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Sorption of Copper and Zinc from Aqueous Solution by Metabasalt Residue and its Mineralogical Behavior
Residues from mining, as metabasalt powder from amethyst exploration, can be used to improve soil properties. Although there is a high-load content of clay minerals in metabasalt, the effects of this residue on cooper (Cu 2+ ) and zinc (Zn 2+ ) sorption and desorption have not been studied. The aim...
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| Published in: | Water, air, and soil pollution air, and soil pollution, 2019-04, Vol.230 (4), p.1-18, Article 90 |
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| container_title | Water, air, and soil pollution |
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| creator | Dalacorte, Luana Escosteguy, Pedro Alexandre Varella Bortoluzzi, Edson Campanhola |
| description | Residues from mining, as metabasalt powder from amethyst exploration, can be used to improve soil properties. Although there is a high-load content of clay minerals in metabasalt, the effects of this residue on cooper (Cu
2+
) and zinc (Zn
2+
) sorption and desorption have not been studied. The aim of this work was to evaluate Cu
2+
and Zn
2+
sorption capacity of metabasalt powder and to discuss the mineralogical behavior facing this phenomenon. This residue sorption capacity was compared to reference clay minerals under two Cu
2+
and Zn
2+
concentrations (8 and 16 cmol
c
/kg) in a competitive system (Cu
2+
+ Zn
2+
). The sorption capacity was estimated by sequential desorption using cation exchange resin. A survey of mineralogical and Cu
2+
and Zn
2+
concentrations was performed on metabasalt before and after sorption, and after desorption tests. All materials sorbed higher amounts of Cu
2+
than Zn
2+
. The sorption magnitude decreased in the following order: metabasalt > montmorillonite > illite > kaolinite. Cu
2+
and Zn
2+
desorption from metabasalt is lower than the standard clay minerals, since the metabasalt sorption sites are expandable interlayers of clay minerals. The relevance and application of our findings are critical in providing information for the management of metabasalt residue, suggesting potential use as a remediation agent in contaminated water, especially those with high Cu
2+
and Zn
2+
loading. It also suggests that the Cu
2+
and Zn
2+
enrichment of this residue could potentially be used for converting the metabasalt into a useful source of slow nutrient supply for agricultural soils. |
| doi_str_mv | 10.1007/s11270-019-4141-x |
| format | article |
| fullrecord | <record><control><sourceid>gale_proqu</sourceid><recordid>TN_cdi_proquest_journals_2200125537</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><galeid>A580713679</galeid><sourcerecordid>A580713679</sourcerecordid><originalsourceid>FETCH-LOGICAL-c355t-5694e24e0eb3e989e554deae9efb8f4145a7b4562f5464e9dadded89ebac56303</originalsourceid><addsrcrecordid>eNp1kE1PxCAQhonRxPXjB3gj8dwVKJTluG78SnZj4urFC6HtsGK6pUJr1n8va008CQeSyfMwMy9CF5RMKSHyKlLKJMkIVRmnnGa7AzShQuYZUzk7RBNCuMoKJdUxOonxnaSjZnKC7NqHrne-xd7ihe86CNi0NX51bYVt8Fs8_xjADxGvfTP8gOUXXkFvShNN0-MniK4e4EdyfcQr10Iwjd-4yjT4Gt7Mp_PhDB1Z00Q4_31P0cvtzfPiPls-3j0s5susyoXoM1EoDowDgTIHNVMgBK_BgAJbzmxaTBhZclEwK3jBQdWmrqFOXGkqUeQkP0WX479d8Gnu2Ot3P4Q2tdSMEUKZELlM1HSkNqYB7Vrr-2CqdGvYusq3YF2qz8WMSJoXUiWBjkIVfIwBrO6C25rwpSnR-_z1mL9O-et9_nqXHDY6MbHtBsLfKP9L36SXiYg</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2200125537</pqid></control><display><type>article</type><title>Sorption of Copper and Zinc from Aqueous Solution by Metabasalt Residue and its Mineralogical Behavior</title><source>ABI/INFORM Global</source><source>Springer Link</source><creator>Dalacorte, Luana ; Escosteguy, Pedro Alexandre Varella ; Bortoluzzi, Edson Campanhola</creator><creatorcontrib>Dalacorte, Luana ; Escosteguy, Pedro Alexandre Varella ; Bortoluzzi, Edson Campanhola</creatorcontrib><description>Residues from mining, as metabasalt powder from amethyst exploration, can be used to improve soil properties. Although there is a high-load content of clay minerals in metabasalt, the effects of this residue on cooper (Cu
