Loading…
Binuclear and Hexanuclear Ti(IV) Complexes Supported by [OOOO]4–-type Ligand for Preparing Disentangled UHMWPE
Binuclear and hexanuclear titanium complexes stabilized by tetradentate [OOOO] 4– -type ligand were active in ethylene polymerization in the presence of Et 2 AlCl/Bu 2 Mg binary co-catalyst, giving high molecular weight polyethylene. The binuclear complex showed significantly higher catalytic activi...
Saved in:
| Published in: | Chinese journal of polymer science 2019, Vol.37 (5), p.471-477 |
|---|---|
| Main Authors: | , , , , , , , , , , , |
| Format: | Article |
| Language: | English |
| Subjects: | |
| Citations: | Items that this one cites Items that cite this one |
| Online Access: | Get full text |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| cited_by | cdi_FETCH-LOGICAL-c2040-8c3e2699bb8f18b397c9db6d87b9f5297ee60672fd315d8cea6c6427a4fdd173 |
|---|---|
| cites | cdi_FETCH-LOGICAL-c2040-8c3e2699bb8f18b397c9db6d87b9f5297ee60672fd315d8cea6c6427a4fdd173 |
| container_end_page | 477 |
| container_issue | 5 |
| container_start_page | 471 |
| container_title | Chinese journal of polymer science |
| container_volume | 37 |
| creator | Tuskaev, Vladislav A. Gagieva, Svetlana Ch Kurmaev, Dmitry A. Vasil’ev, Viktor G. Kolosov, Nikolay A. Zubkevich, Sergey V. Mikhaylik, Elena S. Golubev, Evgenii K. Nikiforova, Galina G. Zhizhko, Pavel A. Serenko, Olga A. Bulychev, Boris M. |
| description | Binuclear and hexanuclear titanium complexes stabilized by tetradentate [OOOO]
4–
-type ligand were active in ethylene polymerization in the presence of Et
2
AlCl/Bu
2
Mg binary co-catalyst, giving high molecular weight polyethylene. The binuclear complex showed significantly higher catalytic activity and thermal stability in comparison to mononuclear analogue. Ultra high molecular weight polyethylene (UHMWPE) samples were processed by a solid-state uniaxial deformation into high-strength (up to 2.5 GPa) and highmodulus (over 100 GPa) oriented film tapes, which indirectly indicates a low degree of entanglements between the macromolecular chains. |
| doi_str_mv | 10.1007/s10118-019-2197-0 |
| format | article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2194643477</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2194643477</sourcerecordid><originalsourceid>FETCH-LOGICAL-c2040-8c3e2699bb8f18b397c9db6d87b9f5297ee60672fd315d8cea6c6427a4fdd173</originalsourceid><addsrcrecordid>eNp1kEFLwzAUx4MoOKcfwFvAix6iSZomzVHndIPJBk49iJS0SUdH18akhe3md_Ab-klsqeLJd3k8eL__4_0AOCX4kmAsrjzBhEQIE4kokQLhPTAgLJCIUxzsgwGmIUeCC3kIjrxfY8yZCMUA2Ju8bNLCKAdVqeHEbNXvvMzPp88XcFRtbGG2xsPHxtrK1UbDZAdf5229sa-PT1TvrIGzfNUFZJWDC2escnm5gre5N2WtylXRQk-Th5fF-BgcZKrw5uSnD8HybrwcTdBsfj8dXc9QSjHDKEoDQ7mUSRJlJEoCKVKpE64jkcgspFIYwzEXNNMBCXWUGsVTzqhQLNOaiGAIzvpY66r3xvg6XleNK9uLceuHcRYw0W2Rfit1lffOZLF1-Ua5XUxw3HmNe69x67XjRIxbhvaMt92Pxv0l_w99A8UTewg</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2194643477</pqid></control><display><type>article</type><title>Binuclear and Hexanuclear Ti(IV) Complexes Supported by [OOOO]4–-type Ligand for Preparing Disentangled UHMWPE</title><source>Springer Link</source><creator>Tuskaev, Vladislav A. ; Gagieva, Svetlana Ch ; Kurmaev, Dmitry A. ; Vasil’ev, Viktor G. ; Kolosov, Nikolay A. ; Zubkevich, Sergey V. ; Mikhaylik, Elena S. ; Golubev, Evgenii K. ; Nikiforova, Galina G. ; Zhizhko, Pavel A. ; Serenko, Olga A. ; Bulychev, Boris M.</creator><creatorcontrib>Tuskaev, Vladislav A. ; Gagieva, Svetlana Ch ; Kurmaev, Dmitry A. ; Vasil’ev, Viktor G. ; Kolosov, Nikolay A. ; Zubkevich, Sergey V. ; Mikhaylik, Elena S. ; Golubev, Evgenii K. ; Nikiforova, Galina G. ; Zhizhko, Pavel A. ; Serenko, Olga A. ; Bulychev, Boris M.</creatorcontrib><description>Binuclear and hexanuclear titanium complexes stabilized by tetradentate [OOOO]
