Loading…
Product Branching Ratio of the HCCO + NO Reaction
The reaction of HCCO radicals with NO was studied at room temperature by excimer laser photolysis of ketene precursor molecules followed by infrared absorption spectroscopic detection of CO and CO2 product molecules. After quantification of product yields and consideration of secondary chemistry, we...
Saved in:
Published in: | The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2000-01, Vol.104 (2), p.293-296 |
---|---|
Main Authors: | , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
cited_by | cdi_FETCH-LOGICAL-a238t-f824a97ed67b0a482ecf00937d4c8fc2e4c02f7aa3693c962621bb104a3d2b503 |
---|---|
cites | cdi_FETCH-LOGICAL-a238t-f824a97ed67b0a482ecf00937d4c8fc2e4c02f7aa3693c962621bb104a3d2b503 |
container_end_page | 296 |
container_issue | 2 |
container_start_page | 293 |
container_title | The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory |
container_volume | 104 |
creator | Rim, Kwang Taeg Hershberger, John F |
description | The reaction of HCCO radicals with NO was studied at room temperature by excimer laser photolysis of ketene precursor molecules followed by infrared absorption spectroscopic detection of CO and CO2 product molecules. After quantification of product yields and consideration of secondary chemistry, we obtain the following product branching ratios (1σ error bars) at 296 K: 0.12 ± 0.04 for CO2 + (HCN) and 0.88 ± 0.04 for CO + (HCNO). In addition, we estimate a relative quantum yield for HCCO production in the 193 nm photolysis of CH2CO to be 0.17 ± 0.02. |
doi_str_mv | 10.1021/jp9922209 |
format | article |
fullrecord | <record><control><sourceid>acs_osti_</sourceid><recordid>TN_cdi_osti_scitechconnect_20017473</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>g13719808</sourcerecordid><originalsourceid>FETCH-LOGICAL-a238t-f824a97ed67b0a482ecf00937d4c8fc2e4c02f7aa3693c962621bb104a3d2b503</originalsourceid><addsrcrecordid>eNpt0FFLwzAQB_AgCs7pg98gID6IVC-XtmkeXdFNGW7W-eJLSLPUdWo7kgz021up7MmnO7gfx92fkFMGVwyQXa83UiIiyD0yYAlClCBL9rseMhklKZeH5Mj7NQAwjvGAsLlrl1sT6Mjpxqzq5o0WOtQtbSsaVpZO8nxGL-njjBZWm27QHJODSn94e_JXh-Tl7naRT6LpbHyf30wjjTwLUZVhrKWwy1SUoOMMrakAJBfL2GSVQRsbwEpozVPJjUwxRVaWDGLNl1gmwIfkrN_b-lArb-pgzcq0TWNNUNjdL2LBO3XRK-Na752t1MbVn9p9KwbqNxG1S6SzUW9rH-zXDmr3rlLBRaIW82clChw_PRQj9dr5895r49W63bqm-_efvT95umqy</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Product Branching Ratio of the HCCO + NO Reaction</title><source>American Chemical Society:Jisc Collections:American Chemical Society Read & Publish Agreement 2022-2024 (Reading list)</source><creator>Rim, Kwang Taeg ; Hershberger, John F</creator><creatorcontrib>Rim, Kwang Taeg ; Hershberger, John F ; North Dakota State Univ., Fargo, ND (US)</creatorcontrib><description>The reaction of HCCO radicals with NO was studied at room temperature by excimer laser photolysis of ketene precursor molecules followed by infrared absorption spectroscopic detection of CO and CO2 product molecules. After quantification of product yields and consideration of secondary chemistry, we obtain the following product branching ratios (1σ error bars) at 296 K: 0.12 ± 0.04 for CO2 + (HCN) and 0.88 ± 0.04 for CO + (HCNO). In addition, we estimate a relative quantum yield for HCCO production in the 193 nm photolysis of CH2CO to be 0.17 ± 0.02.</description><identifier>ISSN: 1089-5639</identifier><identifier>EISSN: 1520-5215</identifier><identifier>DOI: 10.1021/jp9922209</identifier><language>eng</language><publisher>United States: American Chemical Society</publisher><subject>CHEMICAL REACTION KINETICS ; COMBUSTION PRODUCTS ; INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ; KETENES ; NITRIC OXIDE ; PHOTOLYSIS</subject><ispartof>The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory, 2000-01, Vol.104 (2), p.293-296</ispartof><rights>Copyright © 2000 American Chemical Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a238t-f824a97ed67b0a482ecf00937d4c8fc2e4c02f7aa3693c962621bb104a3d2b503</citedby><cites>FETCH-LOGICAL-a238t-f824a97ed67b0a482ecf00937d4c8fc2e4c02f7aa3693c962621bb104a3d2b503</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,315,786,790,891,27957,27958</link.rule.ids><backlink>$$Uhttps://www.osti.gov/biblio/20017473$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Rim, Kwang Taeg</creatorcontrib><creatorcontrib>Hershberger, John F</creatorcontrib><creatorcontrib>North Dakota State Univ., Fargo, ND (US)</creatorcontrib><title>Product Branching Ratio of the HCCO + NO Reaction</title><title>The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory</title><addtitle>J. Phys. Chem. A</addtitle><description>The reaction of HCCO radicals with NO was studied at room temperature by excimer laser photolysis of ketene precursor molecules followed by infrared absorption spectroscopic detection of CO and CO2 product molecules. After quantification of product yields and consideration of secondary chemistry, we obtain the following product branching ratios (1σ error bars) at 296 K: 0.12 ± 0.04 for CO2 + (HCN) and 0.88 ± 0.04 for CO + (HCNO). In addition, we estimate a relative quantum yield for HCCO production in the 193 nm photolysis of CH2CO to be 0.17 ± 0.02.