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Influence of the Fluorinated Aromatic Fragments on the Structures of the Cadmium and Zinc Carboxylate Complexes Using Pentafluorobenzoates and 2,3,4,5-Tetrafluorobenzoates as Examples
A series of the cadmium and zinc carboxylate complexes with anions of pentafluorobenzoic (HРfbz) and 2,3,4,5-tetrafluorobenzoic (HТfbz) acids and N - donor ligands (1,10-phenanthroline (Phen) and quinoline (Quin)), [Cd(Pfbz) 2 (Phen)] n ( I ), [Cd(Рfbz) 2 (Рhen) 2 ]·2MeCN ( II ), [Zn(H 2 O)-(Рfbz) 2...
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| Published in: | Russian journal of coordination chemistry 2021-02, Vol.47 (2), p.127-143 |
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| Main Authors: | , , , , , , , , |
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| cited_by | cdi_FETCH-LOGICAL-c316t-419fd23ca59537aab79400f3ae87fd15f810aa13b3144dea886d19df5bb57953 |
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| cites | cdi_FETCH-LOGICAL-c316t-419fd23ca59537aab79400f3ae87fd15f810aa13b3144dea886d19df5bb57953 |
| container_end_page | 143 |
| container_issue | 2 |
| container_start_page | 127 |
| container_title | Russian journal of coordination chemistry |
| container_volume | 47 |
| creator | Shmelev, M. A. Kuznetsova, G. N. Dolgushin, F. M. Voronina, Yu. K. Gogoleva, N. V. Kiskin, M. A. Ivanov, V. K. Sidorov, A. A. Eremenko, I. L. |
| description | A series of the cadmium and zinc carboxylate complexes with anions of pentafluorobenzoic (HРfbz) and 2,3,4,5-tetrafluorobenzoic (HТfbz) acids and N
-
donor ligands (1,10-phenanthroline (Phen) and quinoline (Quin)), [Cd(Pfbz)
2
(Phen)]
n
(
I
), [Cd(Рfbz)
2
(Рhen)
2
]·2MeCN (
II
), [Zn(H
2
O)-(Рfbz)
2
(Рhen)] (
III
), [Zn
2
Cd(Рfbz)
6
(Рhen)
2
]⋅2C
6
H
6
(
IV
), [Cd
2
(H
2
O)
2
(Tfbz)
4
(Рhen)
2
] (
V
), [Cd
2
-(H
2
O)
2
(Tfbz)
4
(Quin)
2
] (
VI
), and [Cd(Tfbz)
2
(Phen)
2
]⋅HTfbz (
VII
), is synthesized. The structures of new complexes
I
–
VII
are determined by X-ray diffraction analysis (CIF files CCDC nos. 1871300, 2005461, 2005462, 2005464, 2005466, 2005465, and 2005459, respectively). The majority of the synthesized compounds is typical of intramolecular stacking interactions between the coordinated molecules of the aromatic N
-
donor ligands and fluorinated substituents of the carboxylate anions. These interactions lead to the formation of unusual compounds, which are different in the cases of pentafluorobenzoates and tetrafluorobenzoates, in particular, coordination polymer
I
and binuclear complexes
V
and
VI
with coordinated water molecules. The synthesized zinc and cadmium compounds differ in structure and composition. |
| doi_str_mv | 10.1134/S1070328421020068 |
| format | article |
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-
donor ligands (1,10-phenanthroline (Phen) and quinoline (Quin)), [Cd(Pfbz)
2
(Phen)]
n
(
I
), [Cd(Рfbz)
2
(Рhen)
2
]·2MeCN (
II
), [Zn(H
2
O)-(Рfbz)
2
(Рhen)] (
III
), [Zn
2
Cd(Рfbz)
6
(Рhen)
2
]⋅2C
6
H
6
(
IV
), [Cd
2
(H
2
O)
2
(Tfbz)
4
(Рhen)
2
] (
V
), [Cd
2
-(H
2
O)
2
(Tfbz)
4
(Quin)
2
] (
VI
), and [Cd(Tfbz)
2
(Phen)
2
]⋅HTfbz (
VII
), is synthesized. The structures of new complexes
I
–
VII
