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Novel zinc-iodine hybrid supercapacitors with a redox iodide ion electrolyte and B, N dual-doped carbon electrode exhibit boosted energy density
With the development of modern society, energy storage has gradually become a crucial issue for portable devices and electric vehicles. Recently, zinc-ion hybrid supercapacitors (ZHSs), a new type of energy storage devices, have received significant attention mainly because zinc possesses many advan...
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| Published in: | Journal of materials chemistry. A, Materials for energy and sustainability Materials for energy and sustainability, 2019, Vol.7 (42), p.244-2447 |
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| cites | cdi_FETCH-LOGICAL-c318t-d979040d28fb4fce3115bb6adc6ffa95f8d59690dd8010389682fe8a29e570e73 |
| container_end_page | 2447 |
| container_issue | 42 |
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| container_title | Journal of materials chemistry. A, Materials for energy and sustainability |
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| creator | Han, Lu Huang, Hailong Li, Junfeng Yang, Zhongli Zhang, Xinlu Zhang, Dafeng Liu, Xinjuan Xu, Min Pan, Likun |
| description | With the development of modern society, energy storage has gradually become a crucial issue for portable devices and electric vehicles. Recently, zinc-ion hybrid supercapacitors (ZHSs), a new type of energy storage devices, have received significant attention mainly because zinc possesses many advantages such as natural abundance, low cost, non-toxicity and high safety. However, the limited energy density of the currently reported ZHSs should be further improved to achieve their large-scale applications. Herein, we designed novel zinc-iodine hybrid supercapacitors (Z-IHS) by introducing a redox iodide ion into the ZnSO
4
electrolyte to improve the energy density and employing B, N dual-doped porous carbon microtubes (BN-CMTs) as a cathode to facilitate the faradaic reaction on the electrode surface by changing the electronic structure and density state of carbon. The BN-CMT-based Z-IHS exhibits the amazingly high capacity of 416.6 mA h g
−1
, a high energy density (472.6 W h kg
−1
) at the power density of 1600 W kg
−1
in the voltage range of 0.2-1.8 V and excellent cycling stability with the capacity retention of 99.1% over 10 000 cycles at 10 A g
−1
. The strategy proposed in this study should provide a new insight into the exploration of high energy-density storage devices.
A novel high-energy-density zinc-iodine hybrid supercapacitor was designed
via
the introduction of a redox iodide ion electrolyte and B, N dual-doped carbon electrode. |
| doi_str_mv | 10.1039/c9ta07196b |
| format | article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2309913972</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2309913972</sourcerecordid><originalsourceid>FETCH-LOGICAL-c318t-d979040d28fb4fce3115bb6adc6ffa95f8d59690dd8010389682fe8a29e570e73</originalsourceid><addsrcrecordid>eNpF0btOwzAUBuAIgURVurAjWWJDBOykSXzGtuImVWUpc-TLCXUV4mC70PAUPDIpRfQs_xk-29LvKDpn9IbRFG4VBEELBrk8igYJzWhcjCE__t85P41G3q9pP5zSHGAQfS_sB9bkyzQqNlabBsmqk85o4jctOiVaoUywzpNPE1ZEEIfabsmOauyjIVijCs7WXUAiGk2m12RB9EbUsbYtaqKEkwfWH8LtykgTiLTWhx5gg-61Ixobb0J3Fp1UovY4-sth9HJ_t5w9xvPnh6fZZB6rlPEQayiAjqlOeCXHlcKUsUzKXGiVV5WArOI6gxyo1pz25XDIeVIhFwlgVlAs0mF0ub-3dfZ9gz6Ua7txTf9kmaQUgKVQJL262ivlrPcOq7J15k24rmS03JVezmA5-S192uOLPXZe_bvDp6Q_2PaAiw</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2309913972</pqid></control><display><type>article</type><title>Novel zinc-iodine hybrid supercapacitors with a redox iodide ion electrolyte and B, N dual-doped carbon electrode exhibit boosted energy density</title><source>Royal Society of Chemistry:Jisc Collections:Royal Society of Chemistry Read and Publish 2022-2024 (reading list)</source><creator>Han, Lu ; Huang, Hailong ; Li, Junfeng ; Yang, Zhongli ; Zhang, Xinlu ; Zhang, Dafeng ; Liu, Xinjuan ; Xu, Min ; Pan, Likun</creator><creatorcontrib>Han, Lu ; Huang, Hailong ; Li, Junfeng ; Yang, Zhongli ; Zhang, Xinlu ; Zhang, Dafeng ; Liu, Xinjuan ; Xu, Min ; Pan, Likun</creatorcontrib><description>With the development of modern society, energy storage has gradually become a crucial issue for portable devices and electric vehicles. Recently, zinc-ion hybrid supercapacitors (ZHSs), a new type of energy storage devices, have received significant attention mainly because zinc possesses many advantages such as natural abundance, low cost, non-toxicity and high safety. However, the limited energy density of the currently reported ZHSs should be further improved to achieve their large-scale applications. Herein, we designed novel zinc-iodine hybrid supercapacitors (Z-IHS) by introducing a redox iodide ion into the ZnSO
