Loading…
Investigation of the relationship between infrared structure and pyrolysis reactivity of coals with different ranks
•Length of the aliphatic side chains of coal with same rank are in complex tendency.•The function groups of coal can be characterized by infrared structural parameters.•The infrared structural parameters are defined according to the peak area ratio.Parameter S can be referenced to predict pyrolysis...
Saved in:
Published in: | Fuel (Guildford) 2018-03, Vol.216, p.521-530 |
---|---|
Main Authors: | , , , , , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
cited_by | cdi_FETCH-LOGICAL-c365t-542c1fd6d92828363d38201972ce53b6d3bb45a5fba6ffa18359a8b312256a283 |
---|---|
cites | cdi_FETCH-LOGICAL-c365t-542c1fd6d92828363d38201972ce53b6d3bb45a5fba6ffa18359a8b312256a283 |
container_end_page | 530 |
container_issue | |
container_start_page | 521 |
container_title | Fuel (Guildford) |
container_volume | 216 |
creator | Xie, Xing Zhao, Yan Qiu, Penghua Lin, Dan Qian, Juan Hou, Haimeng Pei, Jiangtao |
description | •Length of the aliphatic side chains of coal with same rank are in complex tendency.•The function groups of coal can be characterized by infrared structural parameters.•The infrared structural parameters are defined according to the peak area ratio.Parameter S can be referenced to predict pyrolysis reactivity of different coal.
The chemical structures of six coal samples with different ranks were semi-quantitatively characterized by a series of original infrared structural parameters, and the pyrolysis reactivity of the samples were quantitatively characterized by a comprehensive devolatilization index. A correlation was established between the infrared structural parameters and pyrolysis reactivity. The results show that the infrared structural parameter method presented in this paper can reveal the distribution characteristic of chemical bonds in coal effectively. The total content of oxygen-containing functional groups, CH groups and the inorganic mineral can be satisfactorily characterized by infrared structural parameter, Ia3, Ib4 and Id3 respectively. The length of aliphatic side chains or bridge bonds undergoes a Stable-Increased-Decreased process. Good positive correlation was established between the comprehensive infrared structural parameter S and the pyrolysis reactivity, which was proved effective to predict the pyrolysis reactivity of coal over various ranks. |
doi_str_mv | 10.1016/j.fuel.2017.12.049 |
format | article |
fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2071300112</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0016236117316150</els_id><sourcerecordid>2071300112</sourcerecordid><originalsourceid>FETCH-LOGICAL-c365t-542c1fd6d92828363d38201972ce53b6d3bb45a5fba6ffa18359a8b312256a283</originalsourceid><addsrcrecordid>eNp9kLtOwzAUhi0EEqXwAkyWmBN8iZNUYkEVl0qVWGC2HPuYOhQn2E5R3x6XMjNZR_6_c_kQuqakpITWt31pJ9iWjNCmpKwk1eIEzWjb8KKhgp-iGcmpgvGanqOLGHtCSNOKaobiyu8gJveukhs8HixOG8ABtr913LgRd5C-ATx23gYVwOCYwqTTFAArb_C4D8N2H13MlNLJ7VzaH_roQW0j_nZpg42zFgL4hIPyH_ESndn8B1d_7xy9PT68Lp-L9cvTanm_LjSvRSpExTS1pjYL1rKW19zwNh-4aJgGwbva8K6rhBK2U7W1irZcLFTbccqYqFUm5ujm2HcMw9eUr5T9MAWfR0pGGsqzE8pyih1TOgwxBrByDO5Thb2kRB7kyl4e5MqDXEmZzHIzdHeEIO-_cxBk1A68BuMC6CTN4P7DfwAuMoUR</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2071300112</pqid></control><display><type>article</type><title>Investigation of the relationship between infrared structure and pyrolysis reactivity of coals with different ranks</title><source>ScienceDirect Freedom Collection 2022-2024</source><creator>Xie, Xing ; Zhao, Yan ; Qiu, Penghua ; Lin, Dan ; Qian, Juan ; Hou, Haimeng ; Pei, Jiangtao</creator><creatorcontrib>Xie, Xing ; Zhao, Yan ; Qiu, Penghua ; Lin, Dan ; Qian, Juan ; Hou, Haimeng ; Pei, Jiangtao</creatorcontrib><description>•Length of the aliphatic side chains of coal with same rank are in complex tendency.•The function groups of coal can be characterized by infrared structural parameters.•The infrared structural parameters are defined according to the peak area ratio.Parameter S can be referenced to predict pyrolysis reactivity of different coal.