4–
-type ligand were active in ethylene polymerization in the presence of Et
2
AlCl/Bu
2
Mg binary co-catalyst, giving high molecular weight polyethylene. The binuclear complex showed significantly higher catalytic activity and thermal stability in comparison to mononuclear analogue. Ultra high molecular weight polyethylene (UHMWPE) samples were processed by a solid-state uniaxial deformation into high-strength (up to 2.5 GPa) and highmodulus (over 100 GPa) oriented film tapes, which indirectly indicates a low degree of entanglements between the macromolecular chains.</description><identifier>ISSN: 0256-7679</identifier><identifier>EISSN: 1439-6203</identifier><identifier>DOI: 10.1007/s10118-019-2197-0</identifier><language>eng</language><publisher>Beijing: Chinese Chemical Society and Institute of Chemistry, CAS</publisher><subject>Catalysis ; Catalytic activity ; Chain entanglement ; Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Condensed Matter Physics ; Deformation ; Industrial Chemistry/Chemical Engineering ; Ligands ; Molecular chains ; Molecular weight ; Polyethylene ; Polymer Sciences ; Thermal stability ; Titanium ; Ultra high molecular weight polyethylene</subject><ispartof>Chinese journal of polymer science, 2019, Vol.37 (5), p.471-477</ispartof><rights>Chinese Chemical Society, Institute of Chemistry, Chinese Academy of Sciences, Springer-Verlag GmbH Germany, part of Springer Nature 2018</rights><rights>Copyright Springer Nature B.V. 2019</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c2040-8c3e2699bb8f18b397c9db6d87b9f5297ee60672fd315d8cea6c6427a4fdd173</citedby><cites>FETCH-LOGICAL-c2040-8c3e2699bb8f18b397c9db6d87b9f5297ee60672fd315d8cea6c6427a4fdd173</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>315,786,790,27957,27958</link.rule.ids></links><search><creatorcontrib>Tuskaev, Vladislav A.</creatorcontrib><creatorcontrib>Gagieva, Svetlana Ch</creatorcontrib><creatorcontrib>Kurmaev, Dmitry A.</creatorcontrib><creatorcontrib>Vasil’ev, Viktor G.</creatorcontrib><creatorcontrib>Kolosov, Nikolay A.</creatorcontrib><creatorcontrib>Zubkevich, Sergey V.</creatorcontrib><creatorcontrib>Mikhaylik, Elena S.</creatorcontrib><creatorcontrib>Golubev, Evgenii K.</creatorcontrib><creatorcontrib>Nikiforova, Galina G.</creatorcontrib><creatorcontrib>Zhizhko, Pavel A.</creatorcontrib><creatorcontrib>Serenko, Olga A.</creatorcontrib><creatorcontrib>Bulychev, Boris M.</creatorcontrib><title>Binuclear and Hexanuclear Ti(IV) Complexes Supported by [OOOO]4–-type Ligand for Preparing Disentangled UHMWPE</title><title>Chinese journal of polymer science</title><addtitle>Chin J Polym Sci</addtitle><description>Binuclear and hexanuclear titanium complexes stabilized by tetradentate [OOOO]
4–
-type ligand were active in ethylene polymerization in the presence of Et
2
AlCl/Bu
2