2+
) and zinc (Zn
2+
) sorption and desorption have not been studied. The aim of this work was to evaluate Cu
2+
and Zn
2+
sorption capacity of metabasalt powder and to discuss the mineralogical behavior facing this phenomenon. This residue sorption capacity was compared to reference clay minerals under two Cu
2+
and Zn
2+
concentrations (8 and 16 cmol
c
/kg) in a competitive system (Cu
2+
+ Zn
2+
). The sorption capacity was estimated by sequential desorption using cation exchange resin. A survey of mineralogical and Cu
2+
and Zn
2+
concentrations was performed on metabasalt before and after sorption, and after desorption tests. All materials sorbed higher amounts of Cu
2+
than Zn
2+
. The sorption magnitude decreased in the following order: metabasalt > montmorillonite > illite > kaolinite. Cu
2+
and Zn
2+
desorption from metabasalt is lower than the standard clay minerals, since the metabasalt sorption sites are expandable interlayers of clay minerals. The relevance and application of our findings are critical in providing information for the management of metabasalt residue, suggesting potential use as a remediation agent in contaminated water, especially those with high Cu
2+
and Zn
2+
loading. It also suggests that the Cu
2+
and Zn
2+
enrichment of this residue could potentially be used for converting the metabasalt into a useful source of slow nutrient supply for agricultural soils.</description><identifier>ISSN: 0049-6979</identifier><identifier>EISSN: 1573-2932</identifier><identifier>DOI: 10.1007/s11270-019-4141-x</identifier><language>eng</language><publisher>Cham: Springer International Publishing</publisher><subject>Agricultural land ; Agricultural management ; Aqueous solutions ; Atmospheric Protection/Air Quality Control/Air Pollution ; Cation exchange ; Cation exchanging ; Cations ; Clay ; Clay minerals ; Climate Change/Climate Change Impacts ; Copper ; Desorption ; Earth and Environmental Science ; Environment ; Environmental monitoring ; Exploration ; Hydrogeology ; Illite ; Illites ; Information management ; Interlayers ; Kaolinite ; Mineral exploration ; Mineral nutrients ; Mineralogy ; Minerals ; Mining ; Montmorillonite ; Montmorillonites ; Nutrient cycles ; Powder ; Powders (Particulate matter) ; Soil ; Soil contamination ; Soil improvement ; Soil properties ; Soil Science & Conservation ; Soils ; Sorption ; Surveying ; Water pollution ; Water Quality/Water Pollution ; Work capacity ; Zinc ; Zinc compounds</subject><ispartof>Water, air, and soil pollution, 2019-04, Vol.230 (4), p.1-18, Article 90</ispartof><rights>Springer Nature Switzerland AG 2019</rights><rights>COPYRIGHT 2019 Springer</rights><rights>Water, Air, & Soil Pollution is a copyright of Springer, (2019). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c355t-5694e24e0eb3e989e554deae9efb8f4145a7b4562f5464e9dadded89ebac56303</citedby><cites>FETCH-LOGICAL-c355t-5694e24e0eb3e989e554deae9efb8f4145a7b4562f5464e9dadded89ebac56303</cites><orcidid>0000-0002-4503-7283</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.proquest.com/docview/2200125537/fulltextPDF?pq-origsite=primo$$EPDF$$P50$$Gproquest$$H</linktopdf><linktohtml>$$Uhttps://www.proquest.com/docview/2200125537?pq-origsite=primo$$EHTML$$P50$$Gproquest$$H</linktohtml><link.rule.ids>315,786,790,11715,27957,27958,36095,44398,75252</link.rule.ids></links><search><creatorcontrib>Dalacorte, Luana</creatorcontrib><creatorcontrib>Escosteguy, Pedro Alexandre Varella</creatorcontrib><creatorcontrib>Bortoluzzi, Edson Campanhola</creatorcontrib><title>Sorption of Copper and Zinc from Aqueous Solution by Metabasalt Residue and its Mineralogical Behavior</title><title>Water, air, and soil pollution</title><addtitle>Water Air Soil Pollut</addtitle><description>Residues from mining, as metabasalt powder from amethyst exploration, can be used to improve soil properties. Although there is a high-load content of clay minerals in metabasalt, the effects of this residue on cooper (Cu
2+
) and zinc (Zn
2+
) sorption and desorption have not been studied. The aim of this work was to evaluate Cu
2+
and Zn
2+
sorption capacity of metabasalt powder and to discuss the mineralogical behavior facing this phenomenon. This residue sorption capacity was compared to reference clay minerals under two Cu
2+
and Zn
2+
concentrations (8 and 16 cmol
c
/kg) in a competitive system (Cu
2+
+ Zn
2+
). The sorption capacity was estimated by sequential desorption using cation exchange resin. A survey of mineralogical and Cu
2+
and Zn
2+
concentrations was performed on metabasalt before and after sorption, and after desorption tests. All materials sorbed higher amounts of Cu
2+
than Zn
2+
. The sorption magnitude decreased in the following order: metabasalt > montmorillonite > illite > kaolinite. Cu
2+
and Zn
2+
desorption from metabasalt is lower than the standard clay minerals, since the metabasalt sorption sites are expandable interlayers of clay minerals. The relevance and application of our findings are critical in providing information for the management of metabasalt residue, suggesting potential use as a remediation agent in contaminated water, especially those with high Cu
2+
and Zn
2+
loading. It also suggests that the Cu
2+
and Zn
2+
enrichment of this residue could potentially be used for converting the metabasalt into a useful source of slow nutrient supply for agricultural soils.</description><subject>Agricultural land</subject><subject>Agricultural management</subject><subject>Aqueous solutions</subject><subject>Atmospheric Protection/Air Quality Control/Air Pollution</subject><subject>Cation exchange</subject><subject>Cation exchanging</subject><subject>Cations</subject><subject>Clay</subject><subject>Clay minerals</subject><subject>Climate Change/Climate Change Impacts</subject><subject>Copper</subject><subject>Desorption</subject><subject>Earth and Environmental Science</subject><subject>Environment</subject><subject>Environmental monitoring</subject><subject>Exploration</subject><subject>Hydrogeology</subject><subject>Illite</subject><subject>Illites</subject><subject>Information management</subject><subject>Interlayers</subject><subject>Kaolinite</subject><subject>Mineral exploration</subject><subject>Mineral nutrients</subject><subject>Mineralogy</subject><subject>Minerals</subject><subject>Mining</subject><subject>Montmorillonite</subject><subject>Montmorillonites</subject><subject>Nutrient cycles</subject><subject>Powder</subject><subject>Powders (Particulate matter)</subject><subject>Soil</subject><subject>Soil contamination</subject><subject>Soil improvement</subject><subject>Soil properties</subject><subject>Soil Science & Conservation</subject><subject>Soils</subject><subject>Sorption</subject><subject>Surveying</subject><subject>Water pollution</subject><subject>Water Quality/Water Pollution</subject><subject>Work capacity</subject><subject>Zinc</subject><subject>Zinc compounds</subject><issn>0049-6979</issn><issn>1573-2932</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><sourceid>M0C</sourceid><recordid>eNp1kE1PxCAQhonRxPXjB3gj8dwVKJTluG78SnZj4urFC6HtsGK6pUJr1n8va008CQeSyfMwMy9CF5RMKSHyKlLKJMkIVRmnnGa7AzShQuYZUzk7RBNCuMoKJdUxOonxnaSjZnKC7NqHrne-xd7ihe86CNi0NX51bYVt8Fs8_xjADxGvfTP8gOUXXkFvShNN0-MniK4e4EdyfcQr10Iwjd-4yjT4Gt7Mp_PhDB1Z00Q4_31P0cvtzfPiPls-3j0s5susyoXoM1EoDowDgTIHNVMgBK_BgAJbzmxaTBhZclEwK3jBQdWmrqFOXGkqUeQkP0WX479d8Gnu2Ot3P4Q2tdSMEUKZELlM1HSkNqYB7Vrr-2CqdGvYusq3YF2qz8WMSJoXUiWBjkIVfIwBrO6C25rwpSnR-_z1mL9O-et9_nqXHDY6MbHtBsLfKP9L36SXiYg</recordid><startdate>20190401</startdate><enddate>20190401</enddate><creator>Dalacorte, Luana</creator><creator>Escosteguy, Pedro Alexandre Varella</creator><creator>Bortoluzzi, Edson Campanhola</creator><general>Springer International Publishing</general><general>Springer</general><general>Springer Nature 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of Copper and Zinc from Aqueous Solution by Metabasalt Residue and its Mineralogical Behavior</title><author>Dalacorte, Luana ; Escosteguy, Pedro Alexandre Varella ; Bortoluzzi, Edson Campanhola</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c355t-5694e24e0eb3e989e554deae9efb8f4145a7b4562f5464e9dadded89ebac56303</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Agricultural