are determined by X-ray diffraction analysis (CIF files CCDC nos. 1871300, 2005461, 2005462, 2005464, 2005466, 2005465, and 2005459, respectively). The majority of the synthesized compounds is typical of intramolecular stacking interactions between the coordinated molecules of the aromatic N
-
donor ligands and fluorinated substituents of the carboxylate anions. These interactions lead to the formation of unusual compounds, which are different in the cases of pentafluorobenzoates and tetrafluorobenzoates, in particular, coordination polymer
I
and binuclear complexes
V
and
VI
with coordinated water molecules. The synthesized zinc and cadmium compounds differ in structure and composition.</description><identifier>ISSN: 1070-3284</identifier><identifier>EISSN: 1608-3318</identifier><identifier>DOI: 10.1134/S1070328421020068</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Anions ; Cadmium ; Cadmium compounds ; Chemical synthesis ; Chemistry ; Chemistry and Materials Science ; Coordination polymers ; Fluorination ; Inorganic Chemistry ; Ligands ; Physical Chemistry ; Quinoline ; Water chemistry ; Zinc compounds</subject><ispartof>Russian journal of coordination chemistry, 2021-02, Vol.47 (2), p.127-143</ispartof><rights>Pleiades Publishing, Ltd. 2021. ISSN 1070-3284, Russian Journal of Coordination Chemistry, 2021, Vol. 47, No. 2, pp. 127–143. © Pleiades Publishing, Ltd., 2021. Russian Text © The Author(s), 2021, published in Koordinatsionnaya Khimiya, 2021, Vol. 47, No. 2, pp. 92–108.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-419fd23ca59537aab79400f3ae87fd15f810aa13b3144dea886d19df5bb57953</citedby><cites>FETCH-LOGICAL-c316t-419fd23ca59537aab79400f3ae87fd15f810aa13b3144dea886d19df5bb57953</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>315,786,790,27957,27958</link.rule.ids></links><search><creatorcontrib>Shmelev, M. A.</creatorcontrib><creatorcontrib>Kuznetsova, G. N.</creatorcontrib><creatorcontrib>Dolgushin, F. M.</creatorcontrib><creatorcontrib>Voronina, Yu. K.</creatorcontrib><creatorcontrib>Gogoleva, N. V.</creatorcontrib><creatorcontrib>Kiskin, M. A.</creatorcontrib><creatorcontrib>Ivanov, V. K.</creatorcontrib><creatorcontrib>Sidorov, A. A.</creatorcontrib><creatorcontrib>Eremenko, I. L.</creatorcontrib><title>Influence of the Fluorinated Aromatic Fragments on the Structures of the Cadmium and Zinc Carboxylate Complexes Using Pentafluorobenzoates and 2,3,4,5-Tetrafluorobenzoates as Examples</title><title>Russian journal of coordination chemistry</title><addtitle>Russ J Coord Chem</addtitle><description>A series of the cadmium and zinc carboxylate complexes with anions of pentafluorobenzoic (HРfbz) and 2,3,4,5-tetrafluorobenzoic (HТfbz) acids and N
-
donor ligands (1,10-phenanthroline (Phen) and quinoline (Quin)), [Cd(Pfbz)
2
(Phen)]
n
(
I
), [Cd(Рfbz)
2
(Рhen)
2
]·2MeCN (
II
), [Zn(H
2
O)-(Рfbz)
2
(Рhen)] (
III
), [Zn
2
Cd(Рfbz)
6
(Рhen)
2
]⋅2C
6
H
6
(
IV
), [Cd
2
(H
2
O)
2
(Tfbz)
4
(Рhen)
2
] (
V
), [Cd
2
-(H
2
O)
2
(Tfbz)
4
(Quin)
2
] (
VI
), and [Cd(Tfbz)
2
(Phen)
2
]⋅HTfbz (
VII
), is synthesized. The structures of new complexes
I
–
VII