Mg binary co-catalyst, giving high molecular weight polyethylene. The binuclear complex showed significantly higher catalytic activity and thermal stability in comparison to mononuclear analogue. Ultra high molecular weight polyethylene (UHMWPE) samples were processed by a solid-state uniaxial deformation into high-strength (up to 2.5 GPa) and highmodulus (over 100 GPa) oriented film tapes, which indirectly indicates a low degree of entanglements between the macromolecular chains.</description><subject>Catalysis</subject><subject>Catalytic activity</subject><subject>Chain entanglement</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Condensed Matter Physics</subject><subject>Deformation</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Ligands</subject><subject>Molecular chains</subject><subject>Molecular weight</subject><subject>Polyethylene</subject><subject>Polymer Sciences</subject><subject>Thermal stability</subject><subject>Titanium</subject><subject>Ultra high molecular weight polyethylene</subject><issn>0256-7679</issn><issn>1439-6203</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp1kEFLwzAUx4MoOKcfwFvAix6iSZomzVHndIPJBk49iJS0SUdH18akhe3md_Ab-klsqeLJd3k8eL__4_0AOCX4kmAsrjzBhEQIE4kokQLhPTAgLJCIUxzsgwGmIUeCC3kIjrxfY8yZCMUA2Ju8bNLCKAdVqeHEbNXvvMzPp88XcFRtbGG2xsPHxtrK1UbDZAdf5229sa-PT1TvrIGzfNUFZJWDC2escnm5gre5N2WtylXRQk-Th5fF-BgcZKrw5uSnD8HybrwcTdBsfj8dXc9QSjHDKEoDQ7mUSRJlJEoCKVKpE64jkcgspFIYwzEXNNMBCXWUGsVTzqhQLNOaiGAIzvpY66r3xvg6XleNK9uLceuHcRYw0W2Rfit1lffOZLF1-Ua5XUxw3HmNe69x67XjRIxbhvaMt92Pxv0l_w99A8UTewg</recordid><startdate>2019</startdate><enddate>2019</enddate><creator>Tuskaev, Vladislav A.</creator><creator>Gagieva, Svetlana Ch</creator><creator>Kurmaev, Dmitry A.</creator><creator>Vasil’ev, Viktor G.</creator><creator>Kolosov, Nikolay A.</creator><creator>Zubkevich, Sergey V.</creator><creator>Mikhaylik, Elena S.</creator><creator>Golubev, Evgenii K.</creator><creator>Nikiforova, Galina G.</creator><creator>Zhizhko, Pavel A.</creator><creator>Serenko, Olga A.</creator><creator>Bulychev, Boris M.</creator><general>Chinese Chemical Society and Institute of Chemistry, CAS</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>2019</creationdate><title>Binuclear and Hexanuclear Ti(IV) Complexes Supported by [OOOO]4–-type Ligand for Preparing Disentangled UHMWPE</title><author>Tuskaev, Vladislav A. ; Gagieva, Svetlana Ch ; Kurmaev, Dmitry A. ; Vasil’ev, Viktor G. ; Kolosov, Nikolay A. ; Zubkevich, Sergey V. ; Mikhaylik, Elena S. ; Golubev, Evgenii K. ; Nikiforova, Galina G. ; Zhizhko, Pavel A. ; Serenko, Olga A. ; Bulychev, Boris M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2040-8c3e2699bb8f18b397c9db6d87b9f5297ee60672fd315d8cea6c6427a4fdd173</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Catalysis</topic><topic>Catalytic activity</topic><topic>Chain entanglement</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Condensed Matter Physics</topic><topic>Deformation</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Ligands</topic><topic>Molecular chains</topic><topic>Molecular weight</topic><topic>Polyethylene</topic><topic>Polymer Sciences</topic><topic>Thermal stability</topic><topic>Titanium</topic><topic>Ultra high molecular weight polyethylene</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Tuskaev, Vladislav A.</creatorcontrib><creatorcontrib>Gagieva, Svetlana Ch</creatorcontrib><creatorcontrib>Kurmaev, Dmitry A.</creatorcontrib><creatorcontrib>Vasil’ev, Viktor G.</creatorcontrib><creatorcontrib>Kolosov, Nikolay A.</creatorcontrib><creatorcontrib>Zubkevich, Sergey V.</creatorcontrib><creatorcontrib>Mikhaylik, Elena S.</creatorcontrib><creatorcontrib>Golubev, Evgenii K.