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Effect of Ho substitution on structure and magnetic properties of BiFeO3
Structure and magnetic properties of trivalent Ho substituted BiFeO3 (HoxBi1−xFeO3) have been studied for the compositional range x = 0 to 0.2. The structure remains in rhombohedral R3c for x
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Published in: | Journal of applied physics 2014-05, Vol.115 (17) |
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container_title | Journal of applied physics |
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creator | Suresh, Pittala Babu, P. D. Srinath, S. |
description | Structure and magnetic properties of trivalent Ho substituted BiFeO3 (HoxBi1−xFeO3) have been studied for the compositional range x = 0 to 0.2. The structure remains in rhombohedral R3c for x |
doi_str_mv | 10.1063/1.4863944 |
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D. ; Srinath, S.</creator><creatorcontrib>Suresh, Pittala ; Babu, P. D. ; Srinath, S.</creatorcontrib><description>Structure and magnetic properties of trivalent Ho substituted BiFeO3 (HoxBi1−xFeO3) have been studied for the compositional range x = 0 to 0.2. The structure remains in rhombohedral R3c for x < 0.15, and further increase in x results a structural transition to orthorhombic Pnma. The decrease in Raman modes and the appearance of new mode at 475 cm−1 confirms the structural changes. Ho doping at Bi site breaks the spin cycloid of BiFO3 and leads to the observation of ferromagnetic order at low temperatures. With increase in temperature, the M-H curves exhibit a pinching leading to double hysteresis loops. A minimum is observed in M-T curves for low fields at compensation temperature (ΘC) and HC attains a maximum close to ΘC. Variation of HC with temperature is discussed in terms of a model consisting of two sublattices. The improved magnetic properties achieved by Ho doping enhance the potential of BiFeO3 for multiferroic applications.</description><identifier>ISSN: 0021-8979</identifier><identifier>EISSN: 1089-7550</identifier><identifier>DOI: 10.1063/1.4863944</identifier><language>eng</language><publisher>Melville: American Institute of Physics</publisher><subject>Bismuth ferrite ; Cycloids ; Doping ; Ferromagnetism ; Hysteresis loops ; Lattices (mathematics) ; Magnetic properties ; Magnetism ; Subgroups</subject><ispartof>Journal of applied physics, 2014-05, Vol.115 (17)</ispartof><rights>2014 AIP Publishing LLC.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c257t-81c023aeb37bb1b609d2960e2cc0cb7bb776ca9082d8feaf12a537db032ed5573</citedby><cites>FETCH-LOGICAL-c257t-81c023aeb37bb1b609d2960e2cc0cb7bb776ca9082d8feaf12a537db032ed5573</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>315,786,790,27957,27958</link.rule.ids></links><search><creatorcontrib>Suresh, Pittala</creatorcontrib><creatorcontrib>Babu, P. D.</creatorcontrib><creatorcontrib>Srinath, S.</creatorcontrib><title>Effect of Ho substitution on structure and magnetic properties of BiFeO3</title><title>Journal of applied physics</title><description>Structure and magnetic properties of trivalent Ho substituted BiFeO3 (HoxBi1−xFeO3) have been studied for the compositional range x = 0 to 0.2. The structure remains in rhombohedral R3c for x < 0.15, and further increase in x results a structural transition to orthorhombic Pnma. The decrease in Raman modes and the appearance of new mode at 475 cm−1 confirms the structural changes. Ho doping at Bi site breaks the spin cycloid of BiFO3 and leads to the observation of ferromagnetic order at low temperatures. With increase in temperature, the M-H curves exhibit a pinching leading to double hysteresis loops. A minimum is observed in M-T curves for low fields at compensation temperature (ΘC) and HC attains a maximum close to ΘC. Variation of HC with temperature is discussed in terms of a model consisting of two sublattices. The improved magnetic properties achieved by Ho doping enhance the potential of BiFeO3 for multiferroic applications.