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Curing kinetics and thermal characterization of epoxy resin cured with amidodicarboxylic acids
•Curing properties of epoxy resins crosslinked with amidodicarboxylic acids.•Simultaneous TG/FT-IR/MS analysis of crosslinked resins.•Life time prediction of the crosslinked products. Thermal properties and the curing kinetics of a system based on DGEBA as epoxy resin and two amidodicarboxylic acids...
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Published in: | Applied thermal engineering 2017-10, Vol.125, p.285-296 |
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description | •Curing properties of epoxy resins crosslinked with amidodicarboxylic acids.•Simultaneous TG/FT-IR/MS analysis of crosslinked resins.•Life time prediction of the crosslinked products.
Thermal properties and the curing kinetics of a system based on DGEBA as epoxy resin and two amidodicarboxylic acids as hardeners (epoxy ring/carboxylic proton at 1/0.7molar ratio) were investigated using differential scanning calorimetry (DSC) and simultaneous TG/FT-IR/MS analysis. “Thermokinetics-3” software (Netzsch) was used to simulate the curing reaction mechanisms and thermal degradation of the crosslinked products, simultaneously with the kinetic parameters determination. According to data obtained with this program, the crosslinking processes occurred in two or three steps while the thermal processes occurred in three steps, depending on the chemical structure of the crosslinking agents. |
doi_str_mv | 10.1016/j.applthermaleng.2017.07.037 |
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Thermal properties and the curing kinetics of a system based on DGEBA as epoxy resin and two amidodicarboxylic acids as hardeners (epoxy ring/carboxylic proton at 1/0.7molar ratio) were investigated using differential scanning calorimetry (DSC) and simultaneous TG/FT-IR/MS analysis. “Thermokinetics-3” software (Netzsch) was used to simulate the curing reaction mechanisms and thermal degradation of the crosslinked products, simultaneously with the kinetic parameters determination. According to data obtained with this program, the crosslinking processes occurred in two or three steps while the thermal processes occurred in three steps, depending on the chemical structure of the crosslinking agents.</description><identifier>ISSN: 1359-4311</identifier><identifier>EISSN: 1873-5606</identifier><identifier>DOI: 10.1016/j.applthermaleng.2017.07.037</identifier><language>eng</language><publisher>Oxford: Elsevier Ltd</publisher><subject>Amidodicarboxylic acids ; Crosslinking ; Curing ; Curing kinetics ; Epoxy resins ; Hardeners ; Heat measurement ; Infrared radiation ; Kinetics ; Reaction kinetics ; Reaction mechanisms ; Thermal analysis ; Thermal degradation ; Thermal stability ; Thermodynamic properties</subject><ispartof>Applied thermal engineering, 2017-10, Vol.125, p.285-296</ispartof><rights>2017 Elsevier Ltd</rights><rights>Copyright Elsevier BV Oct 2017</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c358t-1dd0d803d696a93f643e99d52e4a2a1ad4352b00282cf4eb23b12f567e7b13703</citedby><cites>FETCH-LOGICAL-c358t-1dd0d803d696a93f643e99d52e4a2a1ad4352b00282cf4eb23b12f567e7b13703</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>315,786,790,27957,27958</link.rule.ids></links><search><creatorcontrib>Mustata, Fanica</creatorcontrib><creatorcontrib>Tudorachi, Nita</creatorcontrib><title>Curing kinetics and thermal characterization of epoxy resin cured with amidodicarboxylic acids</title><title>Applied thermal engineering</title><description>•Curing properties of epoxy resins crosslinked with amidodicarboxylic acids.•Simultaneous TG/FT-IR/MS analysis of crosslinked resins.•Life time prediction of the crosslinked products.
