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Sol-gel-modified membranes for all-organic battery based on bis-(tert-butylphenyl)nitroxide
It has been shown that sol-gel modification of Nafion membrane with amino-containing silica nanoparticles followed by neutralization converting the membrane in the salt form prevents decomposition of the model redox-active compound, bis( tert -butylphenyl)nitroxide, and suppresses its crossover yet...
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Published in: | Colloid and polymer science 2019-03, Vol.297 (3), p.317-323 |
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container_end_page | 323 |
container_issue | 3 |
container_start_page | 317 |
container_title | Colloid and polymer science |
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creator | Karpushkin, Evgeny A. Gvozdik, Nataliya A. Levitskiy, Oleg A. Stevenson, Keith J. Sergeyev, Vladimir G. Magdesieva, Tatiana V. |
description | It has been shown that sol-gel modification of Nafion membrane with amino-containing silica nanoparticles followed by neutralization converting the membrane in the salt form prevents decomposition of the model redox-active compound, bis(
tert
-butylphenyl)nitroxide, and suppresses its crossover yet maintaining sufficient permeability of a supporting electrolyte in acetonitrile solution. Bis(
tert
-butylphenyl)nitroxide is stable under the operation conditions of the redox flow battery assembled with Celgard membrane. |
doi_str_mv | 10.1007/s00396-018-4387-7 |
format | article |
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tert
-butylphenyl)nitroxide, and suppresses its crossover yet maintaining sufficient permeability of a supporting electrolyte in acetonitrile solution. Bis(
tert
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tert
-butylphenyl)nitroxide, and suppresses its crossover yet maintaining sufficient permeability of a supporting electrolyte in acetonitrile solution. Bis(
tert
-butylphenyl)nitroxide is stable under the operation conditions of the redox flow battery assembled with Celgard membrane.</description><subject>Acetonitrile</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Complex Fluids and Microfluidics</subject><subject>Crossovers</subject><subject>Food Science</subject><subject>Invited Article</subject><subject>Nanoparticles</subject><subject>Nanotechnology and Microengineering</subject><subject>Physical Chemistry</subject><subject>Polymer Sciences</subject><subject>Rechargeable batteries</subject><subject>Silicon dioxide</subject><subject>Soft and Granular Matter</subject><subject>Sol-gel processes</subject><issn>0303-402X</issn><issn>1435-1536</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp1kE1LxDAQhoMouK7-AG8FL3qITpK2SY6y-AULHlQQPIS0SdYubVOTLth_b5YKnmQOLwzPOwMPQucErgkAv4kATJYYiMA5ExzzA7QgOSswKVh5iBbAgOEc6PsxOolxCwC5LMsF-njxLd7YFnfeNK6xJutsVwXd25g5HzLdttiHje6bOqv0ONowpYyJ831WNRFfptWIq904tcOn7af2qm_G4L8bY0_RkdNttGe_uURv93evq0e8fn54Wt2ucc0KNuLScKYto5UTBWFWgKMShNCFNmCZKCQxspKQszRUG6qtc7WRecG4kDQXbIku5rtD8F87G0e19bvQp5eKguSUSyn3FJmpOvgYg3VqCE2nw6QIqL1DNTtUyaHaO1Q8dejciYntNzb8Xf6_9APRIXRz</recordid><startdate>20190301</startdate><enddate>20190301</enddate><creator>Karpushkin, Evgeny A.</creator><creator>Gvozdik, Nataliya A.</creator><creator>Levitskiy, Oleg A.</creator><creator>Stevenson, Keith J.</creator><creator>Sergeyev, Vladimir G.</creator><creator>Magdesieva, Tatiana V.</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><orcidid>https://orcid.org/0000-0003-2173-652X</orcidid></search><sort><creationdate>20190301</creationdate><title>Sol-gel-modified membranes for all-organic battery based on bis-(tert-butylphenyl)nitroxide</title><author>Karpushkin, Evgeny A. ; 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tert
-butylphenyl)nitroxide, and suppresses its crossover yet maintaining sufficient permeability of a supporting electrolyte in acetonitrile solution. Bis(
tert
-butylphenyl)nitroxide is stable under the operation conditions of the redox flow battery assembled with Celgard membrane.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s00396-018-4387-7</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0003-2173-652X</orcidid></addata></record> |
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subjects | Acetonitrile Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Complex Fluids and Microfluidics Crossovers Food Science Invited Article Nanoparticles Nanotechnology and Microengineering Physical Chemistry Polymer Sciences Rechargeable batteries Silicon dioxide Soft and Granular Matter Sol-gel processes |
title | Sol-gel-modified membranes for all-organic battery based on bis-(tert-butylphenyl)nitroxide |
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