4
electrolyte to improve the energy density and employing B, N dual-doped porous carbon microtubes (BN-CMTs) as a cathode to facilitate the faradaic reaction on the electrode surface by changing the electronic structure and density state of carbon. The BN-CMT-based Z-IHS exhibits the amazingly high capacity of 416.6 mA h g
−1
, a high energy density (472.6 W h kg
−1
) at the power density of 1600 W kg
−1
in the voltage range of 0.2-1.8 V and excellent cycling stability with the capacity retention of 99.1% over 10 000 cycles at 10 A g
−1
. The strategy proposed in this study should provide a new insight into the exploration of high energy-density storage devices.
A novel high-energy-density zinc-iodine hybrid supercapacitor was designed
via
the introduction of a redox iodide ion electrolyte and B, N dual-doped carbon electrode.</description><identifier>ISSN: 2050-7488</identifier><identifier>EISSN: 2050-7496</identifier><identifier>DOI: 10.1039/c9ta07196b</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Carbon ; Density ; Electric vehicles ; Electrodes ; Electrolytes ; Electronic structure ; Energy ; Energy storage ; Flux density ; Hybrid vehicles ; Iodides ; Iodine ; Portable equipment ; Supercapacitors ; Toxicity ; Zinc ; Zinc sulfate</subject><ispartof>Journal of materials chemistry. A, Materials for energy and sustainability, 2019, Vol.7 (42), p.244-2447</ispartof><rights>Copyright Royal Society of Chemistry 2019</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c318t-d979040d28fb4fce3115bb6adc6ffa95f8d59690dd8010389682fe8a29e570e73</citedby><cites>FETCH-LOGICAL-c318t-d979040d28fb4fce3115bb6adc6ffa95f8d59690dd8010389682fe8a29e570e73</cites><orcidid>0000-0001-9294-1972 ; 0000-0003-0924-6720</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>315,786,790,4043,27956,27957,27958</link.rule.ids></links><search><creatorcontrib>Han, Lu</creatorcontrib><creatorcontrib>Huang, Hailong</creatorcontrib><creatorcontrib>Li, Junfeng</creatorcontrib><creatorcontrib>Yang, Zhongli</creatorcontrib><creatorcontrib>Zhang, Xinlu</creatorcontrib><creatorcontrib>Zhang, Dafeng</creatorcontrib><creatorcontrib>Liu, Xinjuan</creatorcontrib><creatorcontrib>Xu, Min</creatorcontrib><creatorcontrib>Pan, Likun</creatorcontrib><title>Novel zinc-iodine hybrid supercapacitors with a redox iodide ion electrolyte and B, N dual-doped carbon electrode exhibit boosted energy density</title><title>Journal of materials chemistry. A, Materials for energy and sustainability</title><description>With the development of modern society, energy storage has gradually become a crucial issue for portable devices and electric vehicles. Recently, zinc-ion hybrid supercapacitors (ZHSs), a new type of energy storage devices, have received significant attention mainly because zinc possesses many advantages such as natural abundance, low cost, non-toxicity and high safety. However, the limited energy density of the currently reported ZHSs should be further improved to achieve their large-scale applications. Herein, we designed novel zinc-iodine hybrid supercapacitors (Z-IHS) by introducing a redox iodide ion into the ZnSO
4
electrolyte to improve the energy density and employing B, N dual-doped porous carbon microtubes (BN-CMTs) as a cathode to facilitate the faradaic reaction on the electrode surface by changing the electronic structure and density state of carbon. The BN-CMT-based Z-IHS exhibits the amazingly high capacity of 416.6 mA h g
−1
, a high energy density (472.6 W h kg
−1
) at the power density of 1600 W kg
−1
in the voltage range of 0.2-1.8 V and excellent cycling stability with the capacity retention of 99.1% over 10 000 cycles at 10 A g
−1
. The strategy proposed in this study should provide a new insight into the exploration of high energy-density storage devices.
