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A new triazine-based conjugated polymer from simple monomers with stable photocatalytic hydrogen evolution under visible light
A new triazine-based conjugated polymer THT-TA was constructed with simple building blocks 2,4,6-trihydrazino-1,3,5-triazine (THT) and terephthalaldehyde (TA) via solvothermal reaction. The structural characterizations confirmed the successful synthesis of the polymer, and TEM images clearly reveale...
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Published in: | Polymer (Guilford) 2020-12, Vol.211, p.123079, Article 123079 |
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creator | Cui, Zhiwei Hu, Yue Zhang, Yukang Han, Qiutong Wang, Ying Zhou, Yong Zou, Zhigang |
description | A new triazine-based conjugated polymer THT-TA was constructed with simple building blocks 2,4,6-trihydrazino-1,3,5-triazine (THT) and terephthalaldehyde (TA) via solvothermal reaction. The structural characterizations confirmed the successful synthesis of the polymer, and TEM images clearly revealed the sheet-like morphology. The 2D layered structure was further confirmed by XRD, and the semi-crystalline pattern was better fitted with a novel parallelogram framework rather than classic hexagonal framework. The optical band gap of THT-TA was 2.50 eV, and the frontier orbitals were delocalized across the framework from DFT calculation, validating that higher degree of conjugation was achieved from small monomers. The photocatalytic hydrogen evolution was successfully achieved with Pt as co-catalyst and sodium ascorbate as sacrificial agent under visible light (λ > 420 nm), and the sample showed considerable stability in the long-term test for more than 200 h.
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•A new triazine-based conjugated polymer THT-TA was synthesized.•The 2D layered polymer exhibited parallelogram framework and conjugated π system.•THT-TA showed stable photocatalytic activity of H2 evolution for more than 200 h. |
doi_str_mv | 10.1016/j.polymer.2020.123079 |
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•A new triazine-based conjugated polymer THT-TA was synthesized.•The 2D layered polymer exhibited parallelogram framework and conjugated π system.•THT-TA showed stable photocatalytic activity of H2 evolution for more than 200 h.</description><identifier>ISSN: 0032-3861</identifier><identifier>EISSN: 1873-2291</identifier><identifier>DOI: 10.1016/j.polymer.2020.123079</identifier><language>eng</language><publisher>Kidlington: Elsevier Ltd</publisher><subject>Ascorbic acid ; Catalysts ; Chemical synthesis ; Conjugated polymer ; Conjugation ; Hydrogen evolution ; Monomers ; Morphology ; Photocatalysis ; Polymers ; Triazine</subject><ispartof>Polymer (Guilford), 2020-12, Vol.211, p.123079, Article 123079</ispartof><rights>2020 Elsevier Ltd</rights><rights>Copyright Elsevier BV Dec 21, 2020</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c337t-405500cf70a924d6e25d9a14d3b42cb58c7e27c94cc098e922c3226480450bd43</citedby><cites>FETCH-LOGICAL-c337t-405500cf70a924d6e25d9a14d3b42cb58c7e27c94cc098e922c3226480450bd43</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>315,786,790,27957,27958</link.rule.ids></links><search><creatorcontrib>Cui, Zhiwei</creatorcontrib><creatorcontrib>Hu, Yue</creatorcontrib><creatorcontrib>Zhang, Yukang</creatorcontrib><creatorcontrib>Han, Qiutong</creatorcontrib><creatorcontrib>Wang, Ying</creatorcontrib><creatorcontrib>Zhou, Yong</creatorcontrib><creatorcontrib>Zou, Zhigang</creatorcontrib><title>A new triazine-based conjugated polymer from simple monomers with stable photocatalytic hydrogen evolution under visible light</title><title>Polymer (Guilford)</title><description>A new triazine-based conjugated polymer THT-TA was constructed with simple building blocks 2,4,6-trihydrazino-1,3,5-triazine (THT) and terephthalaldehyde (TA) via solvothermal reaction. The structural characterizations confirmed the successful synthesis of the polymer, and TEM images clearly revealed the sheet-like morphology. The 2D layered structure was further confirmed by XRD, and the semi-crystalline pattern was better fitted with a novel parallelogram framework rather than classic hexagonal framework. The optical band gap of THT-TA was 2.50 eV, and the frontier orbitals were delocalized across the framework from DFT calculation, validating that higher degree of conjugation was achieved from small monomers. The photocatalytic hydrogen evolution was successfully achieved with Pt as co-catalyst and sodium ascorbate as sacrificial agent under visible light (λ > 420 nm), and the sample showed considerable stability in the long-term test for more than 200 h.
