Loading…
IR calibrations for water determination in olivine, r-GeO2, and SiO2 polymorphs
Mineral-specific IR absorption coefficients were calculated for natural and synthetic olivine, SiO 2 polymorphs, and GeO 2 with specific isolated OH point defects using quantitative data from independent techniques such as proton–proton scattering, confocal Raman spectroscopy, and secondary ion mass...
Saved in:
| Published in: | Physics and chemistry of minerals 2009-10, Vol.36 (9), p.489-509 |
|---|---|
| Main Authors: | , , , , , , |
| Format: | Article |
| Language: | English |
| Subjects: | |
| Citations: | Items that this one cites Items that cite this one |
| Online Access: | Get full text |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| cited_by | cdi_FETCH-LOGICAL-c382t-bd3972c678cafaa869d9dcbdbfa8f28bc0a4cbf7f8844e8ddea536e41d14d8b93 |
|---|---|
| cites | cdi_FETCH-LOGICAL-c382t-bd3972c678cafaa869d9dcbdbfa8f28bc0a4cbf7f8844e8ddea536e41d14d8b93 |
| container_end_page | 509 |
| container_issue | 9 |
| container_start_page | 489 |
| container_title | Physics and chemistry of minerals |
| container_volume | 36 |
| creator | Thomas, Sylvia-Monique Koch-Müller, Monika Reichart, Patrick Rhede, Dieter Thomas, Rainer Wirth, Richard Matsyuk, Stanislav |
| description | Mineral-specific IR absorption coefficients were calculated for natural and synthetic olivine, SiO
2
polymorphs, and GeO
2
with specific isolated OH point defects using quantitative data from independent techniques such as proton–proton scattering, confocal Raman spectroscopy, and secondary ion mass spectrometry. Moreover, we present a routine to detect OH traces in anisotropic minerals using Raman spectroscopy combined with the “Comparator Technique”. In case of olivine and the SiO
2
system, it turns out that the magnitude of ε for one structure is independent of the type of OH point defect and therewith the peak position (quartz ε = 89,000 ± 15,000
), but it varies as a function of structure (coesite ε = 214,000 ± 14,000
; stishovite ε = 485,000 ± 109,000
). Evaluation of data from this study confirms that not using mineral-specific IR calibrations for the OH quantification in nominally anhydrous minerals leads to inaccurate estimations of OH concentrations, which constitute the basis for modeling the Earth’s deep water cycle. |
| doi_str_mv | 10.1007/s00269-009-0295-1 |
| format | article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2262079800</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2262079800</sourcerecordid><originalsourceid>FETCH-LOGICAL-c382t-bd3972c678cafaa869d9dcbdbfa8f28bc0a4cbf7f8844e8ddea536e41d14d8b93</originalsourceid><addsrcrecordid>eNp1kEtLAzEQx4MoWKsfwFvAa6OT7HY3OUrRWhAKPs4hm4embDdrslX67U1dwZOHmTn8HwM_hC4pXFOA-iYBsEoQgDxMzAk9QhNaFowwYPQYTaAoGaG1oKfoLKUNQBbr-QStV09Yq9Y3UQ0-dAm7EPGXGmzExua99d2PgH2HQ-s_fWdnOJKlXbMZVp3Bz37NcB_a_TbE_j2doxOn2mQvfu8Uvd7fvSweyON6uVrcPhJdcDaQxhSiZrqquVZOKV4JI4xuTOMUd4w3GlSpG1c7zsvScmOsmheVLamhpeGNKKboauztY_jY2TTITdjFLr-UjFUMasEBsouOLh1DStE62Ue_VXEvKcgDNzlyk5mbPHCTNGfYmEnZ273Z-Nf8f-gbQXpwdQ</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2262079800</pqid></control><display><type>article</type><title>IR calibrations for water determination in olivine, r-GeO2, and SiO2 polymorphs</title><source>Springer Link</source><creator>Thomas, Sylvia-Monique ; Koch-Müller, Monika ; Reichart, Patrick ; Rhede, Dieter ; Thomas, Rainer ; Wirth, Richard ; Matsyuk, Stanislav</creator><creatorcontrib>Thomas, Sylvia-Monique ; Koch-Müller, Monika ; Reichart, Patrick ; Rhede, Dieter ; Thomas, Rainer ; Wirth, Richard ; Matsyuk, Stanislav</creatorcontrib><description>Mineral-specific IR absorption coefficients were calculated for natural and synthetic olivine, SiO
2
polymorphs, and GeO
2
with specific isolated OH point defects using quantitative data from independent techniques such as proton–proton scattering, confocal Raman spectroscopy, and secondary ion mass spectrometry. Moreover, we present a routine to detect OH traces in anisotropic minerals using Raman spectroscopy combined with the “Comparator Technique”. In case of olivine and the SiO
2
system, it turns out that the magnitude of ε for one structure is independent of the type of OH point defect and therewith the peak position (quartz ε = 89,000 ± 15,000
), but it varies as a function of structure (coesite ε = 214,000 ± 14,000
; stishovite ε = 485,000 ± 109,000
). Evaluation of data from this study confirms that not using mineral-specific IR calibrations for the OH quantification in nominally anhydrous minerals leads to inaccurate estimations of OH concentrations, which constitute the basis for modeling the Earth’s deep water cycle.</description><identifier>ISSN: 0342-1791</identifier><identifier>EISSN: 1432-2021</identifier><identifier>DOI: 10.1007/s00269-009-0295-1</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer-Verlag</publisher><subject>Absorptivity ; Coesite ; Crystallography and Scattering Methods ; Deep water ; Earth and Environmental Science ; Earth Sciences ; Geochemistry ; Germanium oxides ; Hydrologic cycle ; Mass spectrometry ; Mineral Resources ; Mineralogy ; Minerals ; Olivine ; Original Paper ; Point defects ; Proton scattering ; Raman spectroscopy ; Secondary ion mass spectrometry ; Silicon dioxide ; Spectroscopy ; Stishovite</subject><ispartof>Physics and chemistry of minerals, 2009-10, Vol.36 (9), p.489-509</ispartof><rights>Springer-Verlag 2009</rights><rights>Physics and Chemistry of Minerals is a copyright of Springer, (2009). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c382t-bd3972c678cafaa869d9dcbdbfa8f28bc0a4cbf7f8844e8ddea536e41d14d8b93</citedby><cites>FETCH-LOGICAL-c382t-bd3972c678cafaa869d9dcbdbfa8f28bc0a4cbf7f8844e8ddea536e41d14d8b93</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>315,786,790,27957,27958</link.rule.ids></links><search><creatorcontrib>Thomas, Sylvia-Monique</creatorcontrib><creatorcontrib>Koch-Müller, Monika</creatorcontrib><creatorcontrib>Reichart, Patrick</creatorcontrib><creatorcontrib>Rhede, Dieter</creatorcontrib><creatorcontrib>Thomas, Rainer</creatorcontrib><creatorcontrib>Wirth, Richard</creatorcontrib><creatorcontrib>Matsyuk, Stanislav</creatorcontrib><title>IR calibrations for water determination in olivine, r-GeO2, and SiO2 polymorphs</title><title>Physics and chemistry of minerals</title><addtitle>Phys Chem Minerals</addtitle><description>Mineral-specific IR absorption coefficients were calculated for natural and synthetic olivine, SiO
2
polymorphs, and GeO
2
with specific isolated OH point defects using quantitative data from independent techniques such as proton–proton scattering, confocal Raman spectroscopy, and secondary ion mass spectrometry. Moreover, we present a routine to detect OH traces in anisotropic minerals using Raman spectroscopy combined with the “Comparator Technique”. In case of olivine and the SiO
2
system, it turns out that the magnitude of ε for one structure is independent of the type of OH point defect and therewith the peak position (quartz ε = 89,000 ± 15,000
), but it varies as a function of structure (coesite ε = 214,000 ± 14,000
; stishovite ε = 485,000 ± 109,000