A novel high-energy-density zinc-iodine hybrid supercapacitor was designed
via
the introduction of a redox iodide ion electrolyte and B, N dual-doped carbon electrode.</description><subject>Carbon</subject><subject>Density</subject><subject>Electric vehicles</subject><subject>Electrodes</subject><subject>Electrolytes</subject><subject>Electronic structure</subject><subject>Energy</subject><subject>Energy storage</subject><subject>Flux density</subject><subject>Hybrid vehicles</subject><subject>Iodides</subject><subject>Iodine</subject><subject>Portable equipment</subject><subject>Supercapacitors</subject><subject>Toxicity</subject><subject>Zinc</subject><subject>Zinc sulfate</subject><issn>2050-7488</issn><issn>2050-7496</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNpF0btOwzAUBuAIgURVurAjWWJDBOykSXzGtuImVWUpc-TLCXUV4mC70PAUPDIpRfQs_xk-29LvKDpn9IbRFG4VBEELBrk8igYJzWhcjCE__t85P41G3q9pP5zSHGAQfS_sB9bkyzQqNlabBsmqk85o4jctOiVaoUywzpNPE1ZEEIfabsmOauyjIVijCs7WXUAiGk2m12RB9EbUsbYtaqKEkwfWH8LtykgTiLTWhx5gg-61Ixobb0J3Fp1UovY4-sth9HJ_t5w9xvPnh6fZZB6rlPEQayiAjqlOeCXHlcKUsUzKXGiVV5WArOI6gxyo1pz25XDIeVIhFwlgVlAs0mF0ub-3dfZ9gz6Ua7txTf9kmaQUgKVQJL262ivlrPcOq7J15k24rmS03JVezmA5-S192uOLPXZe_bvDp6Q_2PaAiw</recordid><startdate>2019</startdate><enddate>2019</enddate><creator>Han, Lu</creator><creator>Huang, Hailong</creator><creator>Li, Junfeng</creator><creator>Yang, Zhongli</creator><creator>Zhang, Xinlu</creator><creator>Zhang, Dafeng</creator><creator>Liu, Xinjuan</creator><creator>Xu, Min</creator><creator>Pan, Likun</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7SR</scope><scope>7ST</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>C1K</scope><scope>JG9</scope><scope>L7M</scope><scope>SOI</scope><orcidid>https://orcid.org/0000-0001-9294-1972</orcidid><orcidid>https://orcid.org/0000-0003-0924-6720</orcidid></search><sort><creationdate>2019</creationdate><title>Novel zinc-iodine hybrid supercapacitors with a redox iodide ion electrolyte and B, N dual-doped carbon electrode exhibit boosted energy density</title><author>Han, Lu ; Huang, Hailong ; Li, Junfeng ; Yang, Zhongli ; Zhang, Xinlu ; Zhang, Dafeng ; Liu, Xinjuan ; Xu, Min ; Pan, Likun</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c318t-d979040d28fb4fce3115bb6adc6ffa95f8d59690dd8010389682fe8a29e570e73</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Carbon</topic><topic>Density</topic><topic>Electric vehicles</topic><topic>Electrodes</topic><topic>Electrolytes</topic><topic>Electronic structure</topic><topic>Energy</topic><topic>Energy storage</topic><topic>Flux density</topic><topic>Hybrid vehicles</topic><topic>Iodides</topic><topic>Iodine</topic><topic>Portable equipment</topic><topic>Supercapacitors</topic><topic>Toxicity</topic><topic>Zinc</topic><topic>Zinc sulfate</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Han, Lu</creatorcontrib><creatorcontrib>Huang, Hailong</creatorcontrib><creatorcontrib>Li, Junfeng</creatorcontrib><creatorcontrib>Yang, Zhongli</creatorcontrib><creatorcontrib>Zhang, Xinlu</creatorcontrib><creatorcontrib>Zhang, Dafeng</creatorcontrib><creatorcontrib>Liu, Xinjuan</creatorcontrib><creatorcontrib>Xu, Min</creatorcontrib><creatorcontrib>Pan, Likun</creatorcontrib><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Environment Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Environment Abstracts</collection><jtitle>Journal of materials