The chemical structures of six coal samples with different ranks were semi-quantitatively characterized by a series of original infrared structural parameters, and the pyrolysis reactivity of the samples were quantitatively characterized by a comprehensive devolatilization index. A correlation was established between the infrared structural parameters and pyrolysis reactivity. The results show that the infrared structural parameter method presented in this paper can reveal the distribution characteristic of chemical bonds in coal effectively. The total content of oxygen-containing functional groups, CH groups and the inorganic mineral can be satisfactorily characterized by infrared structural parameter, Ia3, Ib4 and Id3 respectively. The length of aliphatic side chains or bridge bonds undergoes a Stable-Increased-Decreased process. Good positive correlation was established between the comprehensive infrared structural parameter S and the pyrolysis reactivity, which was proved effective to predict the pyrolysis reactivity of coal over various ranks.</description><identifier>ISSN: 0016-2361</identifier><identifier>EISSN: 1873-7153</identifier><identifier>DOI: 10.1016/j.fuel.2017.12.049</identifier><language>eng</language><publisher>Kidlington: Elsevier Ltd</publisher><subject>Aliphatic compounds ; Chemical bonds ; Chemical reactions ; Chemical structure ; Coal ; Curve fitting ; Devolatilization ; Functional groups ; Infrared structural parameter ; Molecular structure ; Organic chemistry ; Parameters ; Pyrolysis ; Pyrolysis reactivity ; Reactivity</subject><ispartof>Fuel (Guildford), 2018-03, Vol.216, p.521-530</ispartof><rights>2017 Elsevier Ltd</rights><rights>Copyright Elsevier BV Mar 15, 2018</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c365t-542c1fd6d92828363d38201972ce53b6d3bb45a5fba6ffa18359a8b312256a283</citedby><cites>FETCH-LOGICAL-c365t-542c1fd6d92828363d38201972ce53b6d3bb45a5fba6ffa18359a8b312256a283</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>315,786,790,27957,27958</link.rule.ids></links><search><creatorcontrib>Xie, Xing</creatorcontrib><creatorcontrib>Zhao, Yan</creatorcontrib><creatorcontrib>Qiu, Penghua</creatorcontrib><creatorcontrib>Lin, Dan</creatorcontrib><creatorcontrib>Qian, Juan</creatorcontrib><creatorcontrib>Hou, Haimeng</creatorcontrib><creatorcontrib>Pei, Jiangtao</creatorcontrib><title>Investigation of the relationship between infrared structure and pyrolysis reactivity of coals with different ranks</title><title>Fuel (Guildford)</title><description>•Length of the aliphatic side chains of coal with same rank are in complex tendency.•The function groups of coal can be characterized by infrared structural parameters.•The infrared structural parameters are defined according to the peak area ratio.Parameter S can be referenced to predict pyrolysis reactivity of different coal.