Thermal properties and the curing kinetics of a system based on DGEBA as epoxy resin and two amidodicarboxylic acids as hardeners (epoxy ring/carboxylic proton at 1/0.7molar ratio) were investigated using differential scanning calorimetry (DSC) and simultaneous TG/FT-IR/MS analysis. “Thermokinetics-3” software (Netzsch) was used to simulate the curing reaction mechanisms and thermal degradation of the crosslinked products, simultaneously with the kinetic parameters determination. According to data obtained with this program, the crosslinking processes occurred in two or three steps while the thermal processes occurred in three steps, depending on the chemical structure of the crosslinking agents.</description><subject>Amidodicarboxylic acids</subject><subject>Crosslinking</subject><subject>Curing</subject><subject>Curing kinetics</subject><subject>Epoxy resins</subject><subject>Hardeners</subject><subject>Heat measurement</subject><subject>Infrared radiation</subject><subject>Kinetics</subject><subject>Reaction kinetics</subject><subject>Reaction mechanisms</subject><subject>Thermal analysis</subject><subject>Thermal degradation</subject><subject>Thermal stability</subject><subject>Thermodynamic properties</subject><issn>1359-4311</issn><issn>1873-5606</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNqNUE1LAzEUDKJgrf6HgF53zcd-ghcpfkHBi14N2eRtm3W7WZOsWn-9Ke3FmzDwHryZecwgdEVJSgktrrtUjmMf1uA2sodhlTJCy5RE8PIIzWhV8iQvSHEcd57XScYpPUVn3neEUFaV2Qy9LSZnhhV-NwMEozyWg8YHR6zW0kkVwJkfGYwdsG0xjPZ7ix14M2A1OdD4y4Q1lhujrTZKuibee6OwVEb7c3TSyt7DxWHO0ev93cviMVk-PzwtbpeJ4nkVEqo10RXhuqgLWfO2yDjUtc4ZZJJJKnXGc9YQwiqm2gwaxhvK2rwooWwoLwmfo8u97-jsxwQ-iM5ObogvBa1zRrMYlkfWzZ6lnPXeQStGZzbSbQUlYteo6MTfRsWuUUEieBnl93s5xCSfBpzwysCgQBsHKghtzf-MfgEDsIlr</recordid><startdate>20171001</startdate><enddate>20171001</enddate><creator>Mustata, Fanica</creator><creator>Tudorachi, Nita</creator><general>Elsevier Ltd</general><general>Elsevier BV</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7TB</scope><scope>8FD</scope><scope>FR3</scope><scope>KR7</scope></search><sort><creationdate>20171001</creationdate><title>Curing kinetics and thermal characterization of epoxy resin cured with amidodicarboxylic acids</title><author>Mustata, Fanica ; Tudorachi, Nita</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c358t-1dd0d803d696a93f643e99d52e4a2a1ad4352b00282cf4eb23b12f567e7b13703</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Amidodicarboxylic acids</topic><topic>Crosslinking</topic><topic>Curing</topic><topic>Curing kinetics</topic><topic>Epoxy resins</topic><topic>Hardeners</topic><topic>Heat measurement</topic><topic>Infrared radiation</topic><topic>Kinetics</topic><topic>Reaction kinetics</topic><topic>Reaction mechanisms</topic><topic>Thermal analysis</topic><topic>Thermal degradation</topic><topic>Thermal stability</topic><topic>Thermodynamic properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Mustata, Fanica</creatorcontrib><creatorcontrib>Tudorachi, Nita</creatorcontrib><collection>CrossRef</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Civil Engineering Abstracts</collection><jtitle>Applied thermal engineering</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Mustata, Fanica</au><au>Tudorachi, Nita</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Curing kinetics and thermal characterization of epoxy resin cured with amidodicarboxylic acids</atitle><jtitle>Applied thermal engineering</jtitle><date>2017-10-01</date><risdate>2017</risdate><volume>125</volume><spage>285</spage><epage>296</epage><pages>285-296</pages><issn>1359-4311</issn><eissn>1873-5606</eissn><abstract>•Curing properties of epoxy resins crosslinked with amidodicarboxylic acids.•Simultaneous TG/FT-IR/MS analysis of crosslinked resins.•Life time prediction of the crosslinked products.
Thermal properties and the curing kinetics of a system based on DGEBA as epoxy resin and two amidodicarboxylic acids as hardeners (epoxy ring/carboxylic proton at 1/0.7molar ratio) were investigated using differential scanning calorimetry (DSC) and simultaneous TG/FT-IR/MS analysis. “Thermokinetics-3” software (Netzsch) was used to simulate the curing reaction mechanisms and thermal degradation of the crosslinked products, simultaneously with the kinetic parameters determination. According to data obtained with this program, the crosslinking processes occurred in two or three steps while the thermal processes occurred in three steps, depending on the chemical structure of the crosslinking agents.</abstract><cop>Oxford</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.applthermaleng.2017.07.037</doi><tpages>12</tpages></addata></record> |
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subjects | Amidodicarboxylic acids Crosslinking Curing Curing kinetics Epoxy resins Hardeners Heat measurement Infrared radiation Kinetics Reaction kinetics Reaction mechanisms Thermal analysis Thermal degradation Thermal stability Thermodynamic properties |
title | Curing kinetics and thermal characterization of epoxy resin cured with amidodicarboxylic acids |
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