land</topic><topic>Agricultural management</topic><topic>Aqueous solutions</topic><topic>Atmospheric Protection/Air Quality Control/Air Pollution</topic><topic>Cation exchange</topic><topic>Cation exchanging</topic><topic>Cations</topic><topic>Clay</topic><topic>Clay minerals</topic><topic>Climate Change/Climate Change Impacts</topic><topic>Copper</topic><topic>Desorption</topic><topic>Earth and Environmental Science</topic><topic>Environment</topic><topic>Environmental 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pollution</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Dalacorte, Luana</au><au>Escosteguy, Pedro Alexandre Varella</au><au>Bortoluzzi, Edson Campanhola</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Sorption of Copper and Zinc from Aqueous Solution by Metabasalt Residue and its Mineralogical Behavior</atitle><jtitle>Water, air, and soil pollution</jtitle><stitle>Water Air Soil Pollut</stitle><date>2019-04-01</date><risdate>2019</risdate><volume>230</volume><issue>4</issue><spage>1</spage><epage>18</epage><pages>1-18</pages><artnum>90</artnum><issn>0049-6979</issn><eissn>1573-2932</eissn><abstract>Residues from mining, as metabasalt powder from amethyst exploration, can be used to improve soil properties. Although there is a high-load content of clay minerals in metabasalt, the effects of this residue on cooper (Cu
2+
) and zinc (Zn
2+
) sorption and desorption have not been studied. The aim of this work was to evaluate Cu
2+
and Zn
2+
sorption capacity of metabasalt powder and to discuss the mineralogical behavior facing this phenomenon. This residue sorption capacity was compared to reference clay minerals under two Cu
2+
and Zn
2+
concentrations (8 and 16 cmol
c
/kg) in a competitive system (Cu
2+
+ Zn
2+
). The sorption capacity was estimated by sequential desorption using cation exchange resin. A survey of mineralogical and Cu
2+
and Zn
2+
concentrations was performed on metabasalt before and after sorption, and after desorption tests. All materials sorbed higher amounts of Cu
2+
than Zn
2+
. The sorption magnitude decreased in the following order: metabasalt > montmorillonite > illite > kaolinite. Cu
2+
and Zn
2+
desorption from metabasalt is lower than the standard clay minerals, since the metabasalt sorption sites are expandable interlayers of clay minerals. The relevance and application of our findings are critical in providing information for the management of metabasalt residue, suggesting potential use as a remediation agent in contaminated water, especially those with high Cu
2+
and Zn
2+
loading. It also suggests that the Cu
2+
and Zn
2+
enrichment of this residue could potentially be used for converting the metabasalt into a useful source of slow nutrient supply for agricultural soils.</abstract><cop>Cham</cop><pub>Springer International Publishing</pub><doi>10.1007/s11270-019-4141-x</doi><tpages>18</tpages><orcidid>https://orcid.org/0000-0002-4503-7283</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0049-6979 |
| ispartof | Water, air, and soil pollution, 2019-04, Vol.230 (4), p.1-18, Article 90 |
| issn | 0049-6979 1573-2932 |
| language | eng |
| recordid | cdi_proquest_journals_2200125537 |
| source | ABI/INFORM Global; Springer Link |
| subjects | Agricultural land Agricultural management Aqueous solutions Atmospheric Protection/Air Quality Control/Air Pollution Cation exchange Cation exchanging Cations Clay Clay minerals Climate Change/Climate Change Impacts Copper Desorption Earth and Environmental Science Environment Environmental monitoring Exploration Hydrogeology Illite Illites Information management Interlayers Kaolinite Mineral exploration Mineral nutrients Mineralogy Minerals Mining Montmorillonite Montmorillonites Nutrient cycles Powder Powders (Particulate matter) Soil Soil contamination Soil improvement Soil properties Soil Science & Conservation Soils Sorption Surveying Water pollution Water Quality/Water Pollution Work capacity Zinc Zinc compounds |
| title | Sorption of Copper and Zinc from Aqueous Solution by Metabasalt Residue and its Mineralogical Behavior |
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