole molecules, selectively and efficiently with high yield in a short period of time. As presented, the catalyst demonstrates excellent reusability and stability and can be recycled up to five times without significant loss of reactivity. Heterogeneity analysis showed that no leaching of active Zn species occurred during the recycling process of the heterogeneous Zn‐CA‐MOFs.
The synthesis, characterization, and catalytic activity of a novel cubic Zn‐citric acid‐based MOF have been described. A wide range of 5‐substituted 1H‐tetrazoles and pyranopyrazole molecules prepared in the moderate to high yields.</abstract><cop>Chichester</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/aoc.6656</doi><tpages>15</tpages><orcidid>https://orcid.org/0000-0003-4641-5909</orcidid><orcidid>https://orcid.org/0000-0002-7212-1317</orcidid><orcidid>https://orcid.org/0000-0002-4013-0868</orcidid><orcidid>https://orcid.org/0000-0002-1043-3470</orcidid></addata></record> |
fulltext | fulltext |
identifier | ISSN: 0268-2605 |
ispartof | Applied organometallic chemistry, 2022-06, Vol.36 (6), p.n/a |
issn | 0268-2605 1099-0739 |
language | eng |
recordid | cdi_proquest_journals_2666683691 |
source | Wiley |
subjects | 5‐substituted 1H‐tetrazoles Carboxylic acids Catalysts Chemical synthesis Chemistry Citric acid Functional groups Heterogeneity heterogeneous Zn catalyst Hydrothermal reactions Hydroxy acids Leaching Metal-organic frameworks pyranopyrazoles Substitutes Tetrazoles Zinc Zn‐CA‐MOFs |
title | A novel cubic Zn‐citric acid‐based MOF as a highly efficient and reusable catalyst for the synthesis of pyranopyrazoles and 5‐substituted 1H‐tetrazoles |
url | http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-09-21T10%3A42%3A51IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=A%20novel%20cubic%20Zn%E2%80%90citric%20acid%E2%80%90based%20MOF%20as%20a%20highly%20efficient%20and%20reusable%20catalyst%20for%20the%20synthesis%20of%20pyranopyrazoles%20and%205%E2%80%90substituted%201H%E2%80%90tetrazoles&rft.jtitle=Applied%20organometallic%20chemistry&rft.au=Koolivand,%20Mostafa&rft.date=2022-06&rft.volume=36&rft.issue=6&rft.epage=n/a&rft.issn=0268-2605&rft.eissn=1099-0739&rft_id=info:doi/10.1002/aoc.6656&rft_dat=%3Cproquest_cross%3E2666683691%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c2936-8adb5b78ede8d8833c1df0c8d50496b25e6496c5917581263177b576602a2b9a3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=2666683691&rft_id=info:pmid/&rfr_iscdi=true |