</description><subject>CHEMICAL REACTION KINETICS</subject><subject>COMBUSTION PRODUCTS</subject><subject>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</subject><subject>KETENES</subject><subject>NITRIC OXIDE</subject><subject>PHOTOLYSIS</subject><issn>1089-5639</issn><issn>1520-5215</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2000</creationdate><recordtype>article</recordtype><recordid>eNpt0FFLwzAQB_AgCs7pg98gID6IVC-XtmkeXdFNGW7W-eJLSLPUdWo7kgz021up7MmnO7gfx92fkFMGVwyQXa83UiIiyD0yYAlClCBL9rseMhklKZeH5Mj7NQAwjvGAsLlrl1sT6Mjpxqzq5o0WOtQtbSsaVpZO8nxGL-njjBZWm27QHJODSn94e_JXh-Tl7naRT6LpbHyf30wjjTwLUZVhrKWwy1SUoOMMrakAJBfL2GSVQRsbwEpozVPJjUwxRVaWDGLNl1gmwIfkrN_b-lArb-pgzcq0TWNNUNjdL2LBO3XRK-Na752t1MbVn9p9KwbqNxG1S6SzUW9rH-zXDmr3rlLBRaIW82clChw_PRQj9dr5895r49W63bqm-_efvT95umqy</recordid><startdate>20000120</startdate><enddate>20000120</enddate><creator>Rim, Kwang Taeg</creator><creator>Hershberger, John F</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>OTOTI</scope></search><sort><creationdate>20000120</creationdate><title>Product Branching Ratio of the HCCO + NO Reaction</title><author>Rim, Kwang Taeg ; Hershberger, John F</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a238t-f824a97ed67b0a482ecf00937d4c8fc2e4c02f7aa3693c962621bb104a3d2b503</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2000</creationdate><topic>CHEMICAL REACTION KINETICS</topic><topic>COMBUSTION PRODUCTS</topic><topic>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</topic><topic>KETENES</topic><topic>NITRIC OXIDE</topic><topic>PHOTOLYSIS</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Rim, Kwang Taeg</creatorcontrib><creatorcontrib>Hershberger, John F</creatorcontrib><creatorcontrib>North Dakota State Univ., Fargo, ND (US)</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Rim, Kwang Taeg</au><au>Hershberger, John F</au><aucorp>North Dakota State Univ., Fargo, ND (US)</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Product Branching Ratio of the HCCO + NO Reaction</atitle><jtitle>The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory</jtitle><addtitle>J. Phys. Chem. A</addtitle><date>2000-01-20</date><risdate>2000</risdate><volume>104</volume><issue>2</issue><spage>293</spage><epage>296</epage><pages>293-296</pages><issn>1089-5639</issn><eissn>1520-5215</eissn><notes>istex:E97708869B15BEFDBC883A5D4E3A68A0D16351A5</notes><notes>ark:/67375/TPS-7R2GQJRB-Z</notes><notes>FG03-96ER14645</notes><notes>USDOE</notes><abstract>The reaction of HCCO radicals with NO was studied at room temperature by excimer laser photolysis of ketene precursor molecules followed by infrared absorption spectroscopic detection of CO and CO2 product molecules. After quantification of product yields and consideration of secondary chemistry, we obtain the following product branching ratios (1σ error bars) at 296 K: 0.12 ± 0.04 for CO2 + (HCN) and 0.88 ± 0.04 for CO + (HCNO). In addition, we estimate a relative quantum yield for HCCO production in the 193 nm photolysis of CH2CO to be 0.17 ± 0.02.</abstract><cop>United States</cop><pub>American Chemical Society</pub><doi>10.1021/jp9922209</doi><tpages>4</tpages></addata></record> |
fulltext | fulltext |
identifier | ISSN: 1089-5639 |
ispartof | The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory, 2000-01, Vol.104 (2), p.293-296 |
issn | 1089-5639 1520-5215 |
language | eng |
recordid | cdi_osti_scitechconnect_20017473 |
source | American Chemical Society:Jisc Collections:American Chemical Society Read & Publish Agreement 2022-2024 (Reading list) |
subjects | CHEMICAL REACTION KINETICS COMBUSTION PRODUCTS INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY KETENES NITRIC OXIDE PHOTOLYSIS |
title | Product Branching Ratio of the HCCO + NO Reaction |
url | http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-09-22T18%3A19%3A36IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-acs_osti_&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Product%20Branching%20Ratio%20of%20the%20HCCO%20+%20NO%20Reaction&rft.jtitle=The%20journal%20of%20physical%20chemistry.%20A,%20Molecules,%20spectroscopy,%20kinetics,%20environment,%20&%20general%20theory&rft.au=Rim,%20Kwang%20Taeg&rft.aucorp=North%20Dakota%20State%20Univ.,%20Fargo,%20ND%20(US)&rft.date=2000-01-20&rft.volume=104&rft.issue=2&rft.spage=293&rft.epage=296&rft.pages=293-296&rft.issn=1089-5639&rft.eissn=1520-5215&rft_id=info:doi/10.1021/jp9922209&rft_dat=%3Cacs_osti_%3Eg13719808%3C/acs_osti_%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-a238t-f824a97ed67b0a482ecf00937d4c8fc2e4c02f7aa3693c962621bb104a3d2b503%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |