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Cornstarch and tannin in phenol–formaldehyde resins for plywood production
The aim of this work is to demonstrate the performances of cornstarch–quebracho tannin-based resins designed as adhesive in the plywood production. In this way, the cornstarch and quebracho tannin was introduced in the classic adhesive formulation in order to supply a part of phenol–formaldehyde (PF...
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Published in: | Industrial crops and products 2009-09, Vol.30 (2), p.188-193 |
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creator | Moubarik, Amine Pizzi, Antonio Allal, Ahmed Charrier, Fatima Charrier, Bertrand |
description | The aim of this work is to demonstrate the performances of cornstarch–quebracho tannin-based resins designed as adhesive in the plywood production. In this way, the cornstarch and quebracho tannin was introduced in the classic adhesive formulation in order to supply a part of phenol–formaldehyde (PF). The physical properties (rheological characterization, thermogravimetric analysis and solid phase
13C NMR analysis) of the formulated resins were measured. In order to evaluate the mechanical performances of optimal cornstarch–quebracho tannin-based resins, plywood panels were produced and mechanical properties were investigated. These mechanical properties included tensile strength, wood failure and 3-point bending strength. The performance of these panels is comparable to those of plywood panels commercial PF made.
The results showed that plywood panels bonded with cornstarch–quebracho tannin–PF resins (15:5:80, w/w/w) exhibited better mechanical properties than plywood panels commercial PF made. The introduction of small proportions of cornstarch and quebracho tannin in PF resins contributes to the improvement of the boiling water performance of these adhesives. The formaldehyde emission levels obtained from panels bonded with cornstarch–quebracho tannin–PF were lower to those obtained from panels bonded with control PF. Solid state CPMAS NMR spectra indicates that no reaction at all between PF resins and cornstarch and quebracho tannin. Even when reaction does evidently not occur, the addition of cornstarch and quebracho tannin improves markedly the water resistance of PF resins. |
doi_str_mv | 10.1016/j.indcrop.2009.03.005 |
format | article |
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13C NMR analysis) of the formulated resins were measured. In order to evaluate the mechanical performances of optimal cornstarch–quebracho tannin-based resins, plywood panels were produced and mechanical properties were investigated. These mechanical properties included tensile strength, wood failure and 3-point bending strength. The performance of these panels is comparable to those of plywood panels commercial PF made.
The results showed that plywood panels bonded with cornstarch–quebracho tannin–PF resins (15:5:80, w/w/w) exhibited better mechanical properties than plywood panels commercial PF made. The introduction of small proportions of cornstarch and quebracho tannin in PF resins contributes to the improvement of the boiling water performance of these adhesives. The formaldehyde emission levels obtained from panels bonded with cornstarch–quebracho tannin–PF were lower to those obtained from panels bonded with control PF. Solid state CPMAS NMR spectra indicates that no reaction at all between PF resins and cornstarch and quebracho tannin. Even when reaction does evidently not occur, the addition of cornstarch and quebracho tannin improves markedly the water resistance of PF resins.</description><identifier>ISSN: 0926-6690</identifier><identifier>EISSN: 1872-633X</identifier><identifier>DOI: 10.1016/j.indcrop.2009.03.005</identifier><language>eng</language><publisher>Elsevier B.V</publisher><subject>adhesion ; adhesives ; application rate ; bending strength ; Condensed Matter ; corn starch ; Cornstarch ; formaldehyde ; mechanical failure ; mechanical properties ; nuclear magnetic resonance spectroscopy ; Phenol formaldehyde ; phenols ; Physics ; Plywood ; Quebracho tannin ; resins ; rheological properties ; tannins ; tensile strength ; thermogravimetry ; water ; water resistance (materials) ; Wood adhesive</subject><ispartof>Industrial crops and products, 2009-09, Vol.30 (2), p.188-193</ispartof><rights>2009 Elsevier B.V.</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c464t-f33f79783ade341f0f501bcd712f5466305ca86583611ce4ee17f4da562db9b13</citedby><cites>FETCH-LOGICAL-c464t-f33f79783ade341f0f501bcd712f5466305ca86583611ce4ee17f4da562db9b13</cites><orcidid>0000-0002-3435-2499 ; 0000-0001-7391-9358</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,315,783,787,888,27936,27937</link.rule.ids><backlink>$$Uhttps://hal.science/hal-01584331$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Moubarik, Amine</creatorcontrib><creatorcontrib>Pizzi, Antonio</creatorcontrib><creatorcontrib>Allal, Ahmed</creatorcontrib><creatorcontrib>Charrier, Fatima</creatorcontrib><creatorcontrib>Charrier, Bertrand</creatorcontrib><title>Cornstarch and tannin in phenol–formaldehyde resins for plywood production</title><title>Industrial crops and products</title><description>The aim of this work is to demonstrate the performances of cornstarch–quebracho tannin-based resins designed as adhesive in the plywood production. In this way, the cornstarch and quebracho tannin was introduced in the classic adhesive formulation in order to supply a part of phenol–formaldehyde (PF). The physical properties (rheological characterization, thermogravimetric analysis and solid phase
13C NMR analysis) of the formulated resins were measured. In order to evaluate the mechanical performances of optimal cornstarch–quebracho tannin-based resins, plywood panels were produced and mechanical properties were investigated. These mechanical properties included tensile strength, wood failure and 3-point bending strength. The performance of these panels is comparable to those of plywood panels commercial PF made.