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•A new triazine-based conjugated polymer THT-TA was synthesized.•The 2D layered polymer exhibited parallelogram framework and conjugated π system.•THT-TA showed stable photocatalytic activity of H2 evolution for more than 200 h.</description><subject>Ascorbic acid</subject><subject>Catalysts</subject><subject>Chemical synthesis</subject><subject>Conjugated polymer</subject><subject>Conjugation</subject><subject>Hydrogen evolution</subject><subject>Monomers</subject><subject>Morphology</subject><subject>Photocatalysis</subject><subject>Polymers</subject><subject>Triazine</subject><issn>0032-3861</issn><issn>1873-2291</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNqFUMFqGzEQFSGFOG4_oSDoed1ZSetdnUoITVsI9JKchVYa21p2pa2kdXAO_fbK2PfOZYY3771hHiGfa9jUUG-_Dps5jKcJ44YBKxjj0Mobsqq7lleMyfqWrAA4q3i3re_IfUoDALCGiRX5-0A9vtEcnX53HqteJ7TUBD8se53LeLWmuxgmmtw0j0in4EPBEn1z-UBT1n0B50PIweisx1N2hh5ONoY9eorHMC7ZBU8Xb4vR0SV35o9uf8gfyYedHhN-uvY1eX36_vL4s3r-_ePX48NzZThvcyWgaQDMrgUtmbBbZI2VuhaW94KZvulMi6w1UhgDskPJmOGMbUUHooHeCr4mXy6-cwx_FkxZDWGJvpxUrLBKyU4WVnNhmRhSirhTc3STjidVgzpHrQZ1zUOdo1aXqIvu20WH5YWjK9tkHHqD1kU0Wdng_uPwD0dijLA</recordid><startdate>20201221</startdate><enddate>20201221</enddate><creator>Cui, Zhiwei</creator><creator>Hu, Yue</creator><creator>Zhang, Yukang</creator><creator>Han, Qiutong</creator><creator>Wang, Ying</creator><creator>Zhou, Yong</creator><creator>Zou, Zhigang</creator><general>Elsevier Ltd</general><general>Elsevier BV</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7QO</scope><scope>7QQ</scope><scope>7SC</scope><scope>7SE</scope><scope>7SP</scope><scope>7SR</scope><scope>7T7</scope><scope>7TA</scope><scope>7TB</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>C1K</scope><scope>F28</scope><scope>FR3</scope><scope>H8D</scope><scope>H8G</scope><scope>JG9</scope><scope>JQ2</scope><scope>KR7</scope><scope>L7M</scope><scope>L~C</scope><scope>L~D</scope><scope>P64</scope></search><sort><creationdate>20201221</creationdate><title>A new triazine-based conjugated polymer from simple monomers with stable photocatalytic hydrogen evolution under visible light</title><author>Cui, Zhiwei ; Hu, Yue ; Zhang, Yukang ; Han, Qiutong ; Wang, Ying ; Zhou, Yong ; Zou, Zhigang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c337t-405500cf70a924d6e25d9a14d3b42cb58c7e27c94cc098e922c3226480450bd43</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Ascorbic acid</topic><topic>Catalysts</topic><topic>Chemical synthesis</topic><topic>Conjugated polymer</topic><topic>Conjugation</topic><topic>Hydrogen evolution</topic><topic>Monomers</topic><topic>Morphology</topic><topic>Photocatalysis</topic><topic>Polymers</topic><topic>Triazine</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Cui, Zhiwei</creatorcontrib><creatorcontrib>Hu, Yue</creatorcontrib><creatorcontrib>Zhang, Yukang</creatorcontrib><creatorcontrib>Han, Qiutong</creatorcontrib><creatorcontrib>Wang, Ying</creatorcontrib><creatorcontrib>Zhou, Yong</creatorcontrib><creatorcontrib>Zou, Zhigang</creatorcontrib><collection>CrossRef</collection><collection>Aluminium Industry Abstracts</collection><collection>Biotechnology Research Abstracts</collection><collection>Ceramic Abstracts</collection><collection>Computer and Information Systems Abstracts</collection><collection>Corrosion Abstracts</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Industrial and Applied Microbiology Abstracts (Microbiology A)</collection><collection>Materials Business File</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Aerospace Database</collection><collection>Copper Technical Reference Library</collection><collection>Materials Research Database</collection><collection>ProQuest Computer Science Collection</collection><collection>Civil Engineering Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Computer and Information Systems Abstracts Academic</collection><collection>Computer and Information Systems Abstracts Professional</collection><collection>Biotechnology and BioEngineering Abstracts</collection><jtitle>Polymer (Guilford)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Cui, Zhiwei</au><au>Hu, Yue</au><au>Zhang, Yukang</au><au>Han, Qiutong</au><au>Wang, Ying</au><au>Zhou, Yong</au><au>Zou, Zhigang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A new triazine-based conjugated polymer from simple monomers with stable photocatalytic hydrogen evolution under visible light</atitle><jtitle>Polymer (Guilford)</jtitle><date>2020-12-21</date><risdate>2020</risdate><volume>211</volume><spage>123079</spage><pages>123079-</pages><artnum>123079</artnum><issn>0032-3861</issn><eissn>1873-2291</eissn><abstract>A new triazine-based conjugated polymer THT-TA was constructed with simple building blocks 2,4,6-trihydrazino-1,3,5-triazine (THT) and terephthalaldehyde (TA) via solvothermal reaction. The structural characterizations confirmed the successful synthesis of the polymer, and TEM images clearly revealed the sheet-like morphology. The 2D layered structure was further confirmed by XRD, and the semi-crystalline pattern was better fitted with a novel parallelogram framework rather than classic hexagonal framework. The optical band gap of THT-TA was 2.50 eV, and the frontier orbitals were delocalized across the framework from DFT calculation, validating that higher degree of conjugation was achieved from small monomers. The photocatalytic hydrogen evolution was successfully achieved with Pt as co-catalyst and sodium ascorbate as sacrificial agent under visible light (λ > 420 nm), and the sample showed considerable stability in the long-term test for more than 200 h.
[Display omitted]
•A new triazine-based conjugated polymer THT-TA was synthesized.•The 2D layered polymer exhibited parallelogram framework and conjugated π system.•THT-TA showed stable photocatalytic activity of H2 evolution for more than 200 h.</abstract><cop>Kidlington</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.polymer.2020.123079</doi></addata></record> |
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subjects | Ascorbic acid Catalysts Chemical synthesis Conjugated polymer Conjugation Hydrogen evolution Monomers Morphology Photocatalysis Polymers Triazine |
title | A new triazine-based conjugated polymer from simple monomers with stable photocatalytic hydrogen evolution under visible light |
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