are determined by X-ray diffraction analysis (CIF files CCDC nos. 1871300, 2005461, 2005462, 2005464, 2005466, 2005465, and 2005459, respectively). The majority of the synthesized compounds is typical of intramolecular stacking interactions between the coordinated molecules of the aromatic N
-
donor ligands and fluorinated substituents of the carboxylate anions. These interactions lead to the formation of unusual compounds, which are different in the cases of pentafluorobenzoates and tetrafluorobenzoates, in particular, coordination polymer
I
and binuclear complexes
V
and
VI
with coordinated water molecules. The synthesized zinc and cadmium compounds differ in structure and composition.</description><subject>Anions</subject><subject>Cadmium</subject><subject>Cadmium compounds</subject><subject>Chemical synthesis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Coordination polymers</subject><subject>Fluorination</subject><subject>Inorganic Chemistry</subject><subject>Ligands</subject><subject>Physical Chemistry</subject><subject>Quinoline</subject><subject>Water chemistry</subject><subject>Zinc compounds</subject><issn>1070-3284</issn><issn>1608-3318</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp1kb9OwzAQhy0EEqXwAGyWWBvwxfnjjFXVQqVKILUsLJGT2CVVYhfbkVpejNfDaUEMFdOd7r7vd8MhdAvkHoBGD0sgKaEhi0IgISEJO0MDSAgLKAV27nu_Dvr9JbqydkMIEBJnA_Q1V7LphCoF1hK7d4FnTadNrbgTFR4b3XJXl3hm-LoVylms1YFaOtOVrjPC_noTXrV112KuKvxWq9IPTKF3-8Yn4Ylut43YefrV1mqNX3wWl_0lXQj1qT1jD2Y4oqNoFAcr4cwpYPF0x_ske40uJG-suPmpQ7SaTVeTp2Dx_DifjBdBSSFxQQSZrEJa8jiLacp5kWYRIZJywVJZQSwZEM6BFhSiqBKcsaSCrJJxUcSpV4bo7hi7NfqjE9blG90Z5S_mYZRRgDSFnoIjVRptrREy35q65WafA8n79-Qn7_FOeHSsZ9VamL_k_6Vv8cyUZA</recordid><startdate>20210201</startdate><enddate>20210201</enddate><creator>Shmelev, M. A.</creator><creator>Kuznetsova, G. N.</creator><creator>Dolgushin, F. M.</creator><creator>Voronina, Yu. K.</creator><creator>Gogoleva, N. V.</creator><creator>Kiskin, M. A.</creator><creator>Ivanov, V. K.</creator><creator>Sidorov, A. A.</creator><creator>Eremenko, I. L.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20210201</creationdate><title>Influence of the Fluorinated Aromatic Fragments on the Structures of the Cadmium and Zinc Carboxylate Complexes Using Pentafluorobenzoates and 2,3,4,5-Tetrafluorobenzoates as Examples</title><author>Shmelev, M. A. ; Kuznetsova, G. N. ; Dolgushin, F. M. ; Voronina, Yu. K. ; Gogoleva, N. V. ; Kiskin, M. A. ; Ivanov, V. K. ; Sidorov, A. A. ; Eremenko, I. L.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-419fd23ca59537aab79400f3ae87fd15f810aa13b3144dea886d19df5bb57953</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Anions</topic><topic>Cadmium</topic><topic>Cadmium compounds</topic><topic>Chemical synthesis</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Coordination polymers</topic><topic>Fluorination</topic><topic>Inorganic Chemistry</topic><topic>Ligands</topic><topic>Physical Chemistry</topic><topic>Quinoline</topic><topic>Water chemistry</topic><topic>Zinc compounds</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Shmelev, M. A.</creatorcontrib><creatorcontrib>Kuznetsova, G. N.</creatorcontrib><creatorcontrib>Dolgushin, F. M.</creatorcontrib><creatorcontrib>Voronina, Yu. K.</creatorcontrib><creatorcontrib>Gogoleva, N. V.