</description><subject>Bismuth ferrite</subject><subject>Cycloids</subject><subject>Doping</subject><subject>Ferromagnetism</subject><subject>Hysteresis loops</subject><subject>Lattices (mathematics)</subject><subject>Magnetic properties</subject><subject>Magnetism</subject><subject>Subgroups</subject><issn>0021-8979</issn><issn>1089-7550</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNotkEFLAzEQhYMouFYP_oOAJw9bZ5LdTXLU0rpCoRc9hySbyBa7W5PswX_vlhYeDDzezDw-Qh4RlggNf8FlJRuuquqKFAhSlaKu4ZoUAAxLqYS6JXcp7QEQJVcFadcheJfpGGg70jTZlPs85X4c6KyU4-TyFD01Q0cP5nvwuXf0GMejj7n36bT31m_8jt-Tm2B-kn-4zAX52qw_V2253b1_rF63pWO1yKVEB4wbb7mwFm0DqmOqAc-cA2dnT4jGGQWSdTJ4E5CZmovOAme-q2vBF-TpfHcu8Tv5lPV-nOIwv9QMmWiUqBDn1PM55eKYUvRBH2N_MPFPI-gTKI36Aor_A2hDWcg</recordid><startdate>20140507</startdate><enddate>20140507</enddate><creator>Suresh, Pittala</creator><creator>Babu, P. D.</creator><creator>Srinath, S.</creator><general>American Institute of Physics</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FD</scope><scope>H8D</scope><scope>L7M</scope></search><sort><creationdate>20140507</creationdate><title>Effect of Ho substitution on structure and magnetic properties of BiFeO3</title><author>Suresh, Pittala ; Babu, P. D. ; Srinath, S.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c257t-81c023aeb37bb1b609d2960e2cc0cb7bb776ca9082d8feaf12a537db032ed5573</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Bismuth ferrite</topic><topic>Cycloids</topic><topic>Doping</topic><topic>Ferromagnetism</topic><topic>Hysteresis loops</topic><topic>Lattices (mathematics)</topic><topic>Magnetic properties</topic><topic>Magnetism</topic><topic>Subgroups</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Suresh, Pittala</creatorcontrib><creatorcontrib>Babu, P. D.</creatorcontrib><creatorcontrib>Srinath, S.</creatorcontrib><collection>CrossRef</collection><collection>Technology Research Database</collection><collection>Aerospace Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of applied physics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Suresh, Pittala</au><au>Babu, P. D.</au><au>Srinath, S.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Effect of Ho substitution on structure and magnetic properties of BiFeO3</atitle><jtitle>Journal of applied physics</jtitle><date>2014-05-07</date><risdate>2014</risdate><volume>115</volume><issue>17</issue><issn>0021-8979</issn><eissn>1089-7550</eissn><abstract>Structure and magnetic properties of trivalent Ho substituted BiFeO3 (HoxBi1−xFeO3) have been studied for the compositional range x = 0 to 0.2. The structure remains in rhombohedral R3c for x < 0.15, and further increase in x results a structural transition to orthorhombic Pnma. The decrease in Raman modes and the appearance of new mode at 475 cm−1 confirms the structural changes. Ho doping at Bi site breaks the spin cycloid of BiFO3 and leads to the observation of ferromagnetic order at low temperatures. With increase in temperature, the M-H curves exhibit a pinching leading to double hysteresis loops. A minimum is observed in M-T curves for low fields at compensation temperature (ΘC) and HC attains a maximum close to ΘC. Variation of HC with temperature is discussed in terms of a model consisting of two sublattices. The improved magnetic properties achieved by Ho doping enhance the potential of BiFeO3 for multiferroic applications.</abstract><cop>Melville</cop><pub>American Institute of Physics</pub><doi>10.1063/1.4863944</doi></addata></record> |
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subjects | Bismuth ferrite Cycloids Doping Ferromagnetism Hysteresis loops Lattices (mathematics) Magnetic properties Magnetism Subgroups |
title | Effect of Ho substitution on structure and magnetic properties of BiFeO3 |
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