Polyethylene terephthalate degradation under reactor neutron irradiation

This paper is devoted to study the defects generated by reactor neutron in polyethylene terephthalate (PET) films. The explored fast neutron fluence ranges from 2.02×1016 to 2.07×1018ncm−2. The induced damages were investigated using ultraviolet-visible spectrophotometry (UV-vis), Fourier Transform...

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Bibliographic Details
Published in:Radiation physics and chemistry (Oxford, England : 1993) England : 1993), 2017-01, Vol.130, p.431-435
Main Authors: Chikaoui, K., Izerrouken, M., Djebara, M., Abdesselam, M.
Format: Article
Language:English
Subjects:
Absorption spectra
Benzene
Chromophores
Crystal defects
Degradation
Diffraction
Fast neutron
Fast neutrons
Fluence
Fourier transforms
FTIR
Infrared spectroscopy
Neutron irradiation
Neutrons
Polyethylene terephthalate
Radiation damage
Reactor neutron irradiation
Scientific imaging
Spectrometry
Spectrophotometry
UV–vis
X-ray diffraction
X-rays
XRD
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Summary:This paper is devoted to study the defects generated by reactor neutron in polyethylene terephthalate (PET) films. The explored fast neutron fluence ranges from 2.02×1016 to 2.07×1018ncm−2. The induced damages were investigated using ultraviolet-visible spectrophotometry (UV-vis), Fourier Transform Infrared spectrometry (FTIR) and X-ray diffraction (XRD). The UV-vis spectra show important changes indicating the degradation of the chemical structure and the creation of new chromophores. FTIR spectra reveal that the intensities of the different absorption bands decrease linearly under fast neutron irradiation. The internal reference band at 1410cm−1 is used to follow the overall damage during irradiation. The 1342cm−1 band corresponding to CH2 wagging of trans conformation of crystalline phase show a sharpe linear decrease as the fast neutrons fluence goes up. The creation of the monosubstituted benzene, investigated using the 1610cm−1 band. It shows a linear increase with fast neutron fluence. It is found from XRD analysis that the diffraction peak (100) intensity is drastically reduced after irradiation at 2.02×1016ncm−2. •We studied the degradation of PET polymeric material under reactor neutron environment.•Optical and structural properties are progressively destroyed after irradiation.•The band gap decreases linearly with the fast neutron fluence.•The crystallinity is drastically reduced after irradiation to fast neutron fluence of 2.0×1016n/cm2.•A linear relationship between the FTIR absorption band intensity and fast neutron fluence is observed.
ISSN:0969-806X
1879-0895
DOI:10.1016/j.radphyschem.2016.10.002