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Relaxation transitions in polyvinylchloride containing a nanodispersed material
Results of experimental investigations and evaluations of the influence of the microstructure of polyvinylchloride macromolecules on relaxation processes in heterogeneous systems containing nanodispersed copper powders have been given. It has been shown that the relaxation β transition whose paramet...
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Published in: | Journal of engineering physics and thermophysics 2013-07, Vol.86 (4), p.856-862 |
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container_title | Journal of engineering physics and thermophysics |
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creator | Sidletskii, V. A. Kolupaev, B. B. Klepko, V. V. Lebedev, E. V. |
description | Results of experimental investigations and evaluations of the influence of the microstructure of polyvinylchloride macromolecules on relaxation processes in heterogeneous systems containing nanodispersed copper powders have been given. It has been shown that the relaxation β transition whose parameters are dependent on the content of the filler in the composite is realized in the region 300
K
≤
T
< 400
K
. The interrelation between the β transition and the cooperative glass α transition has been established. A derivatographic analysis of the distinctive features of the process of splitting of the α maximum with allowance for the degree of ordering of the arrangement of segments in the composite volume has been made. Calculated and experimental values of the sought quantities have been compared. |
doi_str_mv | 10.1007/s10891-013-0904-1 |
format | article |
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K
≤
T
< 400
K
. The interrelation between the β transition and the cooperative glass α transition has been established. A derivatographic analysis of the distinctive features of the process of splitting of the α maximum with allowance for the degree of ordering of the arrangement of segments in the composite volume has been made. Calculated and experimental values of the sought quantities have been compared.</description><identifier>ISSN: 1062-0125</identifier><identifier>EISSN: 1573-871X</identifier><identifier>DOI: 10.1007/s10891-013-0904-1</identifier><language>eng</language><publisher>Boston: Springer US</publisher><subject>Classical Mechanics ; Complex Systems ; Engineering ; Engineering Thermodynamics ; Heat and Mass Transfer ; Industrial Chemistry/Chemical Engineering ; Thermodynamics</subject><ispartof>Journal of engineering physics and thermophysics, 2013-07, Vol.86 (4), p.856-862</ispartof><rights>Springer Science+Business Media New York 2013</rights><rights>COPYRIGHT 2013 Springer</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c341t-47e3efc282de2da0305d36f39ef7259c939823e480ecc28178e307055af165533</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>315,786,790,27957,27958</link.rule.ids></links><search><creatorcontrib>Sidletskii, V. A.</creatorcontrib><creatorcontrib>Kolupaev, B. B.</creatorcontrib><creatorcontrib>Klepko, V. V.</creatorcontrib><creatorcontrib>Lebedev, E. V.</creatorcontrib><title>Relaxation transitions in polyvinylchloride containing a nanodispersed material</title><title>Journal of engineering physics and thermophysics</title><addtitle>J Eng Phys Thermophy</addtitle><description>Results of experimental investigations and evaluations of the influence of the microstructure of polyvinylchloride macromolecules on relaxation processes in heterogeneous systems containing nanodispersed copper powders have been given. It has been shown that the relaxation β transition whose parameters are dependent on the content of the filler in the composite is realized in the region 300
K
≤
T
< 400
K
. The interrelation between the β transition and the cooperative glass α transition has been established. A derivatographic analysis of the distinctive features of the process of splitting of the α maximum with allowance for the degree of ordering of the arrangement of segments in the composite volume has been made. Calculated and experimental values of the sought quantities have been compared.</description><subject>Classical Mechanics</subject><subject>Complex Systems</subject><subject>Engineering</subject><subject>Engineering Thermodynamics</subject><subject>Heat and Mass Transfer</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Thermodynamics</subject><issn>1062-0125</issn><issn>1573-871X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNp1kUtLAzEUhQdRsD5-gLsBVy5Gb14zybKIj0KhUBXchTBzp6ZMk5pMpf33ZhgXupAscsn9zs09nCy7InBLAKq7SEAqUgBhBSjgBTnKJkRUrJAVeT9ONZQ0dak4zc5iXAOAkpxNssUSO7M3vfUu74Nx0Q5lzK3Lt747fFl36OqPzgfbYF571xvrrFvlJnfG-cbGLYaITb4xPQZruovspDVdxMuf-zx7e3x4vX8u5oun2f10XtSMk77gFTJsayppg7QxwEA0rGyZwraiQtWKKUkZcglYJ4pUEhlUIIRpSSkEY-fZ9Th3G_znDmOv134XXPpSE15JUJRxkajbkVqZDrV1rU8e63Qa3NjkBlub3qeMc8WlKMskuPkjGBzjvl-ZXYx69rL8y5KRrYOPMWCrt8FuTDhoAnoIRY-h6BSKHkLRJGnoqImJdSsMv9b-V_QNKxOOYQ</recordid><startdate>20130701</startdate><enddate>20130701</enddate><creator>Sidletskii, V. A.</creator><creator>Kolupaev, B. B.</creator><creator>Klepko, V. V.</creator><creator>Lebedev, E. V.</creator><general>Springer US</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>ISR</scope></search><sort><creationdate>20130701</creationdate><title>Relaxation transitions in polyvinylchloride containing a nanodispersed material</title><author>Sidletskii, V. A. ; Kolupaev, B. B. ; Klepko, V. V. ; Lebedev, E. V.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c341t-47e3efc282de2da0305d36f39ef7259c939823e480ecc28178e307055af165533</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Classical Mechanics</topic><topic>Complex Systems</topic><topic>Engineering</topic><topic>Engineering Thermodynamics</topic><topic>Heat and Mass Transfer</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Thermodynamics</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sidletskii, V. A.</creatorcontrib><creatorcontrib>Kolupaev, B. B.</creatorcontrib><creatorcontrib>Klepko, V. V.</creatorcontrib><creatorcontrib>Lebedev, E. V.</creatorcontrib><collection>CrossRef</collection><collection>Gale In Context: Science</collection><jtitle>Journal of engineering physics and thermophysics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sidletskii, V. A.</au><au>Kolupaev, B. B.</au><au>Klepko, V. V.</au><au>Lebedev, E. V.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Relaxation transitions in polyvinylchloride containing a nanodispersed material</atitle><jtitle>Journal of engineering physics and thermophysics</jtitle><stitle>J Eng Phys Thermophy</stitle><date>2013-07-01</date><risdate>2013</risdate><volume>86</volume><issue>4</issue><spage>856</spage><epage>862</epage><pages>856-862</pages><issn>1062-0125</issn><eissn>1573-871X</eissn><abstract>Results of experimental investigations and evaluations of the influence of the microstructure of polyvinylchloride macromolecules on relaxation processes in heterogeneous systems containing nanodispersed copper powders have been given. It has been shown that the relaxation β transition whose parameters are dependent on the content of the filler in the composite is realized in the region 300
K
≤
T
< 400
K
. The interrelation between the β transition and the cooperative glass α transition has been established. A derivatographic analysis of the distinctive features of the process of splitting of the α maximum with allowance for the degree of ordering of the arrangement of segments in the composite volume has been made. Calculated and experimental values of the sought quantities have been compared.</abstract><cop>Boston</cop><pub>Springer US</pub><doi>10.1007/s10891-013-0904-1</doi><tpages>7</tpages></addata></record> |
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subjects | Classical Mechanics Complex Systems Engineering Engineering Thermodynamics Heat and Mass Transfer Industrial Chemistry/Chemical Engineering Thermodynamics |
title | Relaxation transitions in polyvinylchloride containing a nanodispersed material |
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