). Evaluation of data from this study confirms that not using mineral-specific IR calibrations for the OH quantification in nominally anhydrous minerals leads to inaccurate estimations of OH concentrations, which constitute the basis for modeling the Earth’s deep water cycle.</description><subject>Absorptivity</subject><subject>Coesite</subject><subject>Crystallography and Scattering Methods</subject><subject>Deep water</subject><subject>Earth and Environmental Science</subject><subject>Earth Sciences</subject><subject>Geochemistry</subject><subject>Germanium oxides</subject><subject>Hydrologic cycle</subject><subject>Mass spectrometry</subject><subject>Mineral Resources</subject><subject>Mineralogy</subject><subject>Minerals</subject><subject>Olivine</subject><subject>Original Paper</subject><subject>Point defects</subject><subject>Proton scattering</subject><subject>Raman spectroscopy</subject><subject>Secondary ion mass spectrometry</subject><subject>Silicon dioxide</subject><subject>Spectroscopy</subject><subject>Stishovite</subject><issn>0342-1791</issn><issn>1432-2021</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><recordid>eNp1kEtLAzEQx4MoWKsfwFvAa6OT7HY3OUrRWhAKPs4hm4embDdrslX67U1dwZOHmTn8HwM_hC4pXFOA-iYBsEoQgDxMzAk9QhNaFowwYPQYTaAoGaG1oKfoLKUNQBbr-QStV09Yq9Y3UQ0-dAm7EPGXGmzExua99d2PgH2HQ-s_fWdnOJKlXbMZVp3Bz37NcB_a_TbE_j2doxOn2mQvfu8Uvd7fvSweyON6uVrcPhJdcDaQxhSiZrqquVZOKV4JI4xuTOMUd4w3GlSpG1c7zsvScmOsmheVLamhpeGNKKboauztY_jY2TTITdjFLr-UjFUMasEBsouOLh1DStE62Ue_VXEvKcgDNzlyk5mbPHCTNGfYmEnZ273Z-Nf8f-gbQXpwdQ</recordid><startdate>20091001</startdate><enddate>20091001</enddate><creator>Thomas, Sylvia-Monique</creator><creator>Koch-Müller, Monika</creator><creator>Reichart, Patrick</creator><creator>Rhede, Dieter</creator><creator>Thomas, Rainer</creator><creator>Wirth, Richard</creator><creator>Matsyuk, Stanislav</creator><general>Springer-Verlag</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>BHPHI</scope><scope>BKSAR</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PCBAR</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope></search><sort><creationdate>20091001</creationdate><title>IR calibrations for water determination in olivine, r-GeO2, and SiO2 polymorphs</title><author>Thomas, Sylvia-Monique ; Koch-Müller, Monika ; Reichart, Patrick ; Rhede, Dieter ; Thomas, Rainer ; Wirth, Richard ; Matsyuk, Stanislav</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c382t-bd3972c678cafaa869d9dcbdbfa8f28bc0a4cbf7f8844e8ddea536e41d14d8b93</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2009</creationdate><topic>Absorptivity</topic><topic>Coesite</topic><topic>Crystallography and Scattering Methods</topic><topic>Deep water</topic><topic>Earth and Environmental Science</topic><topic>Earth Sciences</topic><topic>Geochemistry</topic><topic>Germanium oxides</topic><topic>Hydrologic cycle</topic><topic>Mass spectrometry</topic><topic>Mineral Resources</topic><topic>Mineralogy</topic><topic>Minerals</topic><topic>Olivine</topic><topic>Original Paper</topic><topic>Point defects</topic><topic>Proton scattering</topic><topic>Raman spectroscopy</topic><topic>Secondary ion mass spectrometry</topic><topic>Silicon dioxide</topic><topic>Spectroscopy</topic><topic>Stishovite</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Thomas, Sylvia-Monique</creatorcontrib><creatorcontrib>Koch-Müller, Monika</creatorcontrib><creatorcontrib>Reichart, Patrick</creatorcontrib><creatorcontrib>Rhede, Dieter</creatorcontrib><creatorcontrib>Thomas, Rainer</creatorcontrib><creatorcontrib>Wirth, Richard</creatorcontrib><creatorcontrib>Matsyuk, Stanislav</creatorcontrib><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central</collection><collection>AUTh Library subscriptions: ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest Natural Science