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Ternary Stannides LiTSn4 (T = Ru, Rh, Ir)Chemical Bonding and Physical Properties
Pure samples of the ternary stannides LiTSn4 (T = Ru, Rh, Ir) have been synthesized from the elements in sealed tantalum tubes. They crystallize with an ordered version of the PdGa5 type. LiTSn4 (T = Ru, Rh, Ir) are all metallic conductors and Pauli paramagnets. Spectroscopic measurements indicate s...
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Published in: | The journal of physical chemistry. B 2003-03, Vol.107 (9), p.1943-1948 |
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container_end_page | 1948 |
container_issue | 9 |
container_start_page | 1943 |
container_title | The journal of physical chemistry. B |
container_volume | 107 |
creator | Wu, Zhiyun Eckert, Hellmut Senker, Jürgen Johrendt, Dirk Kotzyba, Gunter Mosel, Bernd D Trill, Henning Hoffmann, Rolf-Dieter Pöttgen, Rainer |
description | Pure samples of the ternary stannides LiTSn4 (T = Ru, Rh, Ir) have been synthesized from the elements in sealed tantalum tubes. They crystallize with an ordered version of the PdGa5 type. LiTSn4 (T = Ru, Rh, Ir) are all metallic conductors and Pauli paramagnets. Spectroscopic measurements indicate significant differences in the chemical bonding properties: As revealed by both 119Sn Mössbauer spectroscopy and solid-state NMR data, the local electron distribution at the tin site is more anisotropic in LiRuSn4 compared to the other two materials. In addition, 7Li Knight shift and spin-lattice relaxation times indicate that LiRuSn4 has a much higher electron density at the lithium atom arising from conduction electrons at the Fermi level. These findings are in good agreement with the results of DFT band structure calculations. |
doi_str_mv | 10.1021/jp0220635 |
format | article |
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They crystallize with an ordered version of the PdGa5 type. LiTSn4 (T = Ru, Rh, Ir) are all metallic conductors and Pauli paramagnets. Spectroscopic measurements indicate significant differences in the chemical bonding properties: As revealed by both 119Sn Mössbauer spectroscopy and solid-state NMR data, the local electron distribution at the tin site is more anisotropic in LiRuSn4 compared to the other two materials. In addition, 7Li Knight shift and spin-lattice relaxation times indicate that LiRuSn4 has a much higher electron density at the lithium atom arising from conduction electrons at the Fermi level. These findings are in good agreement with the results of DFT band structure calculations.</description><identifier>ISSN: 1520-6106</identifier><identifier>EISSN: 1520-5207</identifier><identifier>DOI: 10.1021/jp0220635</identifier><language>eng</language><publisher>American Chemical Society</publisher><ispartof>The journal of physical chemistry. 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B</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wu, Zhiyun</au><au>Eckert, Hellmut</au><au>Senker, Jürgen</au><au>Johrendt, Dirk</au><au>Kotzyba, Gunter</au><au>Mosel, Bernd D</au><au>Trill, Henning</au><au>Hoffmann, Rolf-Dieter</au><au>Pöttgen, Rainer</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Ternary Stannides LiTSn4 (T = Ru, Rh, Ir)Chemical Bonding and Physical Properties</atitle><jtitle>The journal of physical chemistry. B</jtitle><addtitle>J. Phys. Chem. B</addtitle><date>2003-03-06</date><risdate>2003</risdate><volume>107</volume><issue>9</issue><spage>1943</spage><epage>1948</epage><pages>1943-1948</pages><issn>1520-6106</issn><eissn>1520-5207</eissn><notes>istex:E899CE6611BACC8F63B926EA13F76F7E3E2E1C09</notes><notes>ark:/67375/TPS-T3MSVLHQ-0</notes><abstract>Pure samples of the ternary stannides LiTSn4 (T = Ru, Rh, Ir) have been synthesized from the elements in sealed tantalum tubes. They crystallize with an ordered version of the PdGa5 type. LiTSn4 (T = Ru, Rh, Ir) are all metallic conductors and Pauli paramagnets. Spectroscopic measurements indicate significant differences in the chemical bonding properties: As revealed by both 119Sn Mössbauer spectroscopy and solid-state NMR data, the local electron distribution at the tin site is more anisotropic in LiRuSn4 compared to the other two materials. In addition, 7Li Knight shift and spin-lattice relaxation times indicate that LiRuSn4 has a much higher electron density at the lithium atom arising from conduction electrons at the Fermi level. These findings are in good agreement with the results of DFT band structure calculations.</abstract><pub>American Chemical Society</pub><doi>10.1021/jp0220635</doi><tpages>6</tpages></addata></record> |
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title | Ternary Stannides LiTSn4 (T = Ru, Rh, Ir)Chemical Bonding and Physical Properties |
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