Reinvestigation of Dilacunary 19‐Tungsto‐2‐arsenate(III) [AsIII2W19O67(H2O)]14– Including 183W NMR Study in Solution

We have reinvestigated the dilacunary 19‐tungsto‐2‐arsenate(III) [AsIII2W19O67(H2O)]14– (1), resulting in the mixed potassium–sodium salt K8Na6[AsIII2W19O67(H2O)]·28H2O (KNa‐1), which was structurally characterized in the solid state by single‐crystal XRD, IR, TGA, and elemental analysis, as well as...

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Published in:European journal of inorganic chemistry 2017-10, Vol.2017 (36), p.4210-4213
Main Authors: Wang, Kai‐Yao, Bassil, Bassem S., Carey, Akina M., Mougharbel, Ali S., Kortz, Ulrich
Format: Article
Language:English
Subjects:
Arsenates
Crystal structure
Heteropolytungstates
Infrared radiation
Inorganic chemistry
NMR spectroscopy
Polyoxometalates
Single crystals
Solid state
Structure elucidation
Synthesis design
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container_end_page 4213
container_issue 36
container_start_page 4210
container_title European journal of inorganic chemistry
container_volume 2017
creator Wang, Kai‐Yao
Bassil, Bassem S.
Carey, Akina M.
Mougharbel, Ali S.
Kortz, Ulrich
description We have reinvestigated the dilacunary 19‐tungsto‐2‐arsenate(III) [AsIII2W19O67(H2O)]14– (1), resulting in the mixed potassium–sodium salt K8Na6[AsIII2W19O67(H2O)]·28H2O (KNa‐1), which was structurally characterized in the solid state by single‐crystal XRD, IR, TGA, and elemental analysis, as well as in aqueous solution by 183W NMR spectroscopy for the first time. We have reinvestigated the dilacunary heteropolytungstate [As2W19O67(H2O)]14– and discovered a simple procedure for a crystalline mixed potassium–sodium salt, which was studied by 183W NMR spectroscopy in solution for the first time.
doi_str_mv 10.1002/ejic.201700865
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subjects Arsenates
Crystal structure
Heteropolytungstates
Infrared radiation
Inorganic chemistry
NMR spectroscopy
Polyoxometalates
Single crystals
Solid state
Structure elucidation
Synthesis design
title Reinvestigation of Dilacunary 19‐Tungsto‐2‐arsenate(III) [AsIII2W19O67(H2O)]14– Including 183W NMR Study in Solution
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