Collection</collection><collection>Earth, Atmospheric & Aquatic Science Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection (Proquest) (PQ_SDU_P3)</collection><collection>ProQuest Materials Science Database</collection><collection>ProQuest Earth, Atmospheric & Aquatic Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><jtitle>Physics and chemistry of minerals</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Thomas, Sylvia-Monique</au><au>Koch-Müller, Monika</au><au>Reichart, Patrick</au><au>Rhede, Dieter</au><au>Thomas, Rainer</au><au>Wirth, Richard</au><au>Matsyuk, Stanislav</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>IR calibrations for water determination in olivine, r-GeO2, and SiO2 polymorphs</atitle><jtitle>Physics and chemistry of minerals</jtitle><stitle>Phys Chem Minerals</stitle><date>2009-10-01</date><risdate>2009</risdate><volume>36</volume><issue>9</issue><spage>489</spage><epage>509</epage><pages>489-509</pages><issn>0342-1791</issn><eissn>1432-2021</eissn><abstract>Mineral-specific IR absorption coefficients were calculated for natural and synthetic olivine, SiO
2
polymorphs, and GeO
2
with specific isolated OH point defects using quantitative data from independent techniques such as proton–proton scattering, confocal Raman spectroscopy, and secondary ion mass spectrometry. Moreover, we present a routine to detect OH traces in anisotropic minerals using Raman spectroscopy combined with the “Comparator Technique”. In case of olivine and the SiO
2
system, it turns out that the magnitude of ε for one structure is independent of the type of OH point defect and therewith the peak position (quartz ε = 89,000 ± 15,000
), but it varies as a function of structure (coesite ε = 214,000 ± 14,000
; stishovite ε = 485,000 ± 109,000
). Evaluation of data from this study confirms that not using mineral-specific IR calibrations for the OH quantification in nominally anhydrous minerals leads to inaccurate estimations of OH concentrations, which constitute the basis for modeling the Earth’s deep water cycle.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer-Verlag</pub><doi>10.1007/s00269-009-0295-1</doi><tpages>21</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0342-1791 |
| ispartof | Physics and chemistry of minerals, 2009-10, Vol.36 (9), p.489-509 |
| issn | 0342-1791 1432-2021 |
| language | eng |
| recordid | cdi_proquest_journals_2262079800 |
| source | Springer Link |
| subjects | Absorptivity Coesite Crystallography and Scattering Methods Deep water Earth and Environmental Science Earth Sciences Geochemistry Germanium oxides Hydrologic cycle Mass spectrometry Mineral Resources Mineralogy Minerals Olivine Original Paper Point defects Proton scattering Raman spectroscopy Secondary ion mass spectrometry Silicon dioxide Spectroscopy Stishovite |
| title | IR calibrations for water determination in olivine, r-GeO2, and SiO2 polymorphs |
| url | http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-09-23T06%3A32%3A16IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=IR%20calibrations%20for%20water%20determination%20in%20olivine,%20r-GeO2,%20and%20SiO2%20polymorphs&rft.jtitle=Physics%20and%20chemistry%20of%20minerals&rft.au=Thomas,%20Sylvia-Monique&rft.date=2009-10-01&rft.volume=36&rft.issue=9&rft.spage=489&rft.epage=509&rft.pages=489-509&rft.issn=0342-1791&rft.eissn=1432-2021&rft_id=info:doi/10.1007/s00269-009-0295-1&rft_dat=%3Cproquest_cross%3E2262079800%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c382t-bd3972c678cafaa869d9dcbdbfa8f28bc0a4cbf7f8844e8ddea536e41d14d8b93%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=2262079800&rft_id=info:pmid/&rfr_iscdi=true |