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Carnauba straw powder treated with bentonite for copper adsorption in aqueous solution: isothermal, kinetic and thermodynamic study
In this work, the natural and modified carnauba powder from the addition of bentonite was evaluated for the adsorption of Cu(II) ions in synthetic solution. The results showed that the carnauba powder treated with bentonite (CPTB) showed a better percentage of removal of Cu(II) ions when compared to...
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Published in: | Water science and technology 2020-11, Vol.82 (10), p.2178-2192 |
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creator | Pereira, Jéssyca E S Silva, Alfredo J F Nascimento, Paula F P Ferreira, Ruan L S Barros Neto, Eduardo L |
description | In this work, the natural and modified carnauba powder from the addition of bentonite was evaluated for the adsorption of Cu(II) ions in synthetic solution. The results showed that the carnauba powder treated with bentonite (CPTB) showed a better percentage of removal of Cu(II) ions when compared to natural carnauba powder (NCP). The best results for both adsorbents were obtained with pH 5. The adsorption kinetics was governed by the pseudo-second-order model for both bioadsorbents studied. While the isothermal behavior was governed by the Langmuir model and showed that the adsorption capacity of the CPTB for Cu(II) was 21.98 mg·g
. The interaction of the metal and CPTB was also investigated by means of thermodynamic parameters showing that the adsorption process is not spontaneous, although the values of ΔG° decrease with the increase in temperature from 20 to 40 °C and endothermic causing an increase in the degree of disorder at the solid/liquid interface. The results showed that the CPTB is a material with potential adsorbent for the removal of copper ions. |
doi_str_mv | 10.2166/wst.2020.491 |
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. The interaction of the metal and CPTB was also investigated by means of thermodynamic parameters showing that the adsorption process is not spontaneous, although the values of ΔG° decrease with the increase in temperature from 20 to 40 °C and endothermic causing an increase in the degree of disorder at the solid/liquid interface. The results showed that the CPTB is a material with potential adsorbent for the removal of copper ions.</description><identifier>ISSN: 0273-1223</identifier><identifier>EISSN: 1996-9732</identifier><identifier>DOI: 10.2166/wst.2020.491</identifier><identifier>PMID: 33263594</identifier><language>eng</language><publisher>England: IWA Publishing</publisher><subject>Adsorbents ; Adsorption ; Aqueous solutions ; Bentonite ; Copper ; Effluents ; Environmental impact ; Heavy metals ; Hydrogen-Ion Concentration ; Ions ; Kinetics ; Metals ; Pore size ; Powder ; Powders ; Removal ; Thermodynamics ; Water Pollutants, Chemical - analysis</subject><ispartof>Water science and technology, 2020-11, Vol.82 (10), p.2178-2192</ispartof><rights>Copyright IWA Publishing Nov 2020</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c357t-cb145c7be638b6181126f29ddec026428c4bb6e7975ceb021c24cda7413e3fff3</citedby><cites>FETCH-LOGICAL-c357t-cb145c7be638b6181126f29ddec026428c4bb6e7975ceb021c24cda7413e3fff3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>315,786,790,27957,27958</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/33263594$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Pereira, Jéssyca E S</creatorcontrib><creatorcontrib>Silva, Alfredo J F</creatorcontrib><creatorcontrib>Nascimento, Paula F P</creatorcontrib><creatorcontrib>Ferreira, Ruan L S</creatorcontrib><creatorcontrib>Barros Neto, Eduardo L</creatorcontrib><title>Carnauba straw powder treated with bentonite for copper adsorption in aqueous solution: isothermal, kinetic and thermodynamic study</title><title>Water science and technology</title><addtitle>Water Sci Technol</addtitle><description>In this work, the natural and modified carnauba powder from the addition of bentonite was evaluated for the adsorption of Cu(II) ions in synthetic solution. The results showed that the carnauba powder treated with bentonite (CPTB) showed a better percentage of removal of Cu(II) ions when compared to natural carnauba powder (NCP). The best results for both adsorbents were obtained with pH 5. The adsorption kinetics was governed by the pseudo-second-order model for both bioadsorbents studied. While the isothermal behavior was governed by the Langmuir model and showed that the adsorption capacity of the CPTB for Cu(II) was 21.98 mg·g
. The interaction of the metal and CPTB was also investigated by means of thermodynamic parameters showing that the adsorption process is not spontaneous, although the values of ΔG° decrease with the increase in temperature from 20 to 40 °C and endothermic causing an increase in the degree of disorder at the solid/liquid interface. 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The results showed that the carnauba powder treated with bentonite (CPTB) showed a better percentage of removal of Cu(II) ions when compared to natural carnauba powder (NCP). The best results for both adsorbents were obtained with pH 5. The adsorption kinetics was governed by the pseudo-second-order model for both bioadsorbents studied. While the isothermal behavior was governed by the Langmuir model and showed that the adsorption capacity of the CPTB for Cu(II) was 21.98 mg·g
. The interaction of the metal and CPTB was also investigated by means of thermodynamic parameters showing that the adsorption process is not spontaneous, although the values of ΔG° decrease with the increase in temperature from 20 to 40 °C and endothermic causing an increase in the degree of disorder at the solid/liquid interface. The results showed that the CPTB is a material with potential adsorbent for the removal of copper ions.</abstract><cop>England</cop><pub>IWA Publishing</pub><pmid>33263594</pmid><doi>10.2166/wst.2020.491</doi><tpages>15</tpages><oa>free_for_read</oa></addata></record> |
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subjects | Adsorbents Adsorption Aqueous solutions Bentonite Copper Effluents Environmental impact Heavy metals Hydrogen-Ion Concentration Ions Kinetics Metals Pore size Powder Powders Removal Thermodynamics Water Pollutants, Chemical - analysis |
title | Carnauba straw powder treated with bentonite for copper adsorption in aqueous solution: isothermal, kinetic and thermodynamic study |
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