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Nanocomposite polymer electrolytes comprising starch-lithium acetate and titania for all-solid-state supercapacitor
A nanocomposite solid polymer electrolyte (SPE) system has been prepared for application in a supercapacitor. Corn starch is used to host the ionic conduction with lithium acetate (LiOAc) salt as an ion provider. Different concentrations of nanosized titanium dioxide (TiO 2 ) filler have been added...
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| Published in: | Ionics 2021-02, Vol.27 (2), p.853-865 |
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| Main Authors: | , , , , |
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| Language: | English |
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| cites | cdi_FETCH-LOGICAL-c363t-a78b118a610e38c42132d297d8e5f31a2168b9ba1508c2400011d5a25455ffd03 |
| container_end_page | 865 |
| container_issue | 2 |
| container_start_page | 853 |
| container_title | Ionics |
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| creator | Ong, A. C. W. Shamsuri, N. A. Zaine, S. N. A. Panuh, Dedikarni Shukur, M. F. |
| description | A nanocomposite solid polymer electrolyte (SPE) system has been prepared for application in a supercapacitor. Corn starch is used to host the ionic conduction with lithium acetate (LiOAc) salt as an ion provider. Different concentrations of nanosized titanium dioxide (TiO
2
) filler have been added to analyse the influence of nanofiller addition on the conductivity and other properties of the electrolytes. Structural characterisation and complex formation have been examined by X-ray diffraction (XRD) and Fourier transform infrared (FTIR) spectroscopy, respectively. It is shown that the room temperature conductivity changes with the change in TiO
2
concentration. Adding 4 wt.% TiO
2
to the starch-LiOAc complex leads to an optimum conductivity of (8.37 ± 1.04) × 10
−4
S cm
−1
. The variation in conductivity is accompanied by the change in surface morphology as observed from field emission scanning electron microscopy (FESEM) analysis. Linear sweep voltammetry (LSV) indicates that the electrochemical potential stability window of the electrolyte with 4 wt.% TiO
2
lies in the range between − 2.0 and + 1.9 V. A supercapacitor has been assembled using the electrolyte, and its performance has been characterised using impedance technique and cyclic voltammetry. |
| doi_str_mv | 10.1007/s11581-020-03856-3 |
| format | article |
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2
) filler have been added to analyse the influence of nanofiller addition on the conductivity and other properties of the electrolytes. Structural characterisation and complex formation have been examined by X-ray diffraction (XRD) and Fourier transform infrared (FTIR) spectroscopy, respectively. It is shown that the room temperature conductivity changes with the change in TiO
2
concentration. Adding 4 wt.% TiO
2
to the starch-LiOAc complex leads to an optimum conductivity of (8.37 ± 1.04) × 10
−4
S cm
−1
. The variation in conductivity is accompanied by the change in surface morphology as observed from field emission scanning electron microscopy (FESEM) analysis. Linear sweep voltammetry (LSV) indicates that the electrochemical potential stability window of the electrolyte with 4 wt.% TiO
2
lies in the range between − 2.0 and + 1.9 V. A supercapacitor has been assembled using the electrolyte, and its performance has been characterised using impedance technique and cyclic voltammetry.</description><identifier>ISSN: 0947-7047</identifier><identifier>EISSN: 1862-0760</identifier><identifier>DOI: 10.1007/s11581-020-03856-3</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Chemistry ; Chemistry and Materials Science ; Complex formation ; Condensed Matter Physics ; Electrochemical potential ; Electrochemistry ; Electrolytes ; Emission analysis ; Energy Storage ; Field emission microscopy ; Fourier transforms ; Lithium ; Morphology ; Nanocomposites ; Optical and Electronic Materials ; Original Paper ; Renewable and Green Energy ; Room temperature ; Stability analysis ; Supercapacitors ; Thermal conductivity ; Titanium dioxide ; Voltammetry</subject><ispartof>Ionics, 2021-02, Vol.27 (2), p.853-865</ispartof><rights>Springer-Verlag GmbH Germany, part of Springer Nature 2020</rights><rights>Springer-Verlag GmbH Germany, part of Springer Nature 2020.