</creatorcontrib><creatorcontrib>Nikiforova, Galina G.</creatorcontrib><creatorcontrib>Zhizhko, Pavel A.</creatorcontrib><creatorcontrib>Serenko, Olga A.</creatorcontrib><creatorcontrib>Bulychev, Boris M.</creatorcontrib><collection>CrossRef</collection><jtitle>Chinese journal of polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Tuskaev, Vladislav A.</au><au>Gagieva, Svetlana Ch</au><au>Kurmaev, Dmitry A.</au><au>Vasil’ev, Viktor G.</au><au>Kolosov, Nikolay A.</au><au>Zubkevich, Sergey V.</au><au>Mikhaylik, Elena S.</au><au>Golubev, Evgenii K.</au><au>Nikiforova, Galina G.</au><au>Zhizhko, Pavel A.</au><au>Serenko, Olga A.</au><au>Bulychev, Boris M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Binuclear and Hexanuclear Ti(IV) Complexes Supported by [OOOO]4–-type Ligand for Preparing Disentangled UHMWPE</atitle><jtitle>Chinese journal of polymer science</jtitle><stitle>Chin J Polym Sci</stitle><date>2019</date><risdate>2019</risdate><volume>37</volume><issue>5</issue><spage>471</spage><epage>477</epage><pages>471-477</pages><issn>0256-7679</issn><eissn>1439-6203</eissn><abstract>Binuclear and hexanuclear titanium complexes stabilized by tetradentate [OOOO]
4–
-type ligand were active in ethylene polymerization in the presence of Et
2
AlCl/Bu
2
Mg binary co-catalyst, giving high molecular weight polyethylene. The binuclear complex showed significantly higher catalytic activity and thermal stability in comparison to mononuclear analogue. Ultra high molecular weight polyethylene (UHMWPE) samples were processed by a solid-state uniaxial deformation into high-strength (up to 2.5 GPa) and highmodulus (over 100 GPa) oriented film tapes, which indirectly indicates a low degree of entanglements between the macromolecular chains.</abstract><cop>Beijing</cop><pub>Chinese Chemical Society and Institute of Chemistry, CAS</pub><doi>10.1007/s10118-019-2197-0</doi><tpages>7</tpages><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0256-7679 |
| ispartof | Chinese journal of polymer science, 2019, Vol.37 (5), p.471-477 |
| issn | 0256-7679 1439-6203 |
| language | eng |
| recordid | cdi_proquest_journals_2194643477 |
| source | Springer Link |
| subjects | Catalysis Catalytic activity Chain entanglement Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Condensed Matter Physics Deformation Industrial Chemistry/Chemical Engineering Ligands Molecular chains Molecular weight Polyethylene Polymer Sciences Thermal stability Titanium Ultra high molecular weight polyethylene |
| title | Binuclear and Hexanuclear Ti(IV) Complexes Supported by [OOOO]4–-type Ligand for Preparing Disentangled UHMWPE |
| url | http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-09-22T03%3A36%3A14IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Binuclear%20and%20Hexanuclear%20Ti(IV)%20Complexes%20Supported%20by%20%5BOOOO%5D4%E2%80%93-type%20Ligand%20for%20Preparing%20Disentangled%20UHMWPE&rft.jtitle=Chinese%20journal%20of%20polymer%20science&rft.au=Tuskaev,%20Vladislav%20A.&rft.date=2019&rft.volume=37&rft.issue=5&rft.spage=471&rft.epage=477&rft.pages=471-477&rft.issn=0256-7679&rft.eissn=1439-6203&rft_id=info:doi/10.1007/s10118-019-2197-0&rft_dat=%3Cproquest_cross%3E2194643477%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c2040-8c3e2699bb8f18b397c9db6d87b9f5297ee60672fd315d8cea6c6427a4fdd173%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=2194643477&rft_id=info:pmid/&rfr_iscdi=true |