The chemical structures of six coal samples with different ranks were semi-quantitatively characterized by a series of original infrared structural parameters, and the pyrolysis reactivity of the samples were quantitatively characterized by a comprehensive devolatilization index. A correlation was established between the infrared structural parameters and pyrolysis reactivity. The results show that the infrared structural parameter method presented in this paper can reveal the distribution characteristic of chemical bonds in coal effectively. The total content of oxygen-containing functional groups, CH groups and the inorganic mineral can be satisfactorily characterized by infrared structural parameter, Ia3, Ib4 and Id3 respectively. The length of aliphatic side chains or bridge bonds undergoes a Stable-Increased-Decreased process. Good positive correlation was established between the comprehensive infrared structural parameter S and the pyrolysis reactivity, which was proved effective to predict the pyrolysis reactivity of coal over various ranks.</description><subject>Aliphatic compounds</subject><subject>Chemical bonds</subject><subject>Chemical reactions</subject><subject>Chemical structure</subject><subject>Coal</subject><subject>Curve fitting</subject><subject>Devolatilization</subject><subject>Functional groups</subject><subject>Infrared structural parameter</subject><subject>Molecular structure</subject><subject>Organic chemistry</subject><subject>Parameters</subject><subject>Pyrolysis</subject><subject>Pyrolysis reactivity</subject><subject>Reactivity</subject><issn>0016-2361</issn><issn>1873-7153</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNp9kLtOwzAUhi0EEqXwAkyWmBN8iZNUYkEVl0qVWGC2HPuYOhQn2E5R3x6XMjNZR_6_c_kQuqakpITWt31pJ9iWjNCmpKwk1eIEzWjb8KKhgp-iGcmpgvGanqOLGHtCSNOKaobiyu8gJveukhs8HixOG8ABtr913LgRd5C-ATx23gYVwOCYwqTTFAArb_C4D8N2H13MlNLJ7VzaH_roQW0j_nZpg42zFgL4hIPyH_ESndn8B1d_7xy9PT68Lp-L9cvTanm_LjSvRSpExTS1pjYL1rKW19zwNh-4aJgGwbva8K6rhBK2U7W1irZcLFTbccqYqFUm5ujm2HcMw9eUr5T9MAWfR0pGGsqzE8pyih1TOgwxBrByDO5Thb2kRB7kyl4e5MqDXEmZzHIzdHeEIO-_cxBk1A68BuMC6CTN4P7DfwAuMoUR</recordid><startdate>20180315</startdate><enddate>20180315</enddate><creator>Xie, Xing</creator><creator>Zhao, Yan</creator><creator>Qiu, Penghua</creator><creator>Lin, Dan</creator><creator>Qian, Juan</creator><creator>Hou, Haimeng</creator><creator>Pei, Jiangtao</creator><general>Elsevier Ltd</general><general>Elsevier BV</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7QO</scope><scope>7QQ</scope><scope>7SC</scope><scope>7SE</scope><scope>7SP</scope><scope>7SR</scope><scope>7T7</scope><scope>7TA</scope><scope>7TB</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>C1K</scope><scope>F28</scope><scope>FR3</scope><scope>H8D</scope><scope>H8G</scope><scope>JG9</scope><scope>JQ2</scope><scope>KR7</scope><scope>L7M</scope><scope>L~C</scope><scope>L~D</scope><scope>P64</scope></search><sort><creationdate>20180315</creationdate><title>Investigation of the relationship between infrared structure and pyrolysis reactivity of coals with different ranks</title><author>Xie, Xing ; Zhao, Yan ; Qiu, Penghua ; Lin, Dan ; Qian, Juan ; Hou, Haimeng ; Pei, Jiangtao</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c365t-542c1fd6d92828363d38201972ce53b6d3bb45a5fba6ffa18359a8b312256a283</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Aliphatic compounds</topic><topic>Chemical bonds</topic><topic>Chemical reactions</topic><topic>Chemical structure</topic><topic>Coal</topic><topic>Curve fitting</topic><topic>Devolatilization</topic><topic>Functional groups</topic><topic>Infrared structural parameter</topic><topic>Molecular structure</topic><topic>Organic chemistry</topic><topic>Parameters</topic><topic>Pyrolysis</topic><topic>Pyrolysis reactivity</topic><topic>Reactivity</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Xie, Xing</creatorcontrib><creatorcontrib>Zhao, Yan</creatorcontrib><creatorcontrib>Qiu, Penghua</creatorcontrib><creatorcontrib>Lin, Dan</creatorcontrib><creatorcontrib>Qian, Juan</creatorcontrib><creatorcontrib>Hou, Haimeng</creatorcontrib><creatorcontrib>Pei, Jiangtao</creatorcontrib><collection>CrossRef</collection><collection>Aluminium Industry Abstracts</collection><collection>Biotechnology Research Abstracts</collection><collection>Ceramic