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c363t-a78b118a610e38c42132d297d8e5f31a2168b9ba1508c2400011d5a25455ffd03</citedby><cites>FETCH-LOGICAL-c363t-a78b118a610e38c42132d297d8e5f31a2168b9ba1508c2400011d5a25455ffd03</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>315,786,790,27957,27958</link.rule.ids></links><search><creatorcontrib>Ong, A. C. W.</creatorcontrib><creatorcontrib>Shamsuri, N. A.</creatorcontrib><creatorcontrib>Zaine, S. N. A.</creatorcontrib><creatorcontrib>Panuh, Dedikarni</creatorcontrib><creatorcontrib>Shukur, M. F.</creatorcontrib><title>Nanocomposite polymer electrolytes comprising starch-lithium acetate and titania for all-solid-state supercapacitor</title><title>Ionics</title><addtitle>Ionics</addtitle><description>A nanocomposite solid polymer electrolyte (SPE) system has been prepared for application in a supercapacitor. Corn starch is used to host the ionic conduction with lithium acetate (LiOAc) salt as an ion provider. Different concentrations of nanosized titanium dioxide (TiO
2
) filler have been added to analyse the influence of nanofiller addition on the conductivity and other properties of the electrolytes. Structural characterisation and complex formation have been examined by X-ray diffraction (XRD) and Fourier transform infrared (FTIR) spectroscopy, respectively. It is shown that the room temperature conductivity changes with the change in TiO
2
concentration. Adding 4 wt.% TiO
2
to the starch-LiOAc complex leads to an optimum conductivity of (8.37 ± 1.04) × 10
−4
S cm
−1
. The variation in conductivity is accompanied by the change in surface morphology as observed from field emission scanning electron microscopy (FESEM) analysis. Linear sweep voltammetry (LSV) indicates that the electrochemical potential stability window of the electrolyte with 4 wt.% TiO
2
lies in the range between − 2.0 and + 1.9 V. A supercapacitor has been assembled using the electrolyte, and its performance has been characterised using impedance technique and cyclic voltammetry.</description><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Complex formation</subject><subject>Condensed Matter Physics</subject><subject>Electrochemical potential</subject><subject>Electrochemistry</subject><subject>Electrolytes</subject><subject>Emission analysis</subject><subject>Energy Storage</subject><subject>Field emission microscopy</subject><subject>Fourier transforms</subject><subject>Lithium</subject><subject>Morphology</subject><subject>Nanocomposites</subject><subject>Optical and Electronic Materials</subject><subject>Original Paper</subject><subject>Renewable and Green Energy</subject><subject>Room temperature</subject><subject>Stability analysis</subject><subject>Supercapacitors</subject><subject>Thermal conductivity</subject><subject>Titanium dioxide</subject><subject>Voltammetry</subject><issn>0947-7047</issn><issn>1862-0760</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp9kM1OwzAQhC0EEqXwApwicTbs2knsHlHFn1TBBc7W1nFaV2kcbPfQtydtkbhxWq1mvlntMHaLcI8A6iEhVho5COAgdVVzecYmqGvBQdVwziYwKxVXUKpLdpXSBqCuUagJS-_UBxu2Q0g-u2II3X7rYuE6Z3Mcl-xScZCjT75fFSlTtGve-bz2u21B1mUaMeqbIvtMvaeiDbGgruMpdL7h6ain3eCipYGszyFes4uWuuRufueUfT0_fc5f-eLj5W3-uOBW1jJzUnqJqKlGcFLbUqAUjZipRruqlUgCa72cLQkr0FaUAIDYVCSqsqratgE5ZXen3CGG751L2WzCLvbjSSNKDaDlTKjRJU4uG0NK0bVmfHZLcW8QzKFccyrXjOWaY7lGjpA8QWk09ysX_6L_oX4A4Vd-ng</recordid><startdate>20210201</startdate><enddate>20210201</enddate><creator>Ong, A. C. W.</creator><creator>Shamsuri, N. A.</creator><creator>Zaine, S. N. A.</creator><creator>Panuh, Dedikarni</creator><creator>Shukur, M. F.</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20210201</creationdate><title>Nanocomposite polymer electrolytes comprising starch-lithium acetate and titania for all-solid-state supercapacitor</title><author>Ong, A. C. W. ; Shamsuri, N. A. ; Zaine, S. N. A. ; Panuh, Dedikarni ; Shukur, M. F.