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Efficient and stable CH3NH3PbI3-sensitized ZnO nanorod array solid-state solar cells
We report for the first time the use of a perovskite (CH 3 NH 3 PbI 3 ) absorber in combination with ZnO nanorod arrays (NRAs) for solar cell applications. The perovskite material has a higher absorption coefficient than molecular dye sensitizers, gives better solar cell stability, and is therefore...
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| Published in: | Nanoscale 2013-12, Vol.5 (23), p.11686-11691 |
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| Main Authors: | , , , , , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c408t-828cac75c67ba538f3d158c735850267fe09fa3a5f969336c99cb236324b1c323 |
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| cites | cdi_FETCH-LOGICAL-c408t-828cac75c67ba538f3d158c735850267fe09fa3a5f969336c99cb236324b1c323 |
| container_end_page | 11691 |
| container_issue | 23 |
| container_start_page | 11686 |
| container_title | Nanoscale |
| container_volume | 5 |
| creator | Bi, Dongqin Boschloo, Gerrit Schwarzmüller, Stefan Yang, Lei Johansson, Erik M. J Hagfeldt, Anders |
| description | We report for the first time the use of a perovskite (CH
3
NH
3
PbI
3
) absorber in combination with ZnO nanorod arrays (NRAs) for solar cell applications. The perovskite material has a higher absorption coefficient than molecular dye sensitizers, gives better solar cell stability, and is therefore more suited as a sensitizer for ZnO NRAs. A solar cell efficiency of 5.0% was achieved under 1000 W m
−2
AM 1.5 G illumination for a solar cell with the structure: ZnO NRA/CH
3
NH
3
PbI
3
/spiro-MeOTAD/Ag. Moreover, the solar cell shows a good long-term stability. Using transient photocurrent and photovoltage measurements it was found that the electron transport time and lifetime vary with the ZnO nanorod length, a trend which is similar to that in dye-sensitized solar cells, DSCs, suggesting a similar charge transfer process in ZnO NRA/CH
3
NH
3
PbI
3
solar cells as in conventional DSCs. Compared to CH
3
NH
3
PbI
3
/TiO
2
solar cells, ZnO shows a lower performance due to more recombination losses.
Efficient photovoltaic devices based on ZnO nanorod arrays in combination with CH
3
NH
3
PbI
3
. |
| doi_str_mv | 10.1039/c3nr01542d |
| format | article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1039_c3nr01542d</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1450185763</sourcerecordid><originalsourceid>FETCH-LOGICAL-c408t-828cac75c67ba538f3d158c735850267fe09fa3a5f969336c99cb236324b1c323</originalsourceid><addsrcrecordid>eNp90M1LwzAYBvAgipvTi3el3kSsJnmbfhzHnG4wnIfpwUtI00QiXVuTFpl_vR2d3c1TXsgvD28ehM4JviMYknsJhcWEBTQ7QEOKA-wDRPSwn8NggE6c-8Q4TCCEYzSgAcE4CaIhWk21NtKoovZEkXmuFmmuvMkMnmfwks7Bd6pwpjY_KvPei6VXiKK0ZeYJa8XGc2VuMr99VKvtLKwnVZ67U3SkRe7U2e4codfH6Woy8xfLp_lkvPBlgOPaj2kshYyYDKNUMIg1ZITFMgIWM0zDSCucaAGC6aRdHEKZJDKl7Q9okBIJFEbotst136pqUl5ZsxZ2w0th-IN5G_PSfvCm4ZQAwaTl1x2vbPnVKFfztXHbhUWhysZxEjBMYhaF0NKbjkpbOmeV7rMJ5tvS-b70Fl_ucpt0rbKe_rXcgqsOWCf7230ArzLdmov_DPwCoouQiQ</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1450185763</pqid></control><display><type>article</type><title>Efficient and stable CH3NH3PbI3-sensitized ZnO nanorod array solid-state solar cells</title><source>Royal Society of Chemistry:Jisc Collections:Royal Society of Chemistry Read and Publish 2022-2024 (reading list)</source><creator>Bi, Dongqin ; Boschloo, Gerrit ; Schwarzmüller, Stefan ; Yang, Lei ; Johansson, Erik M. J ; Hagfeldt, Anders</creator><creatorcontrib>Bi, Dongqin ; Boschloo, Gerrit ; Schwarzmüller, Stefan ; Yang, Lei ; Johansson, Erik M. J ; Hagfeldt, Anders</creatorcontrib><description>We report for the first time the use of a perovskite (CH
3
NH
3
PbI
3
) absorber in combination with ZnO nanorod arrays (NRAs) for solar cell applications. The perovskite material has a higher absorption coefficient than molecular dye sensitizers, gives better solar cell stability, and is therefore more suited as a sensitizer for ZnO NRAs. A solar cell efficiency of 5.0% was achieved under 1000 W m
−2
AM 1.5 G illumination for a solar cell with the structure: ZnO NRA/CH
3
NH
3
PbI
3
/spiro-MeOTAD/Ag. Moreover, the solar cell shows a good long-term stability. Using transient photocurrent and photovoltage measurements it was found that the electron transport time and lifetime vary with the ZnO nanorod length, a trend which is similar to that in dye-sensitized solar cells, DSCs, suggesting a similar charge transfer process in ZnO NRA/CH
3
NH
3
PbI
3
solar cells as in conventional DSCs. Compared to CH
3
NH
3
PbI
3
/TiO
2
solar cells, ZnO shows a lower performance due to more recombination losses.
