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Redox-Active Supramolecular Polymer Binders for Lithium–Sulfur Batteries That Adapt Their Transport Properties in Operando
π-Stacked perylene bisimide (PBI) molecules are implemented here as highly networked, redox-active supramolecular polymer binders in sulfur cathodes for lightweight and energy-dense Li–S batteries. We show that the in operando reduction and lithiation of these PBI binders sustainably reduces Li–S ce...
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Published in: | Chemistry of materials 2016-10, Vol.28 (20), p.7414-7421 |
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container_end_page | 7421 |
container_issue | 20 |
container_start_page | 7414 |
container_title | Chemistry of materials |
container_volume | 28 |
creator | Frischmann, Peter D Hwa, Yoon Cairns, Elton J Helms, Brett A |
description | π-Stacked perylene bisimide (PBI) molecules are implemented here as highly networked, redox-active supramolecular polymer binders in sulfur cathodes for lightweight and energy-dense Li–S batteries. We show that the in operando reduction and lithiation of these PBI binders sustainably reduces Li–S cell impedance relative to nonredox active conventional polymer binders. This lower impedance enables high-rate cycling in Li–S cells with excellent durability, a critical step toward unlocking the full potential of Li–S batteries for electric vehicles and aviation. |
doi_str_mv | 10.1021/acs.chemmater.6b03013 |
format | article |
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(LBNL), Berkeley, CA (United States)</creatorcontrib><title>Redox-Active Supramolecular Polymer Binders for Lithium–Sulfur Batteries That Adapt Their Transport Properties in Operando</title><title>Chemistry of materials</title><addtitle>Chem. Mater</addtitle><description>π-Stacked perylene bisimide (PBI) molecules are implemented here as highly networked, redox-active supramolecular polymer binders in sulfur cathodes for lightweight and energy-dense Li–S batteries. We show that the in operando reduction and lithiation of these PBI binders sustainably reduces Li–S cell impedance relative to nonredox active conventional polymer binders. 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(LBNL), Berkeley, CA (United States)</creatorcontrib><collection>CrossRef</collection><collection>OSTI.GOV - Hybrid</collection><collection>OSTI.GOV</collection><jtitle>Chemistry of materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Frischmann, Peter D</au><au>Hwa, Yoon</au><au>Cairns, Elton J</au><au>Helms, Brett A</au><aucorp>Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Redox-Active Supramolecular Polymer Binders for Lithium–Sulfur Batteries That Adapt Their Transport Properties in Operando</atitle><jtitle>Chemistry of materials</jtitle><addtitle>Chem. Mater</addtitle><date>2016-10-25</date><risdate>2016</risdate><volume>28</volume><issue>20</issue><spage>7414</spage><epage>7421</epage><pages>7414-7421</pages><issn>0897-4756</issn><eissn>1520-5002</eissn><notes>AC02-05CH11231</notes><notes>USDOE Office of Science (SC), Basic Energy Sciences (BES)</notes><abstract>π-Stacked perylene bisimide (PBI) molecules are implemented here as highly networked, redox-active supramolecular polymer binders in sulfur cathodes for lightweight and energy-dense Li–S batteries. We show that the in operando reduction and lithiation of these PBI binders sustainably reduces Li–S cell impedance relative to nonredox active conventional polymer binders. This lower impedance enables high-rate cycling in Li–S cells with excellent durability, a critical step toward unlocking the full potential of Li–S batteries for electric vehicles and aviation.</abstract><cop>United States</cop><pub>American Chemical Society</pub><doi>10.1021/acs.chemmater.6b03013</doi><tpages>8</tpages><oa>free_for_read</oa></addata></record> |
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subjects | ENERGY STORAGE INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY MATERIALS SCIENCE |
title | Redox-Active Supramolecular Polymer Binders for Lithium–Sulfur Batteries That Adapt Their Transport Properties in Operando |
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