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Fabrication of quartz crystal microbalance humidity sensors based on super-hydrophilic cellulose nanocrystals

Natural cellulose nanocrystals (CNCs) possess outstanding properties, such as biodegradability, hydrophilicity, large specific surface areas, and are low in cost. A highly stable and sensitive humidity sensor based on a quartz crystal microbalance (QCM) was prepared using CNCs as the sensing film. T...

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Bibliographic Details
Published in:Cellulose (London) 2021-04, Vol.28 (6), p.3409-3421
Main Authors: Chen, Weixiang, Chen, Bo, Lv, Rixin, Wu, Milian, Zhou, Jie, Lu, Beili, Huang, Biao, Lu, Qilin, Tang, Lirong
Format: Article
Language:English
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Summary:Natural cellulose nanocrystals (CNCs) possess outstanding properties, such as biodegradability, hydrophilicity, large specific surface areas, and are low in cost. A highly stable and sensitive humidity sensor based on a quartz crystal microbalance (QCM) was prepared using CNCs as the sensing film. To investigate the impact of CNCs loading on the sensor performance, a series of humidity-sensitive performance tests, including linearity, response and recovery times, repeatability, hysteresis characteristics, selectivity, and long-term stability tests, was conducted. The experimental results indicated that the humidity sensor with CNCs loading of 2 μg (QCM-2) exhibited excellent logarithmic linearity, high sensitivity (32.35 Hz/% relative humidity (RH)), excellent reversible behavior, and long-term stability at a RH of 11–84%. The contact angle of QCM-2 was 12.5°, revealing its suitable hydrophilicity. Thus, we demonstrate that CNCs are great prospects for potential application in humidity sensors with high performance and low cost. Graphic abstract
ISSN:0969-0239
1572-882X
DOI:10.1007/s10570-021-03777-y