The photoelectron spectrum of ArXe obtained using resonantly enhanced multiphoton ionization

The photoelectron spectrum of the heteronuclear rare gas dimer ArXe was determined using resonantly enhanced multiphoton ionization-photoelectron spectroscopy (REMPI-PES). Three photoelectron peaks are observed corresponding to the production of ArXe+ in the A2Σ+1/2 B2Π3/2, and B2Π1/2 states. The ki...

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Bibliographic Details
Published in:The Journal of chemical physics 1985-01, Vol.82 (12), p.5758-5760
Main Authors: PRATT, S. T, DEHMER, P. M, DEHMER, J. L
Format: Article
Language:English
Subjects:
ATOMIC AND MOLECULAR PHYSICS
Exact sciences and technology
INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Molecular properties and interactions with photons
Photoelectron spectra
Physics
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Summary:The photoelectron spectrum of the heteronuclear rare gas dimer ArXe was determined using resonantly enhanced multiphoton ionization-photoelectron spectroscopy (REMPI-PES). Three photoelectron peaks are observed corresponding to the production of ArXe+ in the A2Σ+1/2 B2Π3/2, and B2Π1/2 states. The kinetic energies of these peaks are used to determine lower limits for the dissociation energies of the ionic states.
ISSN:0021-9606
1089-7690
DOI:10.1063/1.448566