The results showed that plywood panels bonded with cornstarch–quebracho tannin–PF resins (15:5:80, w/w/w) exhibited better mechanical properties than plywood panels commercial PF made. The introduction of small proportions of cornstarch and quebracho tannin in PF resins contributes to the improvement of the boiling water performance of these adhesives. The formaldehyde emission levels obtained from panels bonded with cornstarch–quebracho tannin–PF were lower to those obtained from panels bonded with control PF. Solid state CPMAS NMR spectra indicates that no reaction at all between PF resins and cornstarch and quebracho tannin. Even when reaction does evidently not occur, the addition of cornstarch and quebracho tannin improves markedly the water resistance of PF resins.</description><subject>adhesion</subject><subject>adhesives</subject><subject>application rate</subject><subject>bending strength</subject><subject>Condensed Matter</subject><subject>corn starch</subject><subject>Cornstarch</subject><subject>formaldehyde</subject><subject>mechanical failure</subject><subject>mechanical properties</subject><subject>nuclear magnetic resonance spectroscopy</subject><subject>Phenol formaldehyde</subject><subject>phenols</subject><subject>Physics</subject><subject>Plywood</subject><subject>Quebracho tannin</subject><subject>resins</subject><subject>rheological properties</subject><subject>tannins</subject><subject>tensile strength</subject><subject>thermogravimetry</subject><subject>water</subject><subject>water resistance (materials)</subject><subject>Wood adhesive</subject><issn>0926-6690</issn><issn>1872-633X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><recordid>eNqFkMFq3DAQhkVpINskjxDiU6EHOyPLlu1TCUvaBBZ6aAK5Ca006mrxSq7k3bC3vkPesE8SOQ69FgYGhm_-GT5CLikUFCi_3hbWaRX8UJQAXQGsAKg_kAVtmzLnjD19JAvoSp5z3sEp-RTjFoA2UDYLslr64OIog9pk0ulslM5Zl6UaNuh8__fPi_FhJ3uNm6PGLGC0LmZplg398dl7nQ3B670arXfn5MTIPuLFez8jj99uH5Z3-erH9_vlzSpXFa_G3DBmmq5pmdTIKmrA1EDXSje0NHXFOYNayZbXLeOUKqwQaWMqLWte6nW3puyMfJlzN7IXQ7A7GY7CSyvublZimgGt24oxepjYzzOb3vy9xziKnY0K-1469PsoSmiSQw4JrGcwmYwxoPmXTEFMnsVWvHsWk2cBTCTPae9q3jPSC_kr2Cgef5ZA2Vts107E15nA5ORgMYioLDqF2gZUo9De_ufGKz72k3M</recordid><startdate>20090901</startdate><enddate>20090901</enddate><creator>Moubarik, Amine</creator><creator>Pizzi, Antonio</creator><creator>Allal, Ahmed</creator><creator>Charrier, Fatima</creator><creator>Charrier, Bertrand</creator><general>Elsevier B.V</general><general>[Amsterdam; New York, NY]: Elsevier Science</general><general>Elsevier</general><scope>FBQ</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7ST</scope><scope>C1K</scope><scope>SOI</scope><scope>1XC</scope><orcidid>https://orcid.org/0000-0002-3435-2499</orcidid><orcidid>https://orcid.org/0000-0001-7391-9358</orcidid></search><sort><creationdate>20090901</creationdate><title>Cornstarch and tannin in phenol–formaldehyde resins for plywood production</title><author>Moubarik, Amine ; Pizzi, Antonio ; Allal, Ahmed ; Charrier, Fatima ; Charrier, Bertrand</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c464t-f33f79783ade341f0f501bcd712f5466305ca86583611ce4ee17f4da562db9b13</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2009</creationdate><topic>adhesion</topic><topic>adhesives</topic><topic>application rate</topic><topic>bending strength</topic><topic>Condensed Matter</topic><topic>corn starch</topic><topic>Cornstarch</topic><topic>formaldehyde</topic><topic>mechanical failure</topic><topic>mechanical properties</topic><topic>nuclear magnetic resonance spectroscopy</topic><topic>Phenol formaldehyde</topic><topic>phenols</topic><topic>Physics</topic><topic>Plywood</topic><topic>Quebracho