Divergent Chemistry Paths for 3D and 1D Metallo‐Covalent Organic Frameworks (COFs)

The marriage of dynamic covalent chemistry (DCC) and coordination chemistry is a powerful tool for assembling complex architectures from simple building units. Recently, the synthesis of woven covalent organic frameworks (COFs) with topologically fascinating structures has been achieved using this a...

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Published in:Angewandte Chemie 2020-07, Vol.132 (28), p.11624-11629
Main Authors: Xu, Hai‐Sen, Luo, Yi, See, Pei Zhen, Li, Xing, Chen, Zhongxin, Zhou, Yi, Zhao, Xiaoxu, Leng, Kai, Park, In‐Hyeok, Li, Runlai, Liu, Cuibo, Chen, Fangzheng, Xi, Shibo, Sun, Junliang, Loh, Kian Ping
Format: Article
Language:English
Subjects:
Assembling
Chemistry
Covalence
covalent organic frameworks (COFs)
dynamic covalent chemistry (DCC)
metal templates
Metallography
self-assembly
structure elucidation
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cited_by cdi_FETCH-LOGICAL-c1624-8477135f60957cf4ed07b2c8ae0fc9ad521f31c64b325931647afad83bdacf5a3
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container_end_page 11629
container_issue 28
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container_title Angewandte Chemie
container_volume 132
creator Xu, Hai‐Sen
Luo, Yi
See, Pei Zhen
Li, Xing
Chen, Zhongxin
Zhou, Yi
Zhao, Xiaoxu
Leng, Kai
Park, In‐Hyeok
Li, Runlai
Liu, Cuibo
Chen, Fangzheng
Xi, Shibo
Sun, Junliang
Loh, Kian Ping
description The marriage of dynamic covalent chemistry (DCC) and coordination chemistry is a powerful tool for assembling complex architectures from simple building units. Recently, the synthesis of woven covalent organic frameworks (COFs) with topologically fascinating structures has been achieved using this approach. However, the scope is highly limited and there is a need to discover new pathways that can assemble covalently linked organic threads into crystalline frameworks. Herein, we have identified branching pathways leading to the assembly of three‐dimensional (3D) woven COFs or one‐dimensional (1D) metallo‐COFs (mCOFs), where the mechanism is underpinned by the absence or presence of ligand exchange. What far from tangled webs we weave: By combining dynamic covalent chemistry (DCC) and coordination chemistry, divergent paths for the construction of three‐dimensional (3D) woven covalent organic frameworks (COFs) or one‐dimensional (1D) metallo‐COFs (mCOFs) are identified. The paths are distinguished by the absence or presence of ligand exchange.
doi_str_mv 10.1002/ange.202002724
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source Wiley-Blackwell Journals
subjects Assembling
Chemistry
Covalence
covalent organic frameworks (COFs)
dynamic covalent chemistry (DCC)
metal templates
Metallography
self-assembly
structure elucidation
title Divergent Chemistry Paths for 3D and 1D Metallo‐Covalent Organic Frameworks (COFs)
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