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Formation and Properties of a Support Made of Solid Solutions Based on Zirconium Oxide for Single Tubular Solid-Oxide Fuel Cells

Technique was developed for fabrication of a supporting thin-walled gas-tight ZrO 2 –Y 2 O 3 electrolyte base of strict configuration for tubular solid-oxide fuel cells. The technique includes a plasma-assisted deposition and vacuum impregnation with salt solutions, followed by a thermal treatment....

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Published in:Russian journal of applied chemistry 2018-02, Vol.91 (2), p.196-201
Main Authors: Kuzmin, A. V., Novikova, Yu. V., Stroeva, A. Yu, Gorelov, V. P., Vylkov, A. I., Ananiev, M. V., Ermakov, A. V., Zaikov, Yu. P.
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container_title Russian journal of applied chemistry
container_volume 91
creator Kuzmin, A. V.
Novikova, Yu. V.
Stroeva, A. Yu
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Vylkov, A. I.
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Ermakov, A. V.
Zaikov, Yu. P.
description Technique was developed for fabrication of a supporting thin-walled gas-tight ZrO 2 –Y 2 O 3 electrolyte base of strict configuration for tubular solid-oxide fuel cells. The technique includes a plasma-assisted deposition and vacuum impregnation with salt solutions, followed by a thermal treatment. The properties of plasma-ceramic solid electrolytes based on cubic and tetragonal (t') forms of ZrO 2 and the same electrolytes modified with small additions (0.5 wt %) of aluminum oxide were examined. The phase composition, electrical conductivity, thermal expansion, and stability of the materials synthesized were studied. A high stability in time of the tetragonal t'-solid electrolytes was noted, which opens up prospects for their application in solid-oxide fuel cells.
doi_str_mv 10.1134/S1070427218020040
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subjects Aluminum oxide
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Electrical resistivity
Electrolytes
Electrolytic cells
Fuel cells
Heat treatment
Industrial Chemistry/Chemical Engineering
Ions
Molten salt electrolytes
Phase composition
Salt solutions
Solid electrolytes
Solid oxide fuel cells
Solid solutions
Stability
Thermal expansion
Various Technological Processes
Yttrium oxide
Zirconium dioxide
Zirconium oxides
title Formation and Properties of a Support Made of Solid Solutions Based on Zirconium Oxide for Single Tubular Solid-Oxide Fuel Cells
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