tannin</topic><topic>resins</topic><topic>rheological properties</topic><topic>tannins</topic><topic>tensile strength</topic><topic>thermogravimetry</topic><topic>water</topic><topic>water resistance (materials)</topic><topic>Wood adhesive</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Moubarik, Amine</creatorcontrib><creatorcontrib>Pizzi, Antonio</creatorcontrib><creatorcontrib>Allal, Ahmed</creatorcontrib><creatorcontrib>Charrier, Fatima</creatorcontrib><creatorcontrib>Charrier, Bertrand</creatorcontrib><collection>AGRIS</collection><collection>CrossRef</collection><collection>Environment Abstracts</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Environment Abstracts</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Industrial crops and products</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Moubarik, Amine</au><au>Pizzi, Antonio</au><au>Allal, Ahmed</au><au>Charrier, Fatima</au><au>Charrier, Bertrand</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Cornstarch and tannin in phenol–formaldehyde resins for plywood production</atitle><jtitle>Industrial crops and products</jtitle><date>2009-09-01</date><risdate>2009</risdate><volume>30</volume><issue>2</issue><spage>188</spage><epage>193</epage><pages>188-193</pages><issn>0926-6690</issn><eissn>1872-633X</eissn><abstract>The aim of this work is to demonstrate the performances of cornstarch–quebracho tannin-based resins designed as adhesive in the plywood production. In this way, the cornstarch and quebracho tannin was introduced in the classic adhesive formulation in order to supply a part of phenol–formaldehyde (PF). The physical properties (rheological characterization, thermogravimetric analysis and solid phase
13C NMR analysis) of the formulated resins were measured. In order to evaluate the mechanical performances of optimal cornstarch–quebracho tannin-based resins, plywood panels were produced and mechanical properties were investigated. These mechanical properties included tensile strength, wood failure and 3-point bending strength. The performance of these panels is comparable to those of plywood panels commercial PF made.
The results showed that plywood panels bonded with cornstarch–quebracho tannin–PF resins (15:5:80, w/w/w) exhibited better mechanical properties than plywood panels commercial PF made. The introduction of small proportions of cornstarch and quebracho tannin in PF resins contributes to the improvement of the boiling water performance of these adhesives. The formaldehyde emission levels obtained from panels bonded with cornstarch–quebracho tannin–PF were lower to those obtained from panels bonded with control PF. Solid state CPMAS NMR spectra indicates that no reaction at all between PF resins and cornstarch and quebracho tannin. Even when reaction does evidently not occur, the addition of cornstarch and quebracho tannin improves markedly the water resistance of PF resins.</abstract><pub>Elsevier B.V</pub><doi>10.1016/j.indcrop.2009.03.005</doi><tpages>6</tpages><orcidid>https://orcid.org/0000-0002-3435-2499</orcidid><orcidid>https://orcid.org/0000-0001-7391-9358</orcidid></addata></record> |
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subjects | adhesion adhesives application rate bending strength Condensed Matter corn starch Cornstarch formaldehyde mechanical failure mechanical properties nuclear magnetic resonance spectroscopy Phenol formaldehyde phenols Physics Plywood Quebracho tannin resins rheological properties tannins tensile strength thermogravimetry water water resistance (materials) Wood adhesive |
title | Cornstarch and tannin in phenol–formaldehyde resins for plywood production |
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