chemistry. A, Materials for energy and sustainability</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Han, Lu</au><au>Huang, Hailong</au><au>Li, Junfeng</au><au>Yang, Zhongli</au><au>Zhang, Xinlu</au><au>Zhang, Dafeng</au><au>Liu, Xinjuan</au><au>Xu, Min</au><au>Pan, Likun</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Novel zinc-iodine hybrid supercapacitors with a redox iodide ion electrolyte and B, N dual-doped carbon electrode exhibit boosted energy density</atitle><jtitle>Journal of materials chemistry. A, Materials for energy and sustainability</jtitle><date>2019</date><risdate>2019</risdate><volume>7</volume><issue>42</issue><spage>244</spage><epage>2447</epage><pages>244-2447</pages><issn>2050-7488</issn><eissn>2050-7496</eissn><notes>10.1039/c9ta07196b</notes><notes>Electronic supplementary information (ESI) available. See DOI</notes><abstract>With the development of modern society, energy storage has gradually become a crucial issue for portable devices and electric vehicles. Recently, zinc-ion hybrid supercapacitors (ZHSs), a new type of energy storage devices, have received significant attention mainly because zinc possesses many advantages such as natural abundance, low cost, non-toxicity and high safety. However, the limited energy density of the currently reported ZHSs should be further improved to achieve their large-scale applications. Herein, we designed novel zinc-iodine hybrid supercapacitors (Z-IHS) by introducing a redox iodide ion into the ZnSO
4
electrolyte to improve the energy density and employing B, N dual-doped porous carbon microtubes (BN-CMTs) as a cathode to facilitate the faradaic reaction on the electrode surface by changing the electronic structure and density state of carbon. The BN-CMT-based Z-IHS exhibits the amazingly high capacity of 416.6 mA h g
−1
, a high energy density (472.6 W h kg
−1
) at the power density of 1600 W kg
−1
in the voltage range of 0.2-1.8 V and excellent cycling stability with the capacity retention of 99.1% over 10 000 cycles at 10 A g
−1
. The strategy proposed in this study should provide a new insight into the exploration of high energy-density storage devices.
A novel high-energy-density zinc-iodine hybrid supercapacitor was designed
via
the introduction of a redox iodide ion electrolyte and B, N dual-doped carbon electrode.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/c9ta07196b</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0001-9294-1972</orcidid><orcidid>https://orcid.org/0000-0003-0924-6720</orcidid></addata></record> |
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| identifier | ISSN: 2050-7488 |
| ispartof | Journal of materials chemistry. A, Materials for energy and sustainability, 2019, Vol.7 (42), p.244-2447 |
| issn | 2050-7488 2050-7496 |
| language | eng |
| recordid | cdi_proquest_journals_2309913972 |
| source | Royal Society of Chemistry:Jisc Collections:Royal Society of Chemistry Read and Publish 2022-2024 (reading list) |
| subjects | Carbon Density Electric vehicles Electrodes Electrolytes Electronic structure Energy Energy storage Flux density Hybrid vehicles Iodides Iodine Portable equipment Supercapacitors Toxicity Zinc Zinc sulfate |
| title | Novel zinc-iodine hybrid supercapacitors with a redox iodide ion electrolyte and B, N dual-doped carbon electrode exhibit boosted energy density |
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