Abstracts</collection><collection>Computer and Information Systems Abstracts</collection><collection>Corrosion Abstracts</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Industrial and Applied Microbiology Abstracts (Microbiology A)</collection><collection>Materials Business File</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Aerospace Database</collection><collection>Copper Technical Reference Library</collection><collection>Materials Research Database</collection><collection>ProQuest Computer Science Collection</collection><collection>Civil Engineering Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Computer and Information Systems Abstracts Academic</collection><collection>Computer and Information Systems Abstracts Professional</collection><collection>Biotechnology and BioEngineering Abstracts</collection><jtitle>Fuel (Guildford)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Xie, Xing</au><au>Zhao, Yan</au><au>Qiu, Penghua</au><au>Lin, Dan</au><au>Qian, Juan</au><au>Hou, Haimeng</au><au>Pei, Jiangtao</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Investigation of the relationship between infrared structure and pyrolysis reactivity of coals with different ranks</atitle><jtitle>Fuel (Guildford)</jtitle><date>2018-03-15</date><risdate>2018</risdate><volume>216</volume><spage>521</spage><epage>530</epage><pages>521-530</pages><issn>0016-2361</issn><eissn>1873-7153</eissn><abstract>•Length of the aliphatic side chains of coal with same rank are in complex tendency.•The function groups of coal can be characterized by infrared structural parameters.•The infrared structural parameters are defined according to the peak area ratio.Parameter S can be referenced to predict pyrolysis reactivity of different coal.
The chemical structures of six coal samples with different ranks were semi-quantitatively characterized by a series of original infrared structural parameters, and the pyrolysis reactivity of the samples were quantitatively characterized by a comprehensive devolatilization index. A correlation was established between the infrared structural parameters and pyrolysis reactivity. The results show that the infrared structural parameter method presented in this paper can reveal the distribution characteristic of chemical bonds in coal effectively. The total content of oxygen-containing functional groups, CH groups and the inorganic mineral can be satisfactorily characterized by infrared structural parameter, Ia3, Ib4 and Id3 respectively. The length of aliphatic side chains or bridge bonds undergoes a Stable-Increased-Decreased process. Good positive correlation was established between the comprehensive infrared structural parameter S and the pyrolysis reactivity, which was proved effective to predict the pyrolysis reactivity of coal over various ranks.</abstract><cop>Kidlington</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.fuel.2017.12.049</doi><tpages>10</tpages></addata></record> |
fulltext | fulltext |
identifier | ISSN: 0016-2361 |
ispartof | Fuel (Guildford), 2018-03, Vol.216, p.521-530 |
issn | 0016-2361 1873-7153 |
language | eng |
recordid | cdi_proquest_journals_2071300112 |
source | ScienceDirect Freedom Collection 2022-2024 |
subjects | Aliphatic compounds Chemical bonds Chemical reactions Chemical structure Coal Curve fitting Devolatilization Functional groups Infrared structural parameter Molecular structure Organic chemistry Parameters Pyrolysis Pyrolysis reactivity Reactivity |
title | Investigation of the relationship between infrared structure and pyrolysis reactivity of coals with different ranks |
url | http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-09-22T11%3A25%3A06IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Investigation%20of%20the%20relationship%20between%20infrared%20structure%20and%20pyrolysis%20reactivity%20of%20coals%20with%20different%20ranks&rft.jtitle=Fuel%20(Guildford)&rft.au=Xie,%20Xing&rft.date=2018-03-15&rft.volume=216&rft.spage=521&rft.epage=530&rft.pages=521-530&rft.issn=0016-2361&rft.eissn=1873-7153&rft_id=info:doi/10.1016/j.fuel.2017.12.049&rft_dat=%3Cproquest_cross%3E2071300112%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c365t-542c1fd6d92828363d38201972ce53b6d3bb45a5fba6ffa18359a8b312256a283%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=2071300112&rft_id=info:pmid/&rfr_iscdi=true |