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c363t-a78b118a610e38c42132d297d8e5f31a2168b9ba1508c2400011d5a25455ffd03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Complex formation</topic><topic>Condensed Matter Physics</topic><topic>Electrochemical potential</topic><topic>Electrochemistry</topic><topic>Electrolytes</topic><topic>Emission analysis</topic><topic>Energy Storage</topic><topic>Field emission microscopy</topic><topic>Fourier transforms</topic><topic>Lithium</topic><topic>Morphology</topic><topic>Nanocomposites</topic><topic>Optical and Electronic Materials</topic><topic>Original Paper</topic><topic>Renewable and Green Energy</topic><topic>Room temperature</topic><topic>Stability analysis</topic><topic>Supercapacitors</topic><topic>Thermal conductivity</topic><topic>Titanium dioxide</topic><topic>Voltammetry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ong, A. C. W.</creatorcontrib><creatorcontrib>Shamsuri, N. A.</creatorcontrib><creatorcontrib>Zaine, S. N. A.</creatorcontrib><creatorcontrib>Panuh, Dedikarni</creatorcontrib><creatorcontrib>Shukur, M. F.</creatorcontrib><collection>CrossRef</collection><jtitle>Ionics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ong, A. C. W.</au><au>Shamsuri, N. A.</au><au>Zaine, S. N. A.</au><au>Panuh, Dedikarni</au><au>Shukur, M. F.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Nanocomposite polymer electrolytes comprising starch-lithium acetate and titania for all-solid-state supercapacitor</atitle><jtitle>Ionics</jtitle><stitle>Ionics</stitle><date>2021-02-01</date><risdate>2021</risdate><volume>27</volume><issue>2</issue><spage>853</spage><epage>865</epage><pages>853-865</pages><issn>0947-7047</issn><eissn>1862-0760</eissn><abstract>A nanocomposite solid polymer electrolyte (SPE) system has been prepared for application in a supercapacitor. Corn starch is used to host the ionic conduction with lithium acetate (LiOAc) salt as an ion provider. Different concentrations of nanosized titanium dioxide (TiO
2
) filler have been added to analyse the influence of nanofiller addition on the conductivity and other properties of the electrolytes. Structural characterisation and complex formation have been examined by X-ray diffraction (XRD) and Fourier transform infrared (FTIR) spectroscopy, respectively. It is shown that the room temperature conductivity changes with the change in TiO
2
concentration. Adding 4 wt.% TiO
2
to the starch-LiOAc complex leads to an optimum conductivity of (8.37 ± 1.04) × 10
−4
S cm
−1
. The variation in conductivity is accompanied by the change in surface morphology as observed from field emission scanning electron microscopy (FESEM) analysis. Linear sweep voltammetry (LSV) indicates that the electrochemical potential stability window of the electrolyte with 4 wt.% TiO
2
lies in the range between − 2.0 and + 1.9 V. A supercapacitor has been assembled using the electrolyte, and its performance has been characterised using impedance technique and cyclic voltammetry.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s11581-020-03856-3</doi><tpages>13</tpages><oa>free_for_read</oa></addata></record> |
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| language | eng |
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| source | Springer Nature:Jisc Collections:Springer Nature Read and Publish 2023-2025: Springer Reading List |
| subjects | Chemistry Chemistry and Materials Science Complex formation Condensed Matter Physics Electrochemical potential Electrochemistry Electrolytes Emission analysis Energy Storage Field emission microscopy Fourier transforms Lithium Morphology Nanocomposites Optical and Electronic Materials Original Paper Renewable and Green Energy Room temperature Stability analysis Supercapacitors Thermal conductivity Titanium dioxide Voltammetry |
| title | Nanocomposite polymer electrolytes comprising starch-lithium acetate and titania for all-solid-state supercapacitor |
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