</creatorcontrib><creatorcontrib>Kiskin, M. A.</creatorcontrib><creatorcontrib>Ivanov, V. K.</creatorcontrib><creatorcontrib>Sidorov, A. A.</creatorcontrib><creatorcontrib>Eremenko, I. L.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of coordination chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Shmelev, M. A.</au><au>Kuznetsova, G. N.</au><au>Dolgushin, F. M.</au><au>Voronina, Yu. K.</au><au>Gogoleva, N. V.</au><au>Kiskin, M. A.</au><au>Ivanov, V. K.</au><au>Sidorov, A. A.</au><au>Eremenko, I. L.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Influence of the Fluorinated Aromatic Fragments on the Structures of the Cadmium and Zinc Carboxylate Complexes Using Pentafluorobenzoates and 2,3,4,5-Tetrafluorobenzoates as Examples</atitle><jtitle>Russian journal of coordination chemistry</jtitle><stitle>Russ J Coord Chem</stitle><date>2021-02-01</date><risdate>2021</risdate><volume>47</volume><issue>2</issue><spage>127</spage><epage>143</epage><pages>127-143</pages><issn>1070-3284</issn><eissn>1608-3318</eissn><abstract>A series of the cadmium and zinc carboxylate complexes with anions of pentafluorobenzoic (HРfbz) and 2,3,4,5-tetrafluorobenzoic (HТfbz) acids and N
-
donor ligands (1,10-phenanthroline (Phen) and quinoline (Quin)), [Cd(Pfbz)
2
(Phen)]
n
(
I
), [Cd(Рfbz)
2
(Рhen)
2
]·2MeCN (
II
), [Zn(H
2
O)-(Рfbz)
2
(Рhen)] (
III
), [Zn
2
Cd(Рfbz)
6
(Рhen)
2
]⋅2C
6
H
6
(
IV
), [Cd
2
(H
2
O)
2
(Tfbz)
4
(Рhen)
2
] (
V
), [Cd
2
-(H
2
O)
2
(Tfbz)
4
(Quin)
2
] (
VI
), and [Cd(Tfbz)
2
(Phen)
2
]⋅HTfbz (
VII
), is synthesized. The structures of new complexes
I
–
VII
are determined by X-ray diffraction analysis (CIF files CCDC nos. 1871300, 2005461, 2005462, 2005464, 2005466, 2005465, and 2005459, respectively). The majority of the synthesized compounds is typical of intramolecular stacking interactions between the coordinated molecules of the aromatic N
-
donor ligands and fluorinated substituents of the carboxylate anions. These interactions lead to the formation of unusual compounds, which are different in the cases of pentafluorobenzoates and tetrafluorobenzoates, in particular, coordination polymer
I
and binuclear complexes
V
and
VI
with coordinated water molecules. The synthesized zinc and cadmium compounds differ in structure and composition.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S1070328421020068</doi><tpages>17</tpages></addata></record> |
| fulltext | fulltext |
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| ispartof | Russian journal of coordination chemistry, 2021-02, Vol.47 (2), p.127-143 |
| issn | 1070-3284 1608-3318 |
| language | eng |
| recordid | cdi_proquest_journals_2493117715 |
| source | Springer Link |
| subjects | Anions Cadmium Cadmium compounds Chemical synthesis Chemistry Chemistry and Materials Science Coordination polymers Fluorination Inorganic Chemistry Ligands Physical Chemistry Quinoline Water chemistry Zinc compounds |
| title | Influence of the Fluorinated Aromatic Fragments on the Structures of the Cadmium and Zinc Carboxylate Complexes Using Pentafluorobenzoates and 2,3,4,5-Tetrafluorobenzoates as Examples |
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