Efficient photovoltaic devices based on ZnO nanorod arrays in combination with CH
3
NH
3
PbI
3
.</description><identifier>ISSN: 2040-3364</identifier><identifier>ISSN: 2040-3372</identifier><identifier>EISSN: 2040-3372</identifier><identifier>DOI: 10.1039/c3nr01542d</identifier><identifier>PMID: 24100947</identifier><language>eng</language><publisher>England</publisher><subject>Coloring Agents - chemistry ; Electron Transport ; Iodides - chemistry ; Lead - chemistry ; Light ; Methylamines - chemistry ; Nanotubes - chemistry ; Solar Energy ; Zinc Oxide - chemistry</subject><ispartof>Nanoscale, 2013-12, Vol.5 (23), p.11686-11691</ispartof><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c408t-828cac75c67ba538f3d158c735850267fe09fa3a5f969336c99cb236324b1c323</citedby><cites>FETCH-LOGICAL-c408t-828cac75c67ba538f3d158c735850267fe09fa3a5f969336c99cb236324b1c323</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,315,786,790,891,27957,27958</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/24100947$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink><backlink>$$Uhttps://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-213101$$DView record from Swedish Publication Index$$Hfree_for_read</backlink></links><search><creatorcontrib>Bi, Dongqin</creatorcontrib><creatorcontrib>Boschloo, Gerrit</creatorcontrib><creatorcontrib>Schwarzmüller, Stefan</creatorcontrib><creatorcontrib>Yang, Lei</creatorcontrib><creatorcontrib>Johansson, Erik M. J</creatorcontrib><creatorcontrib>Hagfeldt, Anders</creatorcontrib><title>Efficient and stable CH3NH3PbI3-sensitized ZnO nanorod array solid-state solar cells</title><title>Nanoscale</title><addtitle>Nanoscale</addtitle><description>We report for the first time the use of a perovskite (CH
3
NH
3
PbI
3
) absorber in combination with ZnO nanorod arrays (NRAs) for solar cell applications. The perovskite material has a higher absorption coefficient than molecular dye sensitizers, gives better solar cell stability, and is therefore more suited as a sensitizer for ZnO NRAs. A solar cell efficiency of 5.0% was achieved under 1000 W m
−2
AM 1.5 G illumination for a solar cell with the structure: ZnO NRA/CH
3
NH
3
PbI
3
/spiro-MeOTAD/Ag. Moreover, the solar cell shows a good long-term stability. Using transient photocurrent and photovoltage measurements it was found that the electron transport time and lifetime vary with the ZnO nanorod length, a trend which is similar to that in dye-sensitized solar cells, DSCs, suggesting a similar charge transfer process in ZnO NRA/CH
3
NH
3
PbI
3
solar cells as in conventional DSCs. Compared to CH
3
NH
3
PbI
3
/TiO
2
solar cells, ZnO shows a lower performance due to more recombination losses.
