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Electrochemical kinetics of Li insertion in nanosized high performance V^sub 2^O^sub 5^ obtained via fluorine chemistry
The kinetics of the electrochemical lithium insertion reaction in nanosized V2O5 prepared from a fluorination synthesis in solution is investigated by AC impedance spectroscopy. The experimental data are obtained vs. x in nano-LixV2O5 over the wide composition range 0 ≤ x < 1.8 and vs. temperatur...
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Published in: | Electrochimica acta 2017-11, Vol.253, p.472 |
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description | The kinetics of the electrochemical lithium insertion reaction in nanosized V2O5 prepared from a fluorination synthesis in solution is investigated by AC impedance spectroscopy. The experimental data are obtained vs. x in nano-LixV2O5 over the wide composition range 0 ≤ x < 1.8 and vs. temperature. Kinetic parameters for Li electroinsertion in nanosized V2O5 are achieved here for the first time. The charge transfer kinetics is little affected by Li content. A moderate evolution of the chemical diffusion coefficient is related to the peculiar single-phase behavior induced by the nanosize effect combined with shorter Li diffusion pathways. Comparison with experimental data obtained for microsized analogue vs. temperature reveals a much lower activation energy barrier (0.06 eV) for the lithium diffusion process in nanosized V2O5 that explains the significant improvement in electrochemical performances and especially a better rate capability. This work illustrates how nanosizing promotes the kinetics of Li insertion reaction, in agreement with the new and specific structural response of nanosized vanadium pentoxide. |
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The experimental data are obtained vs. x in nano-LixV2O5 over the wide composition range 0 ≤ x < 1.8 and vs. temperature. Kinetic parameters for Li electroinsertion in nanosized V2O5 are achieved here for the first time. The charge transfer kinetics is little affected by Li content. A moderate evolution of the chemical diffusion coefficient is related to the peculiar single-phase behavior induced by the nanosize effect combined with shorter Li diffusion pathways. Comparison with experimental data obtained for microsized analogue vs. temperature reveals a much lower activation energy barrier (0.06 eV) for the lithium diffusion process in nanosized V2O5 that explains the significant improvement in electrochemical performances and especially a better rate capability. This work illustrates how nanosizing promotes the kinetics of Li insertion reaction, in agreement with the new and specific structural response of nanosized vanadium pentoxide.</description><identifier>ISSN: 0013-4686</identifier><identifier>EISSN: 1873-3859</identifier><language>eng</language><publisher>Oxford: Elsevier BV</publisher><subject>Charge transfer ; Chemical diffusion ; Chemical synthesis ; Diffusion barriers ; Diffusion coefficient ; Fluorination ; Fluorine ; Insertion ; Kinetics ; Lithium ; Reaction kinetics ; Vanadium pentoxide</subject><ispartof>Electrochimica acta, 2017-11, Vol.253, p.472</ispartof><rights>Copyright Elsevier BV Nov 1, 2017</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>315,786,790</link.rule.ids></links><search><creatorcontrib>Huo, D</creatorcontrib><creatorcontrib>Laïk, B</creatorcontrib><creatorcontrib>Bonnet, P</creatorcontrib><creatorcontrib>Guérin, K</creatorcontrib><creatorcontrib>Baddour-Hadjean, R</creatorcontrib><creatorcontrib>Pereira-Ramos, J-P</creatorcontrib><title>Electrochemical kinetics of Li insertion in nanosized high performance V^sub 2^O^sub 5^ obtained via fluorine chemistry</title><title>Electrochimica acta</title><description>The kinetics of the electrochemical lithium insertion reaction in nanosized V2O5 prepared from a fluorination synthesis in solution is investigated by AC impedance spectroscopy. 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The experimental data are obtained vs. x in nano-LixV2O5 over the wide composition range 0 ≤ x < 1.8 and vs. temperature. Kinetic parameters for Li electroinsertion in nanosized V2O5 are achieved here for the first time. The charge transfer kinetics is little affected by Li content. A moderate evolution of the chemical diffusion coefficient is related to the peculiar single-phase behavior induced by the nanosize effect combined with shorter Li diffusion pathways. Comparison with experimental data obtained for microsized analogue vs. temperature reveals a much lower activation energy barrier (0.06 eV) for the lithium diffusion process in nanosized V2O5 that explains the significant improvement in electrochemical performances and especially a better rate capability. 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subjects | Charge transfer Chemical diffusion Chemical synthesis Diffusion barriers Diffusion coefficient Fluorination Fluorine Insertion Kinetics Lithium Reaction kinetics Vanadium pentoxide |
title | Electrochemical kinetics of Li insertion in nanosized high performance V^sub 2^O^sub 5^ obtained via fluorine chemistry |
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