Efficient photovoltaic devices based on ZnO nanorod arrays in combination with CH
3
NH
3
PbI
3
.</description><subject>Coloring Agents - chemistry</subject><subject>Electron Transport</subject><subject>Iodides - chemistry</subject><subject>Lead - chemistry</subject><subject>Light</subject><subject>Methylamines - chemistry</subject><subject>Nanotubes - chemistry</subject><subject>Solar Energy</subject><subject>Zinc Oxide - chemistry</subject><issn>2040-3364</issn><issn>2040-3372</issn><issn>2040-3372</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNp90M1LwzAYBvAgipvTi3el3kSsJnmbfhzHnG4wnIfpwUtI00QiXVuTFpl_vR2d3c1TXsgvD28ehM4JviMYknsJhcWEBTQ7QEOKA-wDRPSwn8NggE6c-8Q4TCCEYzSgAcE4CaIhWk21NtKoovZEkXmuFmmuvMkMnmfwks7Bd6pwpjY_KvPei6VXiKK0ZeYJa8XGc2VuMr99VKvtLKwnVZ67U3SkRe7U2e4codfH6Woy8xfLp_lkvPBlgOPaj2kshYyYDKNUMIg1ZITFMgIWM0zDSCucaAGC6aRdHEKZJDKl7Q9okBIJFEbotst136pqUl5ZsxZ2w0th-IN5G_PSfvCm4ZQAwaTl1x2vbPnVKFfztXHbhUWhysZxEjBMYhaF0NKbjkpbOmeV7rMJ5tvS-b70Fl_ucpt0rbKe_rXcgqsOWCf7230ArzLdmov_DPwCoouQiQ</recordid><startdate>20131207</startdate><enddate>20131207</enddate><creator>Bi, Dongqin</creator><creator>Boschloo, Gerrit</creator><creator>Schwarzmüller, Stefan</creator><creator>Yang, Lei</creator><creator>Johansson, Erik M. J</creator><creator>Hagfeldt, Anders</creator><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>ADTPV</scope><scope>AOWAS</scope><scope>DF2</scope></search><sort><creationdate>20131207</creationdate><title>Efficient and stable CH3NH3PbI3-sensitized ZnO nanorod array solid-state solar cells</title><author>Bi, Dongqin ; Boschloo, Gerrit ; Schwarzmüller, Stefan ; Yang, Lei ; Johansson, Erik M. J ; Hagfeldt, Anders</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c408t-828cac75c67ba538f3d158c735850267fe09fa3a5f969336c99cb236324b1c323</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Coloring Agents - chemistry</topic><topic>Electron Transport</topic><topic>Iodides - chemistry</topic><topic>Lead - chemistry</topic><topic>Light</topic><topic>Methylamines - chemistry</topic><topic>Nanotubes - chemistry</topic><topic>Solar Energy</topic><topic>Zinc Oxide - chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Bi, Dongqin</creatorcontrib><creatorcontrib>Boschloo, Gerrit</creatorcontrib><creatorcontrib>Schwarzmüller, Stefan</creatorcontrib><creatorcontrib>Yang, Lei</creatorcontrib><creatorcontrib>Johansson, Erik M. J</creatorcontrib><creatorcontrib>Hagfeldt, Anders</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>SwePub</collection><collection>SwePub Articles</collection><collection>SWEPUB Uppsala universitet</collection><jtitle>Nanoscale</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Bi, Dongqin</au><au>Boschloo, Gerrit</au><au>Schwarzmüller, Stefan</au><au>Yang, Lei</au><au>Johansson, Erik M. J</au><au>Hagfeldt, Anders</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Efficient and stable CH3NH3PbI3-sensitized ZnO nanorod array solid-state solar cells</atitle><jtitle>Nanoscale</jtitle><addtitle>Nanoscale</addtitle><date>2013-12-07</date><risdate>2013</risdate><volume>5</volume><issue>23</issue><spage>11686</spage><epage>11691</epage><pages>11686-11691</pages><issn>2040-3364</issn><issn>2040-3372</issn><eissn>2040-3372</eissn><notes>ObjectType-Article-1</notes><notes>SourceType-Scholarly Journals-1</notes><notes>ObjectType-Feature-2</notes><notes>content type line 23</notes><abstract>We report for the first time the use of a perovskite (CH
3
NH
3
PbI
3
) absorber in combination with ZnO nanorod arrays (NRAs) for solar cell applications. The perovskite material has a higher absorption coefficient than molecular dye sensitizers, gives better solar cell stability, and is therefore more suited as a sensitizer for ZnO NRAs. A solar cell efficiency of 5.0% was achieved under 1000 W m
−2
AM 1.5 G illumination for a solar cell with the structure: ZnO NRA/CH
3
NH
3
PbI
3
/spiro-MeOTAD/Ag. Moreover, the solar cell shows a good long-term stability. Using transient photocurrent and photovoltage measurements it was found that the electron transport time and lifetime vary with the ZnO nanorod length, a trend which is similar to that in dye-sensitized solar cells, DSCs, suggesting a similar charge transfer process in ZnO NRA/CH
3
NH
3
PbI
3
solar cells as in conventional DSCs. Compared to CH
3
NH
3
PbI
3
/TiO
2
solar cells, ZnO shows a lower performance due to more recombination losses.
Efficient photovoltaic devices based on ZnO nanorod arrays in combination with CH
3
NH
3
PbI
3
.</abstract><cop>England</cop><pmid>24100947</pmid><doi>10.1039/c3nr01542d</doi><tpages>6</tpages><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 2040-3364 |
| ispartof | Nanoscale, 2013-12, Vol.5 (23), p.11686-11691 |
| issn | 2040-3364 2040-3372 2040-3372 |
| language | eng |
| recordid | cdi_crossref_primary_10_1039_c3nr01542d |
| source | Royal Society of Chemistry:Jisc Collections:Royal Society of Chemistry Read and Publish 2022-2024 (reading list) |
| subjects | Coloring Agents - chemistry Electron Transport Iodides - chemistry Lead - chemistry Light Methylamines - chemistry Nanotubes - chemistry Solar Energy Zinc Oxide - chemistry |
| title | Efficient and stable CH3NH3PbI3-sensitized